spiranthol-C | 128321-91-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: spiranthol-C
• 英文别名: 2-(2-Hydroxypropan-2-yl)-7-methoxy-2,3,4,5-tetrahydronaphtho[2,1-e][1]benzofuran-9-ol
• CAS: 128321-91-5
• 化学式: C₂₀H₂₂O₄
• 分子量: 326.392
• InChiKey: RJZSPFLLKPIMGP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  58.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  盘龙参酚A 、 间氯过氧苯甲酸 以36%的产率得到
  参考文献：
  名称：

  TEZUKA, YASAHIRO;HIRANO, LI JI. HIROYUKI;UEDA, MIDORI;NAGASHIMA, KEIKO;KI+, CHEM. AND PHARM. BULL., 38,(1990) N, C. 629-635

  摘要：

  DOI：

文献信息

• Studies on the constituents of orchidaceous plants. IX. Constituents of Spiranthes sinensis (Pers.) Ames var. amoena (M. Bieberson) Hara. (2). Structures of spiranthesol, spiranthoquinone, spiranthol-C, and spirasineol-B, new isopentenyldihydrophenanthrenes.
  作者：Yasuhiro TEZUKA、Li JI、Hiroyuki HIRANO、Midori UEDA、Keiko NAGASHIMA、Tohru KIKUCHI

  DOI：10.1248/cpb.38.629

  日期：——

  Four new dihydrophenanthrene derivatives, spiranthesol, spiranthoquinone, spiranthol-C, and spirasineol-B, were isolated from the roots of Spiranthes sinensis (PERS.) AMES var. amoena (M. BIEBERSON) HARA (Japanese name "nezibana"). The structures 1, 2, 3, and 4 were proposed for these compounds, respectively, on the basis of spectroscopic data obtained by various methods including 1H-detected heteronuclear multiple-bond multiple-quantum coherence (HMBC) spectroscopy. Chemical conversions of spiranthol-A to spiranthol-C and spiranthoquinone and of spirasineol-A-to spirasineol-B are also described.
• TEZUKA, YASAHIRO;HIRANO, LI JI. HIROYUKI;UEDA, MIDORI;NAGASHIMA, KEIKO;KI+, CHEM. AND PHARM. BULL., 38,(1990) N, C. 629-635
  作者：TEZUKA, YASAHIRO、HIRANO, LI JI. HIROYUKI、UEDA, MIDORI、NAGASHIMA, KEIKO、KI+

  DOI：——

  日期：——