2-(5-(5,5-dimethyl-1,3-dioxan-2-yl)-3-hexylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | 1586824-38-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 2-(5-(5,5-dimethyl-1,3-dioxan-2-yl)-3-hexylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS: 1586824-38-5
• 化学式: C₂₂H₃₇BO₄S
• 分子量: 408.41
• InChiKey: YYIJUYZDYGYKAS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.24
• 重原子数：
  28.0
• 可旋转键数：
  7.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  36.92
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  2-(5-(5,5-dimethyl-1,3-dioxan-2-yl)-3-hexylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 、 difluoro[6-bromo-1-[[6-bromo-3-phenyl-2H-isoindole-l-yl]methylene]-3-phenyl-1H-isoindolate-N¹,N²]boron 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 、 水 为溶剂， 以67%的产率得到difluoro[6-(3-hexyl-5-(5,5-dimethyl-[1,3]dioxane-2-yl)thiophen-2-yl)-1-[[6-(3-hexyl-5-(5,5-dimethyl-[1,3]dioxane)thiophene-2-yl)-3-phenyl-2H-isoindole-1-yl]methylene]-3-phenyl-1H-isoindolate-N¹,N²]boron
  参考文献：
  名称：

  用于染料敏化光电化学水分解的近红外有机光敏剂

  摘要：

  制备了由新型近红外BODIPY染料D1和钌水氧化催化剂C1共沉积组成的染料敏化光电化学电池（DSPEC）。pH值为7.2的设备显示出极好的法拉第制氢效率（65.8％），是三苯胺光敏剂D2和C1共吸附电池的5.4倍。

  DOI：

  10.1039/c7cc02730c

文献信息

• Boron–dibenzopyrromethene-based organic dyes for application in dye-sensitized solar cells
  作者：Yuji Kubo、Daichi Eguchi、Asaki Matsumoto、Ryuhei Nishiyabu、Hidenori Yakushiji、Koichiro Shigaki、Masayoshi Kaneko

  DOI：10.1039/c3ta15340a

  日期：——

  Novel boron–dibenzopyrromethene dyes with thienyl-cyanoacrylic acid units were synthesized and characterized for application in dye-sensitized solar cells (DSSCs).

  合成并表征了一种含有噻吩基-氰基丙烯酸单元的新型硼-二苯并呋喃染料，用于染料敏化太阳能电池（DSSCs）的应用。
• 신규 화합물 및 그것을 사용한 광전 변환 소자
  申请人：TOKYO METROPOLITAN PUBLIC UNIVERSITY CORPORATION 도쿄 메트로폴리탄 퍼블릭 유니버시티 코퍼레이션(520090332948)

  公开号：KR20150123312A

  公开（公告）日：2015-11-03

  하기 식 (1) 로 나타내는 화합물, 및 그 화합물을 기판 상에 형성된 산화물 반도체 미립자의 박막에 담지시킨 광전 변환 소자를 제공한다. (식 (1) 중, m1 은 1 내지 4 의 정수를 나타내고; M 은 반금속 원자를 나타내고; Y, Y 및 Y 은 각각 독립적으로 수소 원자 또는 방향족 잔기를 나타내고; Z 및 Z 는 각각 독립적으로 할로겐 원자를 나타내고; Ar 및 Ar 는 각각 독립적으로 방향족 고리를 나타내고; X 은 방향족 고리(들) Ar 및/또는 Ar 상의 치환기로서, 하기 식 (2), (3) 및 (4) 로 이루어지는 군에서 선택되는 하나 이상의 치환기를 나타냄: )

  This provides a photoelectric conversion device that encapsulates a compound represented by formula (1) and formed on a substrate in an oxide semiconductor nanoparticle film. In formula (1), m1 represents an integer from 1 to 4; M represents a semimetal atom; Y, Y, and Y independently represent a hydrogen atom or an aromatic residue; Z and Z independently represent a halogen atom; Ar and Ar independently represent an aromatic ring; and X represents one or more substituents selected from the group consisting of formulas (2), (3), and (4) as a substituent on the aromatic ring(s) Ar and/or Ar.