(+/-)-2-(p-Aminophenyl)-2-phenyl-propylamin | 20105-54-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (+/-)-2-(p-Aminophenyl)-2-phenyl-propylamin
• 英文别名: 4-(1-Amino-2-phenylpropan-2-yl)aniline
• CAS: 20105-54-8
• 化学式: C₁₅H₁₈N₂
• 分子量: 226.321
• InChiKey: TVGVJEIHDKFARQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (+/-)-2-(N,N-Phthaloyl-p-amino-phenyl)-2-phenyl-propionitril 在 镍 氨 、 氢气 、 一水合肼 作用下， 以 甲醇 、 乙醇 为溶剂， 反应 2.0h， 生成 (+/-)-2-(p-Aminophenyl)-2-phenyl-propylamin
  参考文献：
  名称：

  取代的2,2-二苯乙胺的合成及其肾上腺皮质激素抑制活性。

  摘要：

  DOI：

  10.1021/jm00301a003

文献信息

• Pervaporation method of separating liquid organic compound mixture through aromatic imide polymer asymmetric membrane
  申请人：UBE INDUSTRIES, LTD.

  公开号：EP0361377A2

  公开（公告）日：1990-04-04

  A pervaporation method of separating a liquid organic compound mixture at a high speed and efficiency through an aromatic polyimide asymmetric separating membrane produced from an aromatic tetracarboxylic acid component comprising at least 70 molar% of biphenyl or diphenylether tetracarboxylic dianhydride and an aromatic diamine component comprising 85 molar% or more of an aromatic diamine having 2 to 3 benzene ring structure, or 15 molar% or more of 9,10-di(amino­phenyl)anthracene, di(aminophenoxy)diphenylsulfone, di(aminophenoxy)biphenyl or di(aminophenoxy)di­phenylalkane compounds, or a mixture of 15 to 50 molar% of an aromatic diamine having a one benzene or pyridine ring structure and 50 to 85 molar% of an aromatic diamine having a 2 to 3 benzene ring structure.

  一种通过芳香族聚酰亚胺不对称分离膜高速高效分离液体有机化合物混合物的渗透蒸发方法，该分离膜由芳香族四羧酸组分和芳香族二胺组分制成，前者包含至少70摩尔%的联苯或二苯醚四羧酸二酐，后者包含85摩尔%或以上的具有2至3个苯环结构的芳香族二胺、或 15 摩尔%或更多的 9,10-二(氨基苯基)蒽、二(氨基苯氧基)二苯砜、二(氨基苯氧基)联苯或二(氨基苯氧基)二苯基烷化合物，或 15 至 50 摩尔%具有一个苯环或吡啶环结构的芳香族二胺与 50 至 85 摩尔%具有 2 至 3 个苯环结构的芳香族二胺的混合物。
• Crystalline polypropylene resin composition and amide compounds
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0557721A2

  公开（公告）日：1993-09-01

  Disclosed are a crystalline polypropylene resin composition comprising a crystalline polyproplylene resin and a β-nucleating agent, and a method of increasing the proportion of β-form crystals in a crystalline polypropylene resin molding comprising molding the composition, the β-nucleating agent being a diamide compound.

  本发明公开了一种结晶聚丙烯树脂组合物，该组合物由结晶聚丙烯树脂和 β 成核剂组成；还公开了一种增加结晶聚丙烯树脂模塑中 β 形晶体比例的方法，该方法包括模塑该组合物，β 成核剂为二酰胺化合物。
• Porous stretched article of polypropylene-based resin and process for its preparation
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0632095A2

  公开（公告）日：1995-01-04

  Disclosed are a process for producing a porous stretched article of β-crystalline polypropylene-based resin, the process comprising the steps of crystallizing a melt of a polypropylene-based resin composition at a temperature of 15 to 140°C to form a solidified product containing β-form crystals and stretching the resulting solidified product at a temprature which is higher than 20 °C but lower than the melting point of the β-form crystals in said solidified product, the polypropylene-based resin composition comprising a polypropylene-based resin and 0.0001 to 5 parts by weight, per 100 parts by weight of the polypropylene-based resin, of at least one specific amide compound; and a porous stretched article produced by the process.

  本发明公开了一种用β-结晶聚丙烯基树脂生产多孔拉伸制品的工艺，该工艺包括以下步骤：在15至140℃的温度下使聚丙烯基树脂组合物的熔体结晶，形成含有β-结晶的固化物，并在高于20℃但低于所述固化物中β-结晶的熔点的温度下拉伸所得固化物，所述聚丙烯基树脂组合物包括聚丙烯基树脂和0.0001至5份（按每100份聚丙烯基树脂的重量计）的至少一种特定酰胺化合物；以及由该工艺生产的多孔拉伸制品。
• Polybutene-1 resin composition and a method of accelerating the crystal transformation
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0776933A1

  公开（公告）日：1997-06-04

  Disclosed are a polybutene-1 resin composition comprising a polybutene-1 resin and a Form-II to Form-I crystal transformation accelerator, and a method of accelerating the Form-II to Form-I crystal transformation comprising molding the polybutene-1 resin composition and allowing the molded product to stand at about 0 to 50 °C, the crystal transformation accelerator being an amide compound.

  本发明公开了一种聚丁烯-1 树脂组合物，该组合物由聚丁烯-1 树脂和一种从 Form-II 到 Form-I 的晶体转变促进剂组成；以及一种加速从 Form-II 到 Form-I 晶体转变的方法，该方法包括模塑聚丁烯-1 树脂组合物，并使模塑产品在约 0 至 50 °C 下静置，晶体转变促进剂是一种酰胺化合物。
• SUCCESSIVELY BIAXIAL-ORIENTED POROUS POLYPROPYLENE FILM AND PROCESS FOR PRODUCTION THEREOF
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP1369221A1

  公开（公告）日：2003-12-10

  Disclosed is a successively biaxially stretched film obtained by successive biaxial stretching method comprising extruding a melt of a β-crystal nucleating agent-containing polypropylene-based resin composition from a T-die, cooling the extruded resin on a chill roll, and stretching the resulting web sheet longitudinally and then transversely, wherein the longitudinally stretched sheet is made to have a degree of β-crystal orientation of less than 0.3 by the following method (I) and/or (II), optionally subjected to annealing treatment, and transversely stretched: method (I): melting the polypropylene-based resin composition containing needle crystals of a specific β-crystal nucleating agent at a temperature not lower than m.p. of the polypropylene-based resin and lower than dissolution temperature of the β-crystal nucleating agent in the polypropylene-based resin melt, and extruding the melt from the T-die at the same temperature, method (II): adjusting neck-in ratio during longitudinal stretching to 25 to 55%. The porous polypropylene film has good breakage resistance during manufacture, excellent thickness uniformity, high porosity and air-permeability, and is useful for battery separators.

  本发明公开了一种通过连续双轴拉伸方法获得的连续双轴拉伸薄膜，该连续双轴拉伸方法包括从T型模头挤出含β晶成核剂的聚丙烯基树脂组合物的熔体，在冷却辊上冷却挤出的树脂，然后纵向拉伸所得腹板，再横向拉伸所得腹板，其中纵向拉伸的腹板通过以下方法使β晶取向度小于0.3，可选择进行退火处理，然后进行横向拉伸： 方法 (I)：在不低于聚丙烯基树脂熔融温度和不低于聚丙烯基树脂熔体中 β 结晶成核剂溶解温度的条件下，熔化含有特定 β 结晶成核剂针状晶体的聚丙烯基树脂组合物，并在相同温度下从 T 型模 具挤出熔体、 方法 (II)：在纵向拉伸过程中将缩颈率调整为 25%至 55%。 这种多孔聚丙烯薄膜在制造过程中具有良好的抗破损性、优异的厚度均匀性、高孔隙率和透气性，可用于电池隔膜。