10-bromo-2,3,6,7,14,15,18,19-octakis(dodecyloxy)trinaphtho[1,2,3,4-fgh:1',2',3',4'-pqr:1'',2'',3'',4''-za1b1]trinaphthylene | 1154757-00-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 10-bromo-2,3,6,7,14,15,18,19-octakis(dodecyloxy)trinaphtho[1,2,3,4-fgh:1',2',3',4'-pqr:1'',2'',3'',4''-za1b1]trinaphthylene
• 英文别名: 18-Bromo-4,5,11,12,25,26,32,33-octadodecoxytridecacyclo[34.6.6.02,7.08,41.09,14.015,40.016,21.022,39.023,28.029,38.030,35.037,42.043,48]octatetraconta-1(42),2,4,6,8(41),9,11,13,15(40),16(21),17,19,22(39),23,25,27,29(38),30,32,34,36,43,45,47-tetracosaene
• CAS: 1154757-00-2
• 化学式: C₁₄₄H₂₁₅BrO₈
• 分子量: 2154.19
• InChiKey: NFEWQLKKQOJTOL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  59.3
• 重原子数：
  153
• 可旋转键数：
  96
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  73.8
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  10-bromo-2,3,6,7,14,15,18,19-octakis(dodecyloxy)trinaphtho[1,2,3,4-fgh:1',2',3',4'-pqr:1'',2'',3'',4''-za1b1]trinaphthylene 在 2,2'-联吡啶 、 bis(1,5-cyclooctadiene)nickel (0) 、 1,5-环辛二烯 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 18.0h， 以83%的产率得到2,2'-bi(6,7,10,11,18,19,22,23-octakis(dodecyloxy)trinaphtho[1,2,3,4-fgh:1',2',3',4'-pqr:1'',2'',3'',4''-za1b1]trinaphthylene)
  参考文献：
  名称：

  Expeditious Synthesis of Contorted Hexabenzocoronenes

  摘要：

  Contorted hexabenzocoronenes (HBCs) have been synthesized in an expedited manner utilizing a double Barton-Kellogg olefination reaction and a subsequent Scholl cyclization. The scope of both transformations was investigated using a series of pentacene quinones and double olefin precursors. The utility,of these reactions to help create functionalized and oligomeric HBCs in a rapid manner is demonstrated.

  DOI：

  10.1021/ol9001834
• 作为产物：
  描述：

  6,13-bis{bis[3,4-bis(dodecyloxy)phenyl]methylene}-2-bromo-6,13-dihydropentacene 在 iron(III) chloride 作用下， 以 硝基甲烷 、 二氯甲烷 为溶剂， 反应 0.58h， 以98%的产率得到10-bromo-2,3,6,7,14,15,18,19-octakis(dodecyloxy)trinaphtho[1,2,3,4-fgh:1',2',3',4'-pqr:1'',2'',3'',4''-za1b1]trinaphthylene
  参考文献：
  名称：

  Expeditious Synthesis of Contorted Hexabenzocoronenes

  摘要：

  Contorted hexabenzocoronenes (HBCs) have been synthesized in an expedited manner utilizing a double Barton-Kellogg olefination reaction and a subsequent Scholl cyclization. The scope of both transformations was investigated using a series of pentacene quinones and double olefin precursors. The utility,of these reactions to help create functionalized and oligomeric HBCs in a rapid manner is demonstrated.

  DOI：

  10.1021/ol9001834

文献信息

• Expeditious Synthesis of Contorted Hexabenzocoronenes
  作者：Kyle N. Plunkett、Kamil Godula、Colin Nuckolls、Noah Tremblay、Adam C. Whalley、Shengxiong Xiao

  DOI：10.1021/ol9001834

  日期：2009.6.4

  Contorted hexabenzocoronenes (HBCs) have been synthesized in an expedited manner utilizing a double Barton-Kellogg olefination reaction and a subsequent Scholl cyclization. The scope of both transformations was investigated using a series of pentacene quinones and double olefin precursors. The utility,of these reactions to help create functionalized and oligomeric HBCs in a rapid manner is demonstrated.