1,1,3-tris-(3-hydroxyphenyl)-3-methyl-5-hydroxyindane | 574738-25-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: 1,1,3-tris-(3-hydroxyphenyl)-3-methyl-5-hydroxyindane
• 英文别名: 1,1,3-tris(3-hydroxyphenyl)-3-methyl-2H-inden-5-ol
• CAS: 574738-25-3
• 化学式: C₂₈H₂₄O₄
• 分子量: 424.496
• InChiKey: YNFANWPMKCQWET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  32
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  80.9
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,1,3-tris-(3-methoxyphenyl)-3-methyl-5-methoxyindane 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 1,1,3-tris-(3-hydroxyphenyl)-3-methyl-5-hydroxyindane
  参考文献：
  名称：

  Conformationally constrained compounds as dendrimer cores

  摘要：

  提供了新颖的化合物以及它们在聚合物和寡聚物制备中的用途，以及这些化合物的制备方法。在某些实施例中，提供了树枝状聚合物和寡聚物，这种类型的聚合物或寡聚物具有至少四条聚合物或寡聚物有机链从单一化学核心中发出，每条链的长度基本相等且化学组成基本相同。这种化合物可以称为树状聚合物。还提供了作为核心实体在制备树状聚合物中有用的新颖化学实体。树状聚合物可以识别一个核心亚结构，聚合物/寡聚物链（“树状体”）以共价键连接并沿着径向向外以三维方式系统地分支延伸，使它们彼此的延伸程度大致相同。核心和树状体一起构成具有高度内部结构复制度的大分子，这种复制度归因于分支。

  公开号：

  US20030232932A1

文献信息

• US6703504B2
  申请人：——

  公开号：US6703504B2

  公开（公告）日：2004-03-09
• [EN] CONFORMATIONALLY RESTRICTED COMPOUNDS AS DENDRIMER CORES<br/>[FR] COMPOSES DE CONFORMATION RESTREINTE SOUS FORME DE COEURS DENDRIMERES
  申请人：SLEMON CLARKE

  公开号：WO2003064501A1

  公开（公告）日：2003-08-07

  There are provided novel chemical compounds and their uses in the preparation of polymers and oligomers, and the preparation of such compounds. In certain embodiments there are provided dendritic polymers and oligomers, of a type having at least four polymeric or oligomeric organic chains emanating from a single chemical core, each of the chains being of substantially equal length and substantially the same chemical composition. Such compounds may be referred to as dendrimers. Also provided are novel chemical entities useful as core entities in the preparation of dendrimers. Dendrimers can recognize a core substructure to which the polymeric/oligomeric chains ('dendrons') are covalently attached and from which they extend with systematic branching radially outward in a three dimensional fashion, to approximately the same extent to each other. Together, core and dendrons constitute macromolecules possessing a high degree of internal structural replication attributable to the branches.
• Conformationally constrained compounds as dendrimer cores
  申请人：——

  公开号：US20030232932A1

  公开（公告）日：2003-12-18

  There are provided novel chemical compounds and their uses in the preparation of polymers and oligomers, and the preparation of such compounds. In certain embodiments there are provided dendritic polymers and oligomers, of a type having at least four polymeric or oligomeric organic chains emanating from a single chemical core, each of the chains being of substantially equal length and substantially the same chemical composition. Such compounds may be referred to as dendrimers. Also provided are novel chemical entities useful as core entities in the preparation of dentrimers. Dendrimers can recognize a core substructure to which the polymeric/oligomeric chains (“dendrons”) are covalenty attached and from which they extend with systematic branching radially outward in a three dimensional fashion, to approximately the same extent to each other. Together, core and dendrons constitute macromolecules possessing a high degree of internal structural replication attributable to the branches.

  提供了新颖的化合物以及它们在聚合物和寡聚物制备中的用途，以及这些化合物的制备方法。在某些实施例中，提供了树枝状聚合物和寡聚物，这种类型的聚合物或寡聚物具有至少四条聚合物或寡聚物有机链从单一化学核心中发出，每条链的长度基本相等且化学组成基本相同。这种化合物可以称为树状聚合物。还提供了作为核心实体在制备树状聚合物中有用的新颖化学实体。树状聚合物可以识别一个核心亚结构，聚合物/寡聚物链（“树状体”）以共价键连接并沿着径向向外以三维方式系统地分支延伸，使它们彼此的延伸程度大致相同。核心和树状体一起构成具有高度内部结构复制度的大分子，这种复制度归因于分支。