2,3-Dimethyl-butaneperoxoic acid | 60492-50-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2,3-Dimethyl-butaneperoxoic acid
• 英文别名: 2,3-Dimethylbutaneperoxoic acid
• CAS: 60492-50-4
• 化学式: C₆H₁₂O₃
• 分子量: 132.159
• InChiKey: KGAQRBNLHLEGET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,3-Dimethyl-butaneperoxoic acid 、 乙酸酐 反应 0.17h， 以40%的产率得到acetyl 2,3-dimethylbutyryl peroxide
  参考文献：
  名称：

  Stankevich, A. I.; Zyat'kov, I. P.; Lazareva, A. M., Journal of Organic Chemistry USSR (English Translation), 1980, vol. 16, p. 1543 - 1548

  摘要：

  DOI：

文献信息

• Novel proton type beta zeolite, preparation method thereof and process for preparing phenol compound using the same
  申请人：UBE INDUSTRIES, LTD.

  公开号：US20040242938A1

  公开（公告）日：2004-12-02

  Disclosed are a proton type &bgr; zeolite in which an acid site showing a desorption peak with a range of ±100° C. with a center of 330° C. exists in a spectrum measured by the ammonia temperature programmed desorption method (NH 3 -TPD), and an amount of a strong acid site showing a desorption peak of 500° C. or higher is controlled to 2.5 &mgr;mol/g or less, a method for preparing the same, and a process for preparing a phenol compound by oxidizing a benzene compound with a peroxide in the presence of the proton type &bgr; zeolite.

  揭示了一种质子型β沸石，其中通过氨温度程序脱附法（NH3-TPD）测量的光谱中存在一个酸位显示出一个±100°C范围内的脱附峰，中心温度为330°C，并且控制强酸位显示出500°C或更高脱附峰的量为2.5μmol/g或更低，以及制备该沸石的方法和在质子型β沸石存在的情况下，在过氧化物存在下氧化苯化合物制备苯酚化合物的方法。
• STANKEVICH A. I.; ZYATKOV I. P.; LAZAREVA A. M.; ELNITSKIJ A. P., ZH. ORGAN. XIMII, 1980, 16, HO 9, 1823-1829
  作者：STANKEVICH A. I.、 ZYATKOV I. P.、 LAZAREVA A. M.、 ELNITSKIJ A. P.

  DOI：——

  日期：——
• MODIFIED HYDROGENATED POLYSILOXAZANE, COMPOSITION COMPRISING SAME FOR FORMING SILICA-BASED INSULATION LAYER, METHOD FOR PREPARING COMPOSITION FOR FORMING SILICA-BASED INSULATION LAYER, SILICA-BASED INSULATION LAYER, AND METHOD FOR PREPARING SILICA-BASED INSULATION LAYER
  申请人：CHEIL INDUSTRIES INC.

  公开号：US20150225508A1

  公开（公告）日：2015-08-13

  Disclosed is modified hydrogenated polysiloxazane prepared by reacting hydrogenated polysiloxazane with a silane compound selected from polysilane, polycyclosilane, and a silane oligomer. The modified hydrogenated polysiloxazane has a small mole ratio of nitrogen atoms relative to silicon atoms and may remarkably deteriorate a film shrinkage ratio when included in a composition for forming a silica-based insulation layer to form a silica-based insulation layer.
• US7285688B2
  申请人：——

  公开号：US7285688B2

  公开（公告）日：2007-10-23
• US9890255B2
  申请人：——

  公开号：US9890255B2

  公开（公告）日：2018-02-13