cyclopenta-1,3-diene;1,3-dimethylnaphtho[2,1-c]chromene-6-thione;diphenylphosphanylmethyl(diphenyl)phosphane;ruthenium(2+);tetrafluoroborate | 157620-29-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并呋喃类
• 英文名称: cyclopenta-1,3-diene;1,3-dimethylnaphtho[2,1-c]chromene-6-thione;diphenylphosphanylmethyl(diphenyl)phosphane;ruthenium(2+);tetrafluoroborate
• CAS: 157620-29-6
• 化学式: BF₄*C₄₉H₄₁OP₂RuS
• 分子量: 927.752
• InChiKey: RIDHYWCBQDQFBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.0
• 重原子数：
  59
• 可旋转键数：
  6
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  41.3
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  lithium aluminium deuteride 、 cyclopenta-1,3-diene;1,3-dimethylnaphtho[2,1-c]chromene-6-thione;diphenylphosphanylmethyl(diphenyl)phosphane;ruthenium(2+);tetrafluoroborate 以 四氢呋喃 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Synthesis and ring-opening reactions of cationic ruthenium biaryl thionolactone complexes

  摘要：

  The preparations of novel thionolactone-bridged configuratively labile biaryls and their [Cp(R3P)2Ru]+-complexes are described. The dynamics of helimerization of these complexes and their reactivity towards nucleophiles have been investigated. Hydride transfer reagents lead to a cleavage of the thionolactone bridge to give the corresponding thiolate complexes, apparently via intermediate exothiolactolate ruthenium complexes. A similar lactolate analog is formed upon addition of a mild S-nucleophile.

  DOI：

  10.1016/0022-328x(94)80213-0
• 作为产物：
  描述：

  、 1,3-dimethyl-benzonaphtho<1,2-d>pyran-6-thione 以 二氯甲烷 为溶剂， 以95%的产率得到cyclopenta-1,3-diene;1,3-dimethylnaphtho[2,1-c]chromene-6-thione;diphenylphosphanylmethyl(diphenyl)phosphane;ruthenium(2+);tetrafluoroborate
  参考文献：
  名称：

  Synthesis and ring-opening reactions of cationic ruthenium biaryl thionolactone complexes

  摘要：

  The preparations of novel thionolactone-bridged configuratively labile biaryls and their [Cp(R3P)2Ru]+-complexes are described. The dynamics of helimerization of these complexes and their reactivity towards nucleophiles have been investigated. Hydride transfer reagents lead to a cleavage of the thionolactone bridge to give the corresponding thiolate complexes, apparently via intermediate exothiolactolate ruthenium complexes. A similar lactolate analog is formed upon addition of a mild S-nucleophile.

  DOI：

  10.1016/0022-328x(94)80213-0