1-苄基-3,4-乙烯二氧吡咯-2,5-二羧酸二乙酯 | 557795-97-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 中文名称: 1-苄基-3,4-乙烯二氧吡咯-2,5-二羧酸二乙酯
• 英文名称: 6-benzyl-2,3-dihydro-6H-[1,4]dioxino[2,3-c]pyrrole-5,7-dicarboxylic acid diethyl ester
• 英文别名: Diethyl 1-benzyl-3,4-ethylenedioxypyrrole-2,5-dicarboxylate；diethyl 6-benzyl-2,3-dihydro-[1,4]dioxino[2,3-c]pyrrole-5,7-dicarboxylate
• CAS: 557795-97-8
• 化学式: C₁₉H₂₁NO₆
• 分子量: 359.379
• InChiKey: DNSUDLABFAFLEM-UHFFFAOYSA-N

物化性质

• 熔点：
  92-110 °C(lit.)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  76
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S26
• 危险类别码：
  R36

反应信息

• 作为产物：
  描述：

  1-苄基-3,4-二羟基-1H-吡咯-2,5-二羧酸二乙酯 以 四氢呋喃 、 乙二醇 为溶剂， 生成 1-苄基-3,4-乙烯二氧吡咯-2,5-二羧酸二乙酯
  参考文献：
  名称：

  Process for preparing a compound containing a heteroaromatic group with one or more ether substituents

  摘要：

  制备一种具有杂环芳香核并用一个或多个醚基取代的杂环芳香化合物的方法，包括以下步骤：将具有所述杂环芳香核的化合物中的至少一个羟基与含有一个或多个一级或二级醇基的醇缩合，所述至少一个羟基（—OH）与所述杂环芳香核的杂原子的α-或β-位取代，可选地取代有硝基、酰胺、酯、卤素、氰基或（杂）芳基的醇，使用三芳基或三烷基膦和偶氮二氧化物的氧化还原偶在-40°C至160°C之间的温度下进行。

  公开号：

  US20030162958A1

文献信息

• A new and efficient synthetic route toward 3,4-alkylenedioxypyrrole (XDOP) derivatives via Mitsunobu chemistry
  作者：Kyukwan Zong、L. ‘Bert’ Groenendaal、John R. Reynolds

  DOI：10.1016/j.tetlet.2006.03.086

  日期：2006.5

  A new and high yielding synthetic route toward 3,4-alkylenedioxy-functionalized pyrroles has been achieved by performing tandem Mitsunobu reactions on diethyl 1-benzyl-3,4-dihydroxypyrrole-2,5-dicarboxylate using a variety of 1,2-alkanediols or 1,3-alkanediols.

  通过使用多种1,2-链烷二醇对1-苄基-3,4-二羟基吡咯-2,5-二羧酸二乙酯进行串联Mitsunobu反应，已经获得了一条新的高产合成3,4-亚烷基二氧基官能化吡咯的合成路线或1,3-链烷二醇。
• Systems, structures and materials for electrochemical device thermal management
  申请人：Global Web Horizons, LLC

  公开号：US10431858B2

  公开（公告）日：2019-10-01

  This disclosure provides casings and materials for the thermal management and protection of an electrochemical cell. The casing may also comprise a composite polymeric material for electrochemical cell thermal management, the composite polymeric material comprising a crosslinked polyether polyol phase change material configured to be in physical contact with at least a portion of an electrochemical cell.

  本公开提供了用于电化学电池热管理和保护的外壳和材料。外壳还可包括用于电化学电池热管理的复合聚合材料，复合聚合材料包括交联聚醚多元醇相变材料，该材料被配置为与电化学电池的至少一部分进行物理接触。
• PROCESS FOR PREPARING A HETEROAROMATIC COMPOUND SUBSTITUTED WITH ONE OR MORE ETHER GROUPS
  申请人：AGFA-GEVAERT

  公开号：EP1461341B1

  公开（公告）日：2010-01-27
• THERMAL MANAGEMENT FILMS CONTAINING PHASE CHANGE MATERIALS
  申请人：Outlast Technologies, LLC

  公开号：US20160223269A1

  公开（公告）日：2016-08-04

  A method is provided for manufacturing a polymeric film with thermal management capabilities. The method comprises mixing at least three compounds, wherein a first compound comprises a polymeric phase change material, a second compound comprises an additive, and a third compound comprises a molecule that, in its liquid form, acts as a solvent of the first and second compounds, and which is curable into a solid form as a polymer. Then, the method comprises applying a mixture of the first, second, and third compounds in a liquid form to a substrate, and curing the mixture into a solid state.
• SYSTEMS, STRUCTURES AND MATERIALS FOR ELECTROCHEMICAL DEVICE THERMAL MANAGEMENT
  申请人：Outlast Technologies, LLC

  公开号：US20160226114A1

  公开（公告）日：2016-08-04

  This disclosure provides casings and materials for the thermal management and protection of an electrochemical cell. The casing may also comprise a composite polymeric material for electrochemical cell thermal management, the composite polymeric material comprising a crosslinked polyether polyol phase change material configured to be in physical contact with at least a portion of an electrochemical cell.