2-Butenoic acid, 3-methyl-, silver(1+) salt | 208391-39-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-Butenoic acid, 3-methyl-, silver(1+) salt
• CAS: 208391-39-3
• 化学式: Ag*C₅H₇O₂
• 分子量: 206.978
• InChiKey: HEOCUIIKHRXYPH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  8.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  40.13
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  2-Butenoic acid, 3-methyl-, silver(1+) salt 、 二氯-二(苯基甲基)锡烷 以 二氯甲烷 、 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Swamy, K. C. Kumara; Said, Musa A.; Nagabrahmanandachari, S., Journal of the Chemical Society, Dalton Transactions, 1998, # 10, p. 1645 - 1652

  摘要：

  DOI：

文献信息

• Synthesis and characterization of triphenylphosphine stabilized silver α,β-unsaturated carboxylate: Crystal structure of [Ag(O2CCHC(CH3)2)(PPh3)2]
  作者：Jianlin Han、Yingzhong Shen、Chunxiang Li、Yizhi Li、Yi Pan

  DOI：10.1016/j.ica.2005.10.002

  日期：2005.12

  A series of triphenylphosphine coordinated silver alpha,beta-unsaturated carboxylates of type [Ag(O2CR)(PPh3)(n): n = 1, R = CH3CH=CH (2a), (CH3)(2)C=CH (2b), CH3CH2CH=CH (2c), CH3CH2CH2CH=CH (2d), PhCH=CH (2e), CH2=CH (2f); n = 2, CH3CH=CH (3a), (CH3)(2)C=CH (3b), CH3CH2CH=CH (3c), CH3CH2CH2CH=CH (3d)] were prepared by reaction of relative silver carboxylates (1a-1f) with triphenylphosphine in chloroform. These complexes were obtained in high yields and characterized by elemental analysis, H-1 NMR, C-13 NMR, P-31 NMR and IR spectroscopy. Thermal stability of the complexes has been determined by TG analysis. The molecular structure of [Ag((O2CCH=C(CH3)(2)))(PPh3)(2)] (3b) shows that the senecioato ligand is chelated with silver atom and generate, a distorted tetrahedron. (c) 2005 Elsevier B.V. All rights reserved.
• Roy; Rath; Sudha, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2000, vol. 39, # 8, p. 838 - 842
  作者：Roy、Rath、Sudha、Chakravarty

  DOI：——

  日期：——