3,4-dihexylpyrrole | 73405-51-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 3,4-dihexylpyrrole
• 英文别名: 3,4-Di-n-hexylpyrrol；3,4-dihexyl-1H-pyrrole
• CAS: 73405-51-3
• 化学式: C₁₆H₂₉N
• 分子量: 235.413
• InChiKey: NZCKWPBBYINXJT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  15.8
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3,4-dihexylpyrrole 、 在 sodium hydride 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 15.0h， 以59%的产率得到N,N'-[2,3,5,6-tetrakis(3,4-dihexylpyrrol-1-yl)-1,4-phenylene]bis(1,3-dihydrothieno[3,4-c]pyrrole)
  参考文献：
  名称：

  Oxidation Behavior of 1,3-Dihydrothieno[3,4-a]HPHAC

  摘要：

  通过六氟苯与 1,3-二氢噻吩并[3,4-c]吡咯和 3,4-二己基吡咯的连续 SNAr 反应，然后进行 Scholl 氧化，制备了 1,3-二氢噻吩并[3,4-a]-和 1,3,8,10-四氢二噻吩并[3,4-a;3′4′-m]-HPHACs。在室温下，用过量的碘氧化 1,3-二氢噻吩融合的 HPHAC，可定量得到相应的双(三碘)二元酸。通过除去反应过程中产生的碘化氢，在更高温度下用碘进一步脱氢氧化二ication 物，得到噻吩并[3,4-a]HPHAC 二ication 物。无法分离出噻吩并[3,4-a]HPHAC 的中性物质。

  DOI：

  10.1246/bcsj.20190022

文献信息

• PROCESSES FOR PREPARING CURED FILMS, THE RESULTING FILMS, AND PLASMA-INITIATED POLYMERIZABLE COMPOSITIONS
  申请人：FUJIFILM Corporation

  公开号：US20140170405A1

  公开（公告）日：2014-06-19

  Provided are novel plasma-assisted processes for preparing cured films having excellent heat resistance and moisture resistance. A process for preparing a cured film, comprising at least: applying a composition containing (A) at least one conductive polymer precursor on a substrate to form a coating layer, and irradiating the coating layer with a plasma to polymerize the conductive polymer precursor (A).

  提供了一种新型等离子体辅助制备固化膜的工艺，该固化膜具有优异的耐热性和耐潮性。一种制备固化膜的工艺，包括至少以下步骤：在基板上涂布含有（A）至少一种导电聚合物前体的组合物以形成涂层层，然后用等离子体照射涂层层以聚合导电聚合物前体（A）。
• Conductive polymer suspension and method for producing the same, conductive polymer material, electrolytic capacitor, and solid electrolytic capacitor and method for producing the same
  申请人：NEC TOKIN Corporation

  公开号：EP2154197A1

  公开（公告）日：2010-02-17

  The present invention provides a conductive polymer suspension for providing a conductive polymer material having a high conductivity and a method for producing the same, and in particular, a solid electrolytic capacitor having a low ESR and a method for producing the same. The conductive polymer suspension is produced by: synthesizing a conductive polymer by chemical oxidative polymerization of a monomer giving the conductive polymer by using an oxidant in a solvent containing a dopant consisting of a low-molecular organic acid or a salt thereof; purifying the conductive polymer; and mixing the purified conductive polymer and an oxidant in an aqueous solvent containing a polyacid component.

  本发明提供了一种用于提供具有高导电率的导电聚合物材料的导电聚合物悬浮液 及其生产方法，特别是具有低 ESR 的固体电解电容器及其生产方法。导电聚合物悬浮液的生产方法是：在含有由低分子有机酸或其盐组成的掺杂剂的溶剂中使用氧化剂，通过化学氧化聚合得到导电聚合物的单体，从而合成导电聚合物；纯化导电聚合物；以及将纯化的导电聚合物和氧化剂在含有聚酸成分的水性溶剂中混合。
• Conductive polymer suspension and method for producing the same, conductive polymer material, and solid electrolytic capacitor and method for producing the same
  申请人：Nec Tokin Corporation

  公开号：EP2267053A1

  公开（公告）日：2010-12-29

  An exemplary aspect of the invention provides a conductive polymer suspension for providing a conductive polymer material with high conductivity and a method for producing the same, and provides a solid electrolytic capacitor with low ESR and a method for producing the same. In an exemplary embodiment, a monomer providing a conductive polymer is subjected to chemical oxidative polymerization in a solvent comprising a dopant of an organic acid or a salt thereof, using an oxidant, to synthesize the conductive polymer; the conductive polymer is purified; the purified conductive polymer and an oxidant are mixed in an aqueous solvent comprising a polyacid; and an imidazole compound is further added to produce a conductive polymer suspension.

  本发明的一个示例性方面提供了一种用于提供具有高导电率的导电聚合物材料的导电聚合物悬浮液及其生产方法，并提供了一种具有低ESR的固体电解电容器及其生产方法。在一个示例性实施例中，使用氧化剂在包含有机酸或其盐的掺杂剂的溶剂中对提供导电聚合物的单体进行化学氧化聚合，以合成导电聚合物；纯化导电聚合物；将纯化的导电聚合物和氧化剂混合在包含多元酸的水性溶剂中；以及进一步添加咪唑化合物以生产导电聚合物悬浮液。
• CONDUCTIVE POLYMER SUSPENSION AND METHOD FOR PRODUCING THE SAME, CONDUCTIVE POLYMER MATERIAL, ELECTROLYTIC CAPACITOR, AND SOLID ELECTROLYTIC CAPACITOR AND METHOD FOR PRODUCING THE SAME
  申请人：KOBAYAKAWA Ryuta

  公开号：US20100033905A1

  公开（公告）日：2010-02-11

  The present invention provides a conductive polymer suspension for providing a conductive polymer material having a high conductivity and a method for producing the same, and in particular, a solid electrolytic capacitor having a low ESR and a method for producing the same. The conductive polymer suspension is produced by: synthesizing a conductive polymer by chemical oxidative polymerization of a monomer giving the conductive polymer by using an oxidant in a solvent containing a dopant consisting of a low-molecular organic acid or a salt thereof; purifying the conductive polymer; and mixing the purified conductive polymer and an oxidant in an aqueous solvent containing a polyacid component.
• CONDUCTIVE POLYMER SUSPENSION AND METHOD FOR PRODUCING THE SAME, CONDUCTIVE POLYMER MATERIAL, AND SOLID ELECTROLYTIC CAPACITOR AND METHOD FOR PRODUCING THE SAME
  申请人：Kobayakawa Ryuta

  公开号：US20100302714A1

  公开（公告）日：2010-12-02

  An exemplary aspect of the invention provides a conductive polymer suspension for providing a conductive polymer material with high conductivity and a method for producing the same, and provides a solid electrolytic capacitor with low ESR and a method for producing the same. In an exemplary embodiment, a monomer providing a conductive polymer is subjected to chemical oxidative polymerization in a solvent comprising a dopant of an organic acid or a salt thereof, using an oxidant, to synthesize the conductive polymer; the conductive polymer is purified; the purified conductive polymer and an oxidant are mixed in an aqueous solvent comprising a polyacid; and an imidazole compound is further added to produce a conductive polymer suspension.