| 1092074-83-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 1092074-83-3
• 化学式: C₁₈H₂₉NO₄
• 分子量: 323.433
• InChiKey: SYIZTJFCDOLXKS-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 叔丁基过氧化氢 、 氯酞菁铁 (III) 、 溶剂黄146 作用下， 反应 0.05h， 以92%的产率得到
  参考文献：
  名称：

  A highly efficient biomimetic aromatization of Hantzsch-1,4-dihydropyridines with t-butylhydroperoxide, catalysed by iron(III) phthalocyanine chloride

  摘要：

  Rapid aromatization of Hantzsch-1,4-DHPswith t-butylhydroperoxide catalysed by iron(III) phthalocyanine chloride is described. The reaction proceeds smoothly at room temperature within 1-35 min and the products of high purity were isolated in excellent yields. To explain the reactivity of this catalytical system plausible mechanism have been proposed to involve formation of high-valent oxoferryl species as in cytochrome P450 itself. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmc.2008.09.004