| 1215023-39-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1215023-39-4
• 化学式: C₃₈H₄₂O₆
• 分子量: 594.748
• InChiKey: FHAVPRLBIYJZAJ-ORBPHOAGSA-N

反应信息

• 作为反应物：
  描述：

  、 乙酸酐 在 4-二甲氨基吡啶 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Sugar allyltins in the synthesis of carbohydrate mimics. Study on the cis-hydroxylation of the bicyclo[4.3.0]nonenes derived from d-mannose

  摘要：

  Sugar allyltin derivatives were applied in the synthesis of highly oxygenated hydrindane system. The transformation of organometallic derived from D-mannose into two diastereoisomeric bicyclo[4.3.0]nonenes with the trans geometry between both the rings was realized in a few well-defined steps. The functionalization of these synthons provided a wide range of polyhydroxylated hydrindane derivatives. The stereochemical aspects of these processes are discussed. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2009.11.008
• 作为产物：
  描述：

  (1R,2S,3R,3aR,4S,7aR)-1,2,3-tris(phenylmethoxy)-4-(phenylmethoxymethyl)-2,3,3a,4,5,7a-hexahydro-1H-indene 在 四氧化锇 、 水 、 N-甲基吗啉氧化物 作用下， 以 四氢呋喃 、 叔丁醇 为溶剂， 反应 40.0h， 以75%的产率得到
  参考文献：
  名称：

  Sugar allyltins in the synthesis of carbohydrate mimics. Study on the cis-hydroxylation of the bicyclo[4.3.0]nonenes derived from d-mannose

  摘要：

  Sugar allyltin derivatives were applied in the synthesis of highly oxygenated hydrindane system. The transformation of organometallic derived from D-mannose into two diastereoisomeric bicyclo[4.3.0]nonenes with the trans geometry between both the rings was realized in a few well-defined steps. The functionalization of these synthons provided a wide range of polyhydroxylated hydrindane derivatives. The stereochemical aspects of these processes are discussed. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2009.11.008