2-methylene-1-(2-methoxyethyl)-3,3-dimethylindoline | 52173-92-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 2-methylene-1-(2-methoxyethyl)-3,3-dimethylindoline
• 英文别名: 1-(2-Methoxyethyl)-3,3-dimethyl-2-methylidene-2,3-dihydro-1H-indole；1-(2-methoxyethyl)-3,3-dimethyl-2-methylideneindole
• CAS: 52173-92-9
• 化学式: C₁₄H₁₉NO
• 分子量: 217.311
• InChiKey: QDCUFMACXXYLSY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-methylene-1-(2-methoxyethyl)-3,3-dimethylindoline 、 7-Hydroxy-8-nitrosonaphthalene-2-carboxylic acid 生成 1'-(2-methoxyethyl)-3',3'-dimethylspiro[benzo[f][1,4]benzoxazine-3,2'-indole]-9-carboxylic acid
  参考文献：
  名称：

  ITO, XITOSI;MAEHDA, SYUITI;MITSUXASI, KADZUO

  摘要：

  DOI：
• 作为产物：
  描述：

  2,3,3-三甲基-3H-吲哚 、 2-碘乙基甲醚 生成 2-methylene-1-(2-methoxyethyl)-3,3-dimethylindoline
  参考文献：
  名称：

  TATEHOKA, YASUO;SAGAVA, TAKATOSI

  摘要：

  DOI：

文献信息

• Photochromic compound and photochromic composition
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0350009A1

  公开（公告）日：1990-01-10

  Disclosed herein is a photochromic compound comprising a spirooxazine compound represented by the following general formula (I): wherein R¹ means an alkyl, allyl or alkoxyalkyl group, or a substituted or unsubstituted aralkyl or aryloxyalkyl group, R² and R³ individually denote a substituted or unsubstituted alkyl group, R⁴, R⁵, R⁶ and R⁷ stand individually for a hydrogen or halogen atom, or an alkyl, alkoxy, hydroxy, alkoxyalkyl, or substituted or unsubstituted amino group. A photochromic composition comprising the photochromic compound and a phenol derivative, fluorine-containing alcohol or hindered amine type light stabilizer is also disclosed.

  本发明公开了一种光致变色化合物，它包含由以下通式（I）代表的螺螨嗪化合物： 其中 R¹ 表示烷基、烯丙基或烷氧基烷基，或取代或未取代的芳烷基或芳氧基烷基，R² 和 R³ 单独表示取代或未取代的烷基，R⁴、R⁵、R⁶ 和 R⁷ 单独表示氢原子或卤素原子，或烷基、烷氧基、羟基、烷氧基烷基，或取代或未取代的氨基。此外，还公开了一种光致变色组合物，该组合物由光致变色化合物和苯酚衍生物、含氟醇或受阻胺类光稳定剂组成。
• INDOLENINE COMPOUND, NEAR INFRARED ABSORBER, AND TONER CONTAINING THE SAME
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：EP1541556A1

  公开（公告）日：2005-06-15

  A novel indolenine compound which has a high molar extinction coefficient (weight extinction coefficient) and shows considerably reduced absorption in the visible light region; an infrared absorber; and a toner containing the absorber, specifically a toner for noncontact thermal fixing, especially such as the flash fixing type, which has satisfactory fixability, is reduced in influence on the color tones of color toners, and has a high molar extinction coefficient. The indolenine compound is represented by the following general formula (1). Also provided are: a near infrared absorber comprising the indolenine compound; and a toner for copiers of the noncontact thermal fixing type, which contains the indolenine compound. In the formula (1), R represents a group represented by the following general formula (2).         -((CH2)bO)a(CH2)cOR1     (2) (wherein a is 1 or 0, b and c each independently is 1 or 2, and R1 represents C4 or lower alkyl) ; and X- represents an ion for charge neutralization.

  一种新型吲哚啉化合物，它具有较高的摩尔消光系数（重量消光系数），并且在可见光区域的吸收率大大降低；一种红外线吸收剂；以及一种含有该吸收剂的调色剂，特别是一种用于非接触式热定影的调色剂，尤其是闪光灯定影类型的调色剂，它具有令人满意的定影能力，对彩色调色剂色调的影响较小，并且具有较高的摩尔消光系数。吲哚啉化合物由以下通式（1）表示。还提供了：包含吲哚啉化合物的近红外吸收剂；以及包含吲哚啉化合物的非接触热定影型复印机墨粉。 在式 (1) 中，R 代表由以下通式 (2) 所代表的基团。 -((CH2)bO)a(CH2)cOR1 (2) (其中 a 为 1 或 0，b 和 c 各自独立地为 1 或 2，R1 代表 C4 或低级烷基）；X- 代表用于中和电荷的离子。
• FILTER AND CYANINE COMPOUND
  申请人：NIPPON KAYAKU KABUSHIKI KAISHA

  公开号：EP1806605A1

  公开（公告）日：2007-07-11

  An optical filter, which is capable of cutting-off unnecessary near infrared rays, neon light or the like, and preventing reflection of fluorescent light or the like, in plasma display panels and the like, at the same time, superior in transmittance for visible light, and also superior in heat resistance, moisture resistance, and the like of the coloring matter contained, had been desired. The present invention was made to solve such problems. The present invention relates to an optical filter comprising a salt of a cation of a cyanine coloring matter with a di(halogenoalkylsulfonyl)imide anion, preferably a cyanine compound represented by the following formula: (wherein, in the above formula (1), each of Q and Q' independently represents a benzene ring or a naphthalene ring which may have a substituent; each of R and R' independently represents an alkyl group or an alkoxyalkyl group; and L represents a linking group to form a carbocyanine), and useful as a filter for cutting-off near infrared rays, improving image characteristics for displays or the like.

  人们一直希望有一种光学滤光片，它能够在等离子显示面板等设备中切断不必要的近红外线、霓虹灯或类似光，并防止荧光灯或类似光的反射，同时对可见光的透射率更高，所含着色物质的耐热性、防潮性等也更出色。本发明就是为了解决这些问题而提出的。本发明涉及一种光学滤光片，它包含氰基着色物质阳离子与二(卤代烷基磺酰基)亚胺阴离子的盐，最好是由下式表示的氰基化合物： (其中，在上式（1）中，Q 和 Q'各自独立地代表一个苯环或一个可具有取代基的萘环；R 和 R'各自独立地代表一个烷基或一个烷氧基烷基；以及 L 代表一个连接基团以形成一个碳菁），可用作滤光片，用于切断近红外线、改善显示器的图像特性或类似用途。
• Indolenine compound, near infrared absorber, and toner containing the same
  申请人：Toriniwa Toshitaka

  公开号：US20060105257A1

  公开（公告）日：2006-05-18

  A novel indolenine compound which has a high molar extinction coefficient (weight extinction coefficient) and shows considerably reduced absorption in the visible light region; an infrared absorber; and a toner containing the absorber, specifically a toner for noncontact thermal fixing, especially such as the flash fixing type, which has satisfactory fixability, is reduced in influence on the color tones of color toners, and has a high molar extinction coefficient. The indolenine compound is represented by the following general formula (1). Also provided are: a near infrared absorber comprising the indolenine compound; and a toner for copiers of the noncontact thermal fixing type, which contains the indolenine compound. In the formula (1), R represents a group represented by the following general formula (2). —((CH 2 ) b O) a (CH 2 ) c OR 1 (2) (wherein a is 1 or 0, b and c each independently is 1 or 2, and R 1 represents C 4 or lower alkyl); and X − represents an ion for charge neutralization.

  一种新型吲哚啉化合物，它具有较高的摩尔消光系数（重量消光系数），并且在可见光区域的吸收率大大降低；一种红外线吸收剂；以及一种含有该吸收剂的调色剂，特别是一种用于非接触式热定影的调色剂，尤其是闪光灯定影类型的调色剂，它具有令人满意的定影能力，对彩色调色剂色调的影响较小，并且具有较高的摩尔消光系数。吲哚啉化合物由以下通式（1）表示。还提供了：包含吲哚啉化合物的近红外吸收剂；以及包含吲哚啉化合物的非接触热定影型复印机墨粉。 在式 (1) 中，R 代表由以下通式 (2) 所代表的基团。 -((CH 2 ) b O) a (CH 2 ) c 或 1 (2) (其中 a 为 1 或 0，b 和 c 各自独立地为 1 或 2，且 R 1 代表 C 4 或低级烷基）；以及 X - 代表用于中和电荷的离子。
• Bartnik, Romuald; Mloston, Grzegorz; Lesniak, Stanislaw, Polish Journal of Chemistry, 1991, vol. 65, # 11, p. 1957 - 1961
  作者：Bartnik, Romuald、Mloston, Grzegorz、Lesniak, Stanislaw

  DOI：——

  日期：——