1,2-Diamino-phenanthren | 4061-24-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1,2-Diamino-phenanthren
• 英文别名: Diaminophenanthren；phenanthrene-1,2-diamine
• CAS: 4061-24-9
• 化学式: C₁₄H₁₂N₂
• 分子量: 208.263
• InChiKey: ARFWEVQMYYLLPJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,2-Phenanthrenchinon-dioxim 在 盐酸 、 tin(ll) chloride 作用下， 以 乙醇 为溶剂， 生成 1,2-Diamino-phenanthren
  参考文献：
  名称：

  Bogdanov,S.V.; Shibryaeva,L.S., Journal of General Chemistry of the USSR, 1961, vol. 31, p. 479 - 484

  摘要：

  DOI：

文献信息

• BIODEGRADABLE HYBRID POLYMERS USABLE IN MEDICAL TECHNOLOGY OR IN BIOLOGY, STARTING SILANES THEREFOR, AND PREPARATION PROCESS THEREFOR AND USES THEREOF
  申请人：Fraunhofer-Gesellschaft Zur Forderung der Angewandten Forschung E.V.

  公开号：US20170313726A1

  公开（公告）日：2017-11-02

  The invention relates to a silane or silane mixture obtainable by reacting a hydrolysable silane of the formula (A): SiR4 in which R is a hydrolytically condensable group or hydroxyl with a compound R*(OH)x where x is 1, 2, 3 or greater 3, where R* has a straight-chain or branched hydrocarbon skeleton which, according to the number x, is monovalent, divalent, trivalent or multivalent, and has a hydrocarbonaceous chain interrupted by at least two —C(O)O— groups, wherein there are a maximum of 8 successive carbon atoms in the individual hydrocarbon units formed by interruptions within this chain and the, or in the case of branched structures at least one, end of the hydrocarbonaceous chain at the opposite end to the sole hydroxyl group or one of the hydroxyl groups bears an organically polymerizable group, wherein the alcohol is otherwise unsubstituted or has further substituents. The invention further relates to an organically modified silica polycondensate formed as a result of hydrolytic condensation of the silane or silane mixture and optionally a subsequent organic polymerization of the organically polymerizable groups, with optional addition of an organic, at least difunctional compound to the silica polycondensate prior to the organic polymerization.

  该发明涉及一种硅烷或硅烷混合物，其可通过将具有以下式(A)的可水解硅烷与化合物R*(OH)x反应而得到：SiR4，其中R是一个可水解缩聚基团或羟基，化合物R*具有直链或支链烃骨架，根据数目x，该骨架是一价、二价、三价或多价的，并且具有至少两个—C(O)O—基团中断的烃链，其中在该链内由中断形成的各个烃单元中最多有8个连续的碳原子，或者在支链结构的情况下，至少有一个烃链的末端，与唯一的羟基或其中一个羟基相对的末端具有一个有机聚合基团，其中醇在其他方面未被取代或具有进一步的取代基。该发明还涉及一种有机改性的二氧化硅缩聚物，其是由硅烷或硅烷混合物的水解缩聚以及有机聚合基团的随后有机聚合形成的，有机聚合之前在有机聚合之前向二氧化硅缩聚物中添加有机的至少二官能化合物。
• Non-symmetric tripyrranes in the synthesis of novel macrocycles
  申请人：——

  公开号：US20030232800A1

  公开（公告）日：2003-12-18

  The present invention provides certain non-symmetric tripyrranes; that is, tripyrranes that do not contain a mirror plane of symmetry perpendicular to the plane containing the tripyrrane. Further, the invention includes texaphyrin compounds and sapphyrin compounds, as well as other polypyrrolic macrocycles, prepared using tripyrranes of Formula I as a precursor. These macrocycles are characterized by a tripyrrolic portion of the macrocyclic ring having substituents that cause the heterocycle to lack a plane of symmetry perpendicular to the plane of the macrocycle.

  本发明提供了某些非对称的三吡喃；即，不包含垂直于三吡喃所在平面的镜面对称面的三吡喃。此外，该发明包括使用式I的三吡喃作为前体制备的锗菲林化合物和蓝菲林化合物，以及其他多吡咯大环化合物。这些大环化合物的特征在于大环的三吡咯部分具有使杂环缺乏垂直于大环平面的对称面的取代基。
• [EN] "COMPOUNDS AS POTENTIAL DYE MOLECULES"<br/>[FR] COMPOSÉS UTILISÉS EN TANT QUE MOLÉCULES DE COLORANT POTENTIELLES
  申请人：LLEAF PTY LTD

  公开号：WO2019028508A1

  公开（公告）日：2019-02-14

  Disclosed herein are a series of compounds based on Formula (I). These compounds comprise perylene core which has been extended with optionally functionalised imidazoles at the 3,4;9,10 positions. The compounds of Formula (I) can be functionalised at two positions on the perylene core, such as the 1,6 or 1,7 positions. Also disclosed herein are compositions comprising said compounds, methods of forming said compounds and potential applications of said compounds, such as applying the compounds as a dye whose absorbance and fluorescence spectrum are red-shifted.

  本文披露了一系列基于化学式(I)的化合物。这些化合物包括带有可选择功能化的咪唑基团的苝芯，该苝芯在3,4;9,10位置进行了扩展。化学式(I)的化合物可以在苝芯的两个位置进行功能化，例如1,6或1,7位置。本文还披露了包含所述化合物的组合物、形成所述化合物的方法以及所述化合物的潜在应用，例如将化合物应用为吸收和荧光光谱向红移的染料。
• [EN] DYE COMPOSITION FOR USE IN PHOTOELECTRIC MATERIAL<br/>[FR] COMPOSITION DE COLORANT POUR UN USAGE DANS UN MATÉRIAU PHOTOÉLECTRIQUE
  申请人：UNIV WOLLONGONG

  公开号：WO2010088723A1

  公开（公告）日：2010-08-12

  A dye composition for use in a photoelectric material, the dye composition comprising a plurality of dyes comprising a chromophore and at least one binding group for binding with a semiconductor (preferably a metal oxide semiconductor) wherein the plurality of dyes include a first dye wherein the binding group is linked to the dye chromophore by a linker not in conjugation with the chromophore and a second dye wherein the binding group is attached by a linker in conjugation with the chromophore.

  一种用于光电材料的染料组合物，该染料组合物包括多种染料，其中包括一个色团和至少一个用于与半导体（最好是金属氧化物半导体）结合的结合基团，其中多种染料包括第一种染料，其中结合基团通过与色团不共轭的连接剂连接到染料色团上，以及第二种染料，其中结合基团通过与色团共轭的连接剂连接。
• [EN] FLUORESCENT DIKETOPYRROLOPYRROLES<br/>[FR] DICETOPYRROLOPYRROLS FLUORESCENTS
  申请人：CIBA SC HOLDING AG

  公开号：WO2004090046A1

  公开（公告）日：2004-10-21

  The present invention relates to fluorescent diketopyrrolopyrrole of the formula (I), a process for their preparation and their use for the preparation of inks, colorants, pigmented plastics for coatings, non-impact-printing material, color filters, cosmetics, polymeric ink particles, toners, as fluorescent tracers, in color changing media, in solid dye lasers and electroluminescent devices. A luminescent device comprising a composition according to the present invention is high in the efficiency of electrical energy utilisation and high in luminance.

  本发明涉及公式(I)的荧光二酮吡咯吡咯，其制备方法以及它们用于制备墨水、颜料、用于涂料的颜色塑料、非冲击打印材料、彩色滤光片、化妆品、聚合墨粒子、色调剂、作为荧光示踪剂、在颜色变化媒体中、在固体染料激光器和电致发光装置中的用途。根据本发明的组合物构成的发光装置在电能利用效率和光亮度方面表现出很高的效率。