| 75675-08-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• CAS: 75675-08-0
• 化学式: C₁₆H₁₆N₃NiO*NO₃
• 分子量: 387.017
• InChiKey: SPSGWYLLTZYATQ-IBGYSACPSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶-2-甲醛 以 甲醇 为溶剂， 反应 8.0h， 生成
  参考文献：
  名称：

  C–H···O_nitrate synthon assisted molecular assembly of hydrogen bonded Ni(II) and Cu(II) complexes

  摘要：

  Two Schiff base metal complexes [Cu-SPETNNO3 (1) and Ni-SPETNNO3 (2) [SPETN=2,2-[propane,1,3-diylbis(nitrilomethyldyne)pyridyl,phenolate]] with hydrogen bonding groups have been synthesized and characterized by single-crystal X-ray diffraction. In both of the compounds nitrates occupy a crystallographic general position. In 1 the lattice nitrates are on the 2(1) screw axis while in 2 they are at the crystallographic inversion center. C-HOnitrate synthons (formed by the nitrate anions and peripheral hydrogen bonding groups of the metal complexes) are non-covalent building blocks in molecular-assembly and packing of the cationic Schiff base metal complexes (M=Ni2+, Cu2+), resulting in 2-D hydrogen bonded networks. The CuCu non-bonding contact in 1 is 3.268 angstrom while the Ni-Ni bonding distance in 2 is 3.437 angstrom.

  DOI：

  10.1080/00958972.2013.797967

文献信息

• Unsymmetrical ligand complexes of Cu II , Ni II , and Co II derived from salicylaldehyde and 1,3-propanediamine with either pyridine-2-carbaldehyde or pyrrole-2-carbaldehyde
  作者：Philip J. Burke、David R. McMillin

  DOI：10.1039/dt9800001794

  日期：——

  condensates of salicylaldehyde, propanediamine, and either pyrrole-2-carbaldehyde (L1) or pyridine-2-carbaldehyde (L2) have been isolated and combined with selected first-row transition-metal ions. The copper(II) and nickel(II) complexes of L1 have been prepared and characterized, as has the pyridine adduct of the corresponding cobalt(II) derivative. The copper(II) and nickel(II) complexes of L2 have also

  已分离出水杨醛，丙二胺和吡咯-2-甲醛（L 1）或吡啶-2-甲醛（L 2）的1：1缩合物，并将其与选定的第一行过渡金属离子结合。已经制备并表征了L 1的铜（II）和镍（II）配合物，以及相应的钴（II）衍生物的吡啶加合物。还已经表征了L 2的铜（II）和镍（II）配合物。将这些系统的光谱和化学性质与涉及类似对称席夫碱配体的配合物的光谱和化学性质进行了比较。