| 1351984-91-2

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 1351984-91-2
• 化学式: C₂₈H₄₈O₅
• 分子量: 464.686
• InChiKey: SQEQHNLKZXREDA-GEDLFVTFSA-N

反应信息

• 作为产物：
  描述：

  在 碘代三甲硅烷 作用下， 以 氯仿 为溶剂， 反应 24.0h， 生成 、
  参考文献：
  名称：

  Synthesis of various secosteroidal macrocycles by ring-closing metathesis

  摘要：

  We set out to describe an efficient and versatile method for preparing secosteroidal macrocycles from cholic acid, via an oxidative ring-expansion/ring-opening sequence and a ring-closing metathesis reaction as the key steps. The characteristic H-1 and C-13 NMR spectroscopic features of the synthesized compounds are reported. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.steroids.2013.03.004

文献信息

• A ring-closing metathesis approach to secosteroidal macrocycles
  作者：Malika Ibrahim-Ouali、Jamel Zoubir、Eugénie Romero

  DOI：10.1016/j.tetlet.2011.10.108

  日期：2011.12

  An efficient synthesis of secosteroidal macrocycles has been achieved via an oxidative ring-expansion/ring-opening sequence and a ring-closing metathesis reaction as the key steps. (C) 2011 Elsevier Ltd. All rights reserved.