| 1427305-87-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并三唑类
• CAS: 1427305-87-0
• 化学式: C₂₀H₁₄Br₂N₆
• 分子量: 498.179
• InChiKey: ZZXAGHKQQWUHAR-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 苯乙炔 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 三乙胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 以80%的产率得到1,1'-((3,6-bis(phenylethynyl)-1,2-phenylene)bis(methylene))bis(1H-benzo[d][1,2,3]triazole)
  参考文献：
  名称：

  A benzimidazole-based ratiometric fluorescent sensor for Cr3+ and Fe3+ in aqueous solution

  摘要：

  A novel ratiometric fluorescent sensor bearing two benzimidazole groups has been synthesized. The sensor showed a ratiometric fluorescence response with an enhancement of the ratios of emission intensities at 443 and 378 nm from 0.17 to 3.21 for Cr3+. The ratios of emission intensities at 443 and 380 nm were enhanced from 0.40 to 2.09 for Fe3+. Fe3+ revealed significant adsorption in the UV-vis region, which can be used to discriminate Cr3+ and Fe3+. Detection limits of the method for Cr3+ and Fe3+ were 25 mu M and 2 mu M, respectively. In addition, the sensor showed good selectivity to Cr3+ and Fe3+ over other metal ions. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.02.005
• 作为产物：
  描述：

  T406石油添加剂 、 1,4-dibromo-2,3-bis(bromomethyl)benzene 在 sodium hydroxide 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  A benzimidazole-based ratiometric fluorescent sensor for Cr3+ and Fe3+ in aqueous solution

  摘要：

  A novel ratiometric fluorescent sensor bearing two benzimidazole groups has been synthesized. The sensor showed a ratiometric fluorescence response with an enhancement of the ratios of emission intensities at 443 and 378 nm from 0.17 to 3.21 for Cr3+. The ratios of emission intensities at 443 and 380 nm were enhanced from 0.40 to 2.09 for Fe3+. Fe3+ revealed significant adsorption in the UV-vis region, which can be used to discriminate Cr3+ and Fe3+. Detection limits of the method for Cr3+ and Fe3+ were 25 mu M and 2 mu M, respectively. In addition, the sensor showed good selectivity to Cr3+ and Fe3+ over other metal ions. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.02.005