8-Sulfanylidene-7,9-dithiapentacyclo[13.2.1.02,14.04,12.06,10]octadeca-4,6(10),11,16-tetraene-3,13-dione | 273213-78-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 8-Sulfanylidene-7,9-dithiapentacyclo[13.2.1.02,14.04,12.06,10]octadeca-4,6(10),11,16-tetraene-3,13-dione
• CAS: 273213-78-8
• 化学式: C₁₆H₁₀O₂S₃
• 分子量: 330.452
• InChiKey: BHHGEWZQSBVICT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  117
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  8-Sulfanylidene-7,9-dithiapentacyclo[13.2.1.02,14.04,12.06,10]octadeca-4,6(10),11,16-tetraene-3,13-dione 在 三甲氧基磷 作用下， 生成 8-(3,13-dioxo-7,9-dithiapentacyclo[13.2.1.02,14.04,12.06,10]octadeca-4,6(10),11,16-tetraen-8-ylidene)-7,9-dithiapentacyclo[13.2.1.02,14.04,12.06,10]octadeca-4,6(10),11,16-tetraene-3,13-dione
  参考文献：
  名称：

  A novel array in extended tetrathiafulvalenes (TTF): the ‘H’ shape

  摘要：

  The highly extended, cro;ss-conjugated and sulfur rich rr-electron donor 2a was synthesized and characterized introducing the 'H' shape as a new approach in the tetrathiafulvalene (TTF) array. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)00107-6
• 作为产物：
  描述：

  4,5-Dimethylene-[1,3]dithiolane-2-thione 在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 四氢呋喃 为溶剂， 生成 8-Sulfanylidene-7,9-dithiapentacyclo[13.2.1.02,14.04,12.06,10]octadeca-4,6(10),11,16-tetraene-3,13-dione
  参考文献：
  名称：

  A novel array in extended tetrathiafulvalenes (TTF): the ‘H’ shape

  摘要：

  The highly extended, cro;ss-conjugated and sulfur rich rr-electron donor 2a was synthesized and characterized introducing the 'H' shape as a new approach in the tetrathiafulvalene (TTF) array. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)00107-6

文献信息

• TETRATHIAFULVALENE DERIVATIVE, AND ORGANIC FILM AND ORGANIC TRANSISTOR USING THE SAME
  申请人：Shinoda Masato

  公开号：US20120035364A1

  公开（公告）日：2012-02-09

  A tetrathiafulvalene derivative expressed by General Formula (I): General Formula (I) in General Formula (I), X represents an atom selected from a carbon atom, a sulfur atom, and a nitrogen atom, and Xs may be the same or different; provided that when X is the carbon atom or the nitrogen atom, R 1 to R 8 each represent one of a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, and a substituted or unsubstituted thioalkoxy group, and may be the same or different; and Y 1 and Y 2 each represent one of structures expressed by General Formulas (II) and (III), and may be the same or different: General Formula (II) General Formula (III).

  一种四硫富瓦烯衍生物，由通式（I）表示：在通式（I）中，X代表从碳原子、硫原子和氮原子中选择的一个原子，X可以相同或不同；但当X为碳原子或氮原子时，R1到R8分别代表氢原子、卤素原子、取代或未取代的烷基、取代或未取代的烷氧基和取代或未取代的硫代烷氧基中的一种，可以相同或不同；而Y1和Y2分别代表通式（II）和（III）所表示的结构中的一种，可以相同或不同：通式（II）通式（III）。
• A novel array in extended tetrathiafulvalenes (TTF): the ‘H’ shape
  作者：N Gautier、M Cariou、A Gorgues、P Hudhomme

  DOI：10.1016/s0040-4039(00)00107-6

  日期：2000.3

  The highly extended, cro;ss-conjugated and sulfur rich rr-electron donor 2a was synthesized and characterized introducing the 'H' shape as a new approach in the tetrathiafulvalene (TTF) array. (C) 2000 Elsevier Science Ltd. All rights reserved.