1-Methylheptyl-t-butylperoxid | 31469-06-4

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: 1-Methylheptyl-t-butylperoxid
• 英文别名: tert-butyl 1-methyl-heptyl peroxide；2-Tert-butylperoxyoctane
• CAS: 31469-06-4
• 化学式: C₁₂H₂₆O₂
• 分子量: 202.337
• InChiKey: SUPWYOBVVUHAOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-t-Butylperoxyoctyl-quecksilber(II)acetat 在 sodium tetrahydroborate 作用下， 生成 1-Methylheptyl-t-butylperoxid
  参考文献：
  名称：

  末端烯烃的烷基过氧化汞固化；仲烷基过氧化物和β-官能取代的过氧化物的合成

  摘要：

  叔丁基氢过氧化物在乙酸汞的存在下与1-烯烃反应生成2-烷基-2-叔丁基过氧乙基汞乙酸酯[Bu t O·O·CHR·CH 2 ·Hg·OAc]；产物的碳汞键可以用硼氢化钠或卤素裂解，分别得到1-烷基乙基叔丁基过氧化物和1-烷基-2-卤代乙基叔丁基过氧化物。

  DOI：

  10.1039/c2969000815b

文献信息

• Releasing agents and resin compositions therewith
  申请人：SANYO CHEMICAL INDUSTRIES

  公开号：EP0581150A2

  公开（公告）日：1994-02-02

  The present invention provides a releasing agent obtained by reacting of an organic polysiloxane having a hydroxyl group or an epoxy group with an ethylenically unsaturated dicarboxylic acid grafted polyolefin or a reaction product of said grafted polyolefin and an active hydrogen atom-containing compound selected from the group consisting of an alcohol, an amine and an aminoalcohol. This releasing agent can be used in a resin composition for use in electrophotographic toner.

  本发明提供了一种脱模剂，它是由具有羟基或环氧基的有机聚硅氧烷与乙烯基不饱和二羧酸接枝聚烯烃或上述接枝聚烯烃与选自醇、胺和氨基醇的含活性氢原子化合物的反应产物反应而得。 这种脱模剂可用于电子照相调色剂的树脂组合物中。
• EP0581150B1
  申请人：——

  公开号：EP0581150B1

  公开（公告）日：1998-10-21
• Toner and resin composition for the toner
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP1096326B1

  公开（公告）日：2004-04-07
• HYDROPHOBIC INORGANIC FINE PARTICLE AND TONER
  申请人：Canon Kabushiki Kaisha

  公开号：EP2281778B1

  公开（公告）日：2016-08-31
• HYDROPHOBIC INORGANIC FINE PARTICLES AND TONER
  申请人：Ogawa Yoshihiro

  公开号：US20100009277A1

  公开（公告）日：2010-01-14

  Hydrophobic inorganic fine particles are provided which: does not cause melt adhesion of toner to a photosensitive member and contamination of a contact charging member; imparts excellent flowability, charging performance and durability to toner even after the toner is stored in a high-temperature, high-humidity environment over a long time period; and does not cause dripping of toner and contamination with the toner. The hydrophobic inorganic fine particles are obtained by subjecting inorganic fine particles to surface treatment with silicone oil and then with a silane compound and/or a silazane compound, or by subjecting inorganic fine particles to surface treatment with a silane compound and/or a silazane compound in the presence of silicone oil, and further subjecting the inorganic fine particles thus surface-treated to surface treatment with silicone oil.