di(nitrato-O)(4,7-diphenyl-1,10-phenanthroline-N,N')palladium(II) dimethyl sulfoxide solvate | 161896-55-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: di(nitrato-O)(4,7-diphenyl-1,10-phenanthroline-N,N')palladium(II) dimethyl sulfoxide solvate
• 英文别名: dinitrato(diphenylphenanthroline)palladium(II) dimethyl sulfoxide solvate
• CAS: 161896-55-5
• 化学式: C₂H₆OS*C₂₄H₁₆N₄O₆Pd
• 分子量: 640.969
• InChiKey: SBWUPPARYHQFRQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4,7-二苯基-1,10-菲罗啉 、 硝酸 、 钯 生成 di(nitrato-O)(4,7-diphenyl-1,10-phenanthroline-N,N')palladium(II) dimethyl sulfoxide solvate
  参考文献：
  名称：

  A Dinitrato(diphenylphenanthroline)palladium(II) Complex

  摘要：

  The crystal structure of di(nitrato-O)(4,7-diphenyl-1,10-phenanthroline-N,N')palladium(II) dimethyl sulfoxide solvate, [Pd(NO3)2(C24H16N2)].C2H6OS, contains two unidentate O-bonded nitrato groups, and the bidentate 4,7-diphenyl-1,10-phenanthroline molecule in almost square-planar coordination around the Pd atom. The phenanthroline ring system is non-planar, exhibiting a bow-shaped deformation likely originating from the metal coordination. The coordinated ligand, as a consequence, exhibits geometrical deformations compared with the free ligand molecule. The crystals have channels which host the disordered solvate molecules. The geometrical results are compared with those for related compounds.

  DOI：

  10.1107/s0108270194008887