| 1097105-50-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 1097105-50-4
• 化学式: C₈₀H₃₂Cl₈
• 分子量: 1276.76
• InChiKey: YBLHMEPRIPAYIP-JHVLPGAXSA-N

反应信息

• 作为产物：
  描述：

  2,4-dichloro-6H-benzo[a]acephenanthrylen-7-one 在 四氯化钛 作用下， 以 邻二氯苯 为溶剂， 反应 2.0h， 生成 、 7,9,26,28,45,47-Hexachlorohexadecacyclo[40.15.1.14,12.123,31.02,41.03,21.06,11.013,18.022,40.025,30.032,37.044,49.050,58.051,56.020,60.039,59]hexaconta-1(57),2,4(60),5,7,9,11,13,15,17,19,21,23(59),24,26,28,30,32,34,36,38,40,42(58),43,45,47,49,51,53,55-triacontaene 、
  参考文献：
  名称：

  Steps toward the synthesis of a geodesic C60H12 end cap for a C3v carbon [6,6]nanotube

  摘要：

  Several shape-persistent carbon-rich nanomolecules with diameters exceeding 1.7 nm have been prepared by the aldol trimerization of 20-carbon aromatic ketones bearing chlorine atoms at Various sites. These C60H27Cl3 and C60H24Cl6 polycyclic aromatic compounds represent attractive intermediates for the synthesis of a geodesic C60H12 end cap of a C-3v carbon [6,6]nanotube. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.09.087