3-hex-5-enyl-4-methyl-1H-indole | 1334535-15-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3-hex-5-enyl-4-methyl-1H-indole
• CAS: 1334535-15-7
• 化学式: C₁₅H₁₉N
• 分子量: 213.323
• InChiKey: CTGFEFBWHIQRQQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  15.8
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-hex-5-enyl-4-methyl-1H-indole 在 詹氏催化剂 、 邻硝基苯甲酸 、 (9R)-6'-甲氧基奎宁-9-胺三盐酸盐 作用下， 以 二氯甲烷 、 乙酸乙酯 为溶剂， 反应 6.5h， 生成
  参考文献：
  名称：

  奎宁衍生的伯胺催化的吲哚烯酮对映选择性迈克尔/曼尼希多环化反应

  摘要：

  3's人群：标题反应提供了一个带有三个手性中心的四环核（见方案； Ts = 4-甲苯磺酰基），具有出色的对映选择性和良好的非对映选择性。该反应用于有效构建（+）-克雷西丁胺骨架。

  DOI：

  10.1002/anie.201103937

文献信息

• METHODS AND SYSTEMS FOR SACCHARIFICATION OF BIOMASS
  申请人：Sweetwater Energy, Inc.

  公开号：EP2836602A1

  公开（公告）日：2015-02-18
• [EN] BIOFUEL PRODUCTION<br/>[FR] PRODUCTION DE BIOCARBURANT
  申请人：BIO ARCHITECTURE LAB INC

  公开号：WO2009046370A2

  公开（公告）日：2009-04-09

  Methods, enzymes, recombinant microorganism, and microbial systems are provided for converting polysaccharides, such as those derived from biomass, into suitable monosaccharides or oligosaccharides, as well as for converting suitable monosaccharides or oligosaccharides into commodity chemicals, such as biofuels. Commodity chemicals produced by the methods described herein are also provided. Commodity chemical enriched refinery-produced petroleum products are also provided, as well as methods for producing the same.
• [EN] MODIFIED ORGANISMS FOR IMPROVED SACCHARIFICATION OF BIOMASS<br/>[FR] ORGANISMES MODIFIÉS UTILISÉS POUR UNE MEILLEURE SACCHARIFICATION DE LA BIOMASSE
  申请人：QTEROS INC

  公开号：WO2011028623A2

  公开（公告）日：2011-03-10

  Modified organisms are provided for enhancing saccharification of biomass. Microorganisms are modified to enhance activity of one or more cellulase proteins and/or modified to express at least one expansin or swollenin polypeptide.
• [EN] REDIRECTED BIOENERGETICS IN RECOMBINANT CELLULOLYTIC CLOSTRIDIUM MICROORGANISMS<br/>[FR] ÉLÉMENTS BIOGÉNÉTIQUES REDIRIGÉS DANS DES MICRO-ORGANISMES CELLULOLYTIQUES DE CLOSTRIDIUM RECOMBINANTS
  申请人：QTEROS INC

  公开号：WO2011137401A2

  公开（公告）日：2011-11-03

  Compositions and methods are provided for redirecting metabolic solventogenesis pathways to enhance the product yield from fermentation of biomass. Clostridium microorganism pathways are modified to extend the growth phase and prevent inhibition of acetaldehyde while bypassing the synthesis of acetyl CoA.
• [EN] BIOCATALYSTS SYNTHESIZING DEREGULATED CELLULASES<br/>[FR] BIOCATALYSEURS SYNTHÉTISANT DES CELLULASES DÉRÉGULÉES
  申请人：QTEROS INC

  公开号：WO2012103385A2

  公开（公告）日：2012-08-02

  Provided are isolated novel Clostridium phytofermentans biocatalysts with deregulated cellulase activity that produce high yields of products. Further provided are methods of using the biocatalysts to degrade organic material and for use in industrial processes.