tert-butyl-meta-phenylenediamine | 960147-66-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tert-butyl-meta-phenylenediamine
• 英文别名: 3-Amino-2-tert-butylphenylamine；2-tert-butylbenzene-1,3-diamine
• CAS: 960147-66-4
• 化学式: C₁₀H₁₆N₂
• 分子量: 164.25
• InChiKey: KWTZFUAWBOIKBN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tert-butyl-meta-phenylenediamine 、 2-isothiocyanato-1-pyrrolidin-1-yl-ethanone 在 N,N-二异丙基乙胺 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 16.0h， 生成
  参考文献：
  名称：

  WO2007/144370

  摘要：

  公开号：
• 作为产物：
  描述：

  2-tert-butyl-3-nitroaniline 在 镍 氢气 作用下， 以 四氢呋喃 为溶剂， 反应 16.0h， 生成 tert-butyl-meta-phenylenediamine
  参考文献：
  名称：

  WO2007/144370

  摘要：

  公开号：

文献信息

• Diamino-beta-alkylstyrenes for use in preparing polyurethane/urea systems
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0272650A1

  公开（公告）日：1988-06-29

  This invention relates to a class of alkenylated toluenediamines and phenylenediamines having at least one alkenyl group ortho to an amine group. More particularly the aryldiamines are represented by the formula: wherein R is hydrogen or C₁-C₃ aliphatic, R₁ is hydrogen, R₂ is C₂-C₄, and R₁ and R₂ form an alkylene radical (CH₂)y wherein y=3 or 4, and x is one or two. The above described alkenylated aryldiamine, hereafter referred to as diamino-β-alkyl styrenes, have been found to be well suited as antioxidants and as tri-and tetra functional chain extenders in forming polyurethane/urea elastomers systems and for providing pendant unsaturation for post curing and polymerization.

  本发明涉及一类至少有一个烯基与一个胺基正交的烯化甲苯二胺和苯二胺。更具体地说，芳基二胺由式表示： 其中 R 是氢或 C₁-C₃ 脂肪族，R₁ 是氢，R₂ 是 C₂-C₄，R₁ 和 R₂ 形成亚烷基 (CH₂)y 其中 y=3 或 4，x 是 1 或 2。 已发现上述烯基芳基二胺（以下称为二氨基-β-烷基苯乙烯）非常适合用作抗氧化剂和三官能和四官能链延伸剂，以形成聚氨酯/尿素弹性体体系，并为后固化和聚合提供悬垂不饱和度。
• Alkenylated phenylenediamines for use in preparing cross linkable condensation polymers
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0290962A2

  公开（公告）日：1988-11-17

  This invention relates to a class of alkenylated phenylenediamines having at least one alkenyl group ortho to an amine group. More particularly the phenylenediamines are represented by the formula: wherein R₁, R₂, R₃, R₄ and R₅ are hydrogen, C₁₋₃ aliphatic, phenyl, halogen or alkoxy radicals, or R₂ and R₄ or R₅ are bridged via an alkylene radical -(CH₂)y- wherein y=2 to 5 and ortho to an amine group,provided that in said formula at least one of R₁, R₂, R₃, R₄ or R₅ is C₁ or greater and not more than one is phenyl, halogen or alkoxy and x is one or two. The above described alkenylated phenylenediamines have been found to be well suited as antioxidants and as tri-and tetra functional chain extenders in forming polyurethane/urea elastomers systems and for providing pendant unsaturation for post curing and polymerization.

  本发明涉及一类至少有一个烯基与胺基正交的烯化苯二胺。更具体地说，这些苯二胺由式表示： 其中 R₁、R₂、R₃、R₄ 和 R₅ 是氢、C₁₋₃ 脂肪族、苯基、卤素或烷氧基、或 R₂ 和 R₄ 或 R₅ 通过亚烷基-(CH₂)y-桥接，其中 y=2 至 5 并与胺基正交、条件是在所述式中，R₁、R₂、R₃、R₄或 R₅ 中至少有一个是 C₁或更大，且不多于一个是苯基、卤素或烷氧基，且 x 为 1 或 2。 研究发现，上述烯基化苯二胺非常适合作为抗氧化剂、三官能团和四官能团扩链 剂，用于形成聚氨酯/尿素弹性体体系，并为后固化和聚合提供悬垂不饱和度。
• Alpha, beta-unsaturated alkenyl bis-aryldiamines for use in preparing cross-linkable condensation polymer
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0311899A2

  公开（公告）日：1989-04-19

  This invention relates to a class of alkenylated dianilines having at least one alkenyl group ortho to an amine group and in conjugated relationship to the ring. More particularly the dianilines are represented by the formula: wherein R₁, R₂, and R₃, are hydrogen, C₁₋₃ aliphatic, phenyl, halogen or alkoxy radicals, or R₁ and R₂ or R₃ are bridged via an alkylene radical -(CH₂)y- wherein y=2 to 5, and provided not more than one is phenyl, halogen, or alkoxy, X is methylene, alkylene, or branched C₁-C₆ alkylene group, oxygen, sulfur, carbonyl, sulfonyl; or fluoroalkylene group, n=0 or 1, and z=0 or 1. The above described alkenylated dianilines have been found to be well suited as tri-and tetra functional chain extenders in forming polyurethane/urea elastomers systems and for providing pendant unsaturation for post curing and polymerization.

  本发明涉及一类至少有一个烯基与胺基正交并与环呈共轭关系的烯化二苯胺。更具体地说，这些二苯胺由式表示： 其中 R₁、R₂ 和 R₃ 是氢、C₁₋₃ 脂肪族、苯基、卤素或烷氧基，或 R₁ 和 R₂ 或 R₃ 通过亚烷基-(CH₂)y-桥接，其中 y=2 至 5、且不超过一个为苯基、卤素或烷氧基，X 为亚甲基、亚烷基或支链 C₁-C₆亚烷基、氧、硫、羰基、磺酰基或氟烷基，n 为亚甲基、亚烷基或支链 C₁-C₆亚烷基；或氟烷基，n=0 或 1，z=0 或 1。 研究发现，上述烯化二苯胺非常适合作为三官能团和四官能团的扩链剂，用于形成聚氨酯/尿素弹性体体系，并为后固化和聚合提供悬垂不饱和度。
• Beta, gamma-unsaturated alkenyl dianilines for use in preparing cross-linkable condensation polymers
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0311902A2

  公开（公告）日：1989-04-19

  This invention relates to a class of alkenylated dianilines having at least one alkenyl group ortho to an amine group and in conjugated relationship to the ring. More particularly the dianilines are represented by the formula: wherein R₁, R₂, R₃, R₄ and R₅ are hydrogen, C₁₋₃ aliphatic, phenyl, halogen or alkoxy radicals, or R₂ and R₄ or R₅ are bridged via an alkylene radical -(CH₂)y- wherein y=2 to 5, and provided not more than one is phenyl, halogen or alkoxy, X is methylene, alkylene, or branched C₁-C₆ alkylene group, oxygen, sulfur, carbonyl, sulfonyl; or per fluoroalkylene group, n=1 or 0, and z=0 or 1. The above described alkenylated dianilines have been found to be well suited as tri-and tetra functional chain extenders in forming polyurethane/urea elastomers systems and for providing pendant unsaturation for post curing and polymerization.

  本发明涉及一类至少有一个烯基与胺基正交并与环呈共轭关系的烯化二苯胺。更具体地说，这些二苯胺由式表示： 其中 R₁、R₂、R₃、R₄ 和 R₅ 是氢、C₁₋₃ 脂肪族、苯基、卤素或烷氧基，或 R₂ 和 R₄ 或 R₅ 通过亚烷基-(CH₂)y-桥接，其中 y=2 至 5、且不超过一个为苯基、卤素或烷氧基，X 为亚甲基、亚烷基或支链 C₁-C₆亚烷基、氧、硫、羰基、磺酰基；或每一个氟亚烃基，n=1 或 0，z=0 或 1。 研究发现，上述烯化二苯胺非常适合作为三官能团和四官能团的扩链剂，用于形成聚氨酯/尿素弹性体体系，并为后固化和聚合提供悬垂的不饱和度。
• Aromatic amine resins, their production process and thermosetting resin compositions making use of the same
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0311387A2

  公开（公告）日：1989-04-12

  Disclosed herein is an aromatic amine resin formed of a mixture of aromatic amine compounds represented by the following general formula (a): wherein A means a phenylene, alkyl-substituted phenylene, diphenylene, diphenyl ether or naphthylenyl group, R¹ denotes a halogen atom or a hydroxyl, C1-4 alkoxy or C1-5 alkyl group, ℓ stands for 1 or 2, m is an integer of 0-3, when m is 2 or 3, R¹s may be the same or different and two of R¹s may join together into a 5- to 6-membered alicyclic moiety which may optionally contain one or more side chains, and n stands for an integer of 0-300.

  本发明公开了一种芳香胺树脂，该树脂由以下通式(a)代表的芳香胺化合物混合物形成： 其中 A 表示亚苯基、烷基取代亚苯基、二苯基、二苯醚或萘基，R¹ 表示卤素原子或羟基、C1-4 烷氧基或 C1-5 烷基，ℓ 表示 1 或 2，m 为 0-3 的整数、当 m 为 2 或 3 时，R¹ 可相同或不同，两个 R¹ 可连接成 5 至 6 元脂环分子，该分子可选择包含一条或多条侧链，n 代表 0 至 300 的整数。