N-methyl-3,4-perylenedicarboximide | 59681-17-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N-methyl-3,4-perylenedicarboximide
• 英文别名: N-methylperylen-3,4-dicarboxylic acid imide；N-methylperylene-3,4-dicarboximide；16-methyl-16-azahexacyclo[12.6.2.12,6.011,21.018,22.010,23]tricosa-1(21),2,4,6(23),7,9,11,13,18(22),19-decaene-15,17-dione
• CAS: 59681-17-3
• 化学式: C₂₃H₁₃NO₂
• 分子量: 335.362
• InChiKey: JPWCOXCGVAYUKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-methyl-3,4:9,10-perylenetetracarboxylic monoanhydride monoimide 在 氢氧化钾 作用下， 反应 18.0h， 以74%的产率得到N-methyl-3,4-perylenedicarboximide
  参考文献：
  名称：

  苝羧酸衍生物的合成和反应。X. N-烷基-3,4-苝二甲酰亚胺的合成

  摘要：

  N-烷基-3,4-苝二甲酰亚胺（烷基=甲基、乙基、丙基、丁基、异丁基、戊基、己基和辛基）是通过 N-烷基-3,4:9,10-苝四羧酸单酐单酰亚胺的脱羧反应制备的（相同的烷基）在氢氧化钾溶液中。

  DOI：

  10.1246/bcsj.54.1575

文献信息

• Use of Rylene Derivatives as Photosensitizers in Solar Cells
  申请人：Pschirer Neil Gregory

  公开号：US20080269482A1

  公开（公告）日：2008-10-30

  Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR 1 R 2 (y1) -L-Z-R 3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR 1 R 2 ; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO 3 M; —PO 3 M 2 ; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR 5 ] 4 + ; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R 1 , R 2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R 3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R 5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.

  使用以下变量定义的莱伦衍生物I的用途： X一起 两者都是-COOM; Y是一个基团 -L-NR 1 R 2 (y1) -L-Z-R 3 (y2) 另一个基团是氢; 一起 两者都是氢; R可选择地被取代为(het)芳氧基，(het)芳基硫基; P是-NR 1 R 2 ; B是烷基; 可选择地被取代的苯基; 它们的组合; A是-COOM; -SO 3 M; -PO 3 M 2 ; D可选择地被取代为苯基，萘基，吡啶基; M是氢; 碱金属阳离子; [NR 5 ] 4 + ; L是化学键; 可选择地间接键合，可选择地被取代的(het)芳基基团; R 1 ，R 2 可选择地被取代的(环)烷基，(het)芳基; 一起可选择地被取代的环，其中包括氮原子; Z是-O-; -S-; R 3 可选择地被取代的烷基，(het)芳基; R′是氢; 可选择地被取代的(环)烷基，(het)芳基; R 5 是氢; 可选择地被取代的烷基(het)芳基; m为0, 1, 2; n, p, m=0: 0, 2, 4其中：n+p=2, 4，如果适用为0; m=1: 0, 2, 4其中：n+p=0, 2, 4; m=2: 0, 4, 6其中：n+p=0, 4, 6， 或者作为太阳能电池中的光敏剂的混合物。
• HIGHLY-FLUORESCENT AND PHOTO-STABLE CHROMOPHORES FOR ENHANCED SOLAR HARVESTING EFFICIENCY
  申请人：NITTO DENKO CORPORATION

  公开号：US20130074927A1

  公开（公告）日：2013-03-28

  The invention provides highly fluorescent materials comprising a single (n=0) or a series (n=1, 2, etc.) of benzo heterocyclic systems. The photo-stable highly luminescent chromophores are useful in various applications, including in wavelength conversion films. Wavelength conversion films have the potential to significantly enhance the solar harvesting efficiency of photovoltaic or solar cell devices.

  这项发明提供了包括单个（n=0）或一系列（n=1、2等）苯并杂环系统的高荧光材料。这种光稳定的高发光色团在各种应用中很有用，包括波长转换膜。波长转换膜有潜力显著提高光伏或太阳能电池器件的太阳能收集效率。
• LIQUID CRYSTALLINE RYLENE TETRACARBOXYLIC ACID DERIVATIVES AND USE THEREOF
  申请人：Koenemann Martin

  公开号：US20110042651A1

  公开（公告）日：2011-02-24

  The present invention relates to liquid-crystalline rylenetetracarboxylic acid derivatives, to processes for their preparation and to their use as n-type organic semiconductors for producing organic field-effect transistors and solar cells.

  本发明涉及液晶芳纶四羧酸衍生物，其制备方法以及作为n型有机半导体用于制造有机场效应晶体管和太阳能电池的用途。
• [EN] LUMINESCENT MATERIALS AND METHODS THEREOF<br/>[FR] MATÉRIAUX LUMINESCENTS ET PROCÉDÉS ASSOCIÉS
  申请人：UNIV WASHINGTON

  公开号：WO2021062035A1

  公开（公告）日：2021-04-01

  The present disclosure features a luminescent molecule, including a luminophore (e.g., a fluorescent dye); and a moiety including a heteroaryl core covalently and directly bonded to the luminophore. The luminescent molecule has an increased photoluminescence quantum yield relative to an analogous luminophore without a covalently bonded moiety including the heteroaryl core.

  本公开涉及一种发光分子，包括一种发光团（例如，荧光染料）；以及一种包括与发光团共价直接连接的杂芳基核的基团。该发光分子相对于不包括包括杂芳基核的共价连接基团的类似发光团具有增加的光致发光量子产率。
• FLUORESCENT COMPOUND AND AUTOPHAGY DETECTION REAGENT USING SAME
  申请人：DOJINDO LABORATORIES

  公开号：US20200172489A1

  公开（公告）日：2020-06-04

  A fluorescent compound or a salt thereof represented by General Formulae (I) or (II) shown below: In the General Formulae (1) and (II) shown above, R 1 and R 11 represent an alkyl group or an ω-aminoalkyl group, R 2 and R 12 represent a hydrogen atom or a alkyl group, R 3 and R 13 represent an atomic group represented by a formula —(CH 2 ) m — (m is a natural number of 10 or less), R 4 and R 14 represent an atomic group represented by a formula —CH 2 — or —NR 6 — (—NR 16 —) (R 6 and R 16 represent an alkyl group), R 5 and R 15 represent an atomic group represented by a formula —(CH 2 ) n — (n is a natural number of or less), R represents an atomic group represented by any one of formulae —NH 2 , —NHR 7 —, NR 7 R 8 and —NR 7 R 8 R 9 (—NHR 17 , —NR 17 R 18 and —N + R 17 R 18 R 19 ) (R 7 , R 8 , R 9 , R 17 , R 18 and R 19 independently represents an alkyl group, respectively) and when R 2 and R 12 are alkyl groups and R 4 (R 14 ) is an atomic group represented by the formula —NR 6 —(—NR 16 —), R 2 and R 6 and R 12 and R 16 may bind with each other to form a ring.

  下面显示的一般式（I）或（II）代表的荧光化合物或其盐：在上述的一般式（I）和（II）中，R1和R11代表烷基或ω-氨基烷基，R2和R12代表氢原子或烷基，R3和R13代表由式—（CH2）m—（m为不超过10的自然数）表示的原子团，R4和R14代表由式—CH2—或—NR6—（—NR16—）表示的原子团（R6和R16代表烷基），R5和R15代表由式—（CH2）n—（n为不超过的自然数）表示的原子团，R代表由下列任一式—NH2、—NHR7—、NR7R8和—NR7R8R9（—NHR17、—NR17R18和—N+R17R18R19）表示的原子团（R7、R8、R9、R17、R18和R19分别独立地代表烷基），当R2和R12为烷基且R4（R14）为由式—NR6—（—NR16—）表示的原子团时，R2和R6以及R12和R16可以结合形成环。