trans-1-(9-phenanthryl)-2-(3-pyridyl)-ethylene | 87875-29-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: trans-1-(9-phenanthryl)-2-(3-pyridyl)-ethylene
• 英文别名: trans-9-phenanthryl-3-pyridyl-ethylene；3-(2-phenanthren-9-yl-vinyl)pyridine；3-[(E)-2-phenanthren-9-ylethenyl]pyridine
• CAS: 87875-29-4
• 化学式: C₂₁H₁₅N
• 分子量: 281.357
• InChiKey: DKNQRCXLSXWYOT-VAWYXSNFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  trans-1-(9-phenanthryl)-2-(3-pyridyl)-ethylene 以 正己烷 为溶剂， 生成 cis-9-phenanthryl-3-pyridyl-ethylene
  参考文献：
  名称：

  Aloisi, Gian Gaetano; Mazzucato, Ugo; Spalletti, Anna, Zeitschrift fur physikalische Chemie (Neue Folge), 1982, vol. 133, p. 107 - 118

  摘要：

  DOI：
• 作为产物：
  描述：

  cis-9-phenanthryl-3-pyridyl-ethylene 以 水 、 乙腈 为溶剂， 生成 trans-1-(9-phenanthryl)-2-(3-pyridyl)-ethylene
  参考文献：
  名称：

  Spalletti, Anna; Mazzucato, Ugo; Aloisi, Gian Gaetano, Zeitschrift für Physikalische Chemie, 1983, vol. 138, p. 199 - 206

  摘要：

  DOI：

文献信息

• METHOD FOR ELECTROCHEMICAL DETECTION OF SEQUENCES OF NUCLEIC ACIDS
  申请人：Universidad Autónoma de Madrid

  公开号：EP2168949A1

  公开（公告）日：2010-03-31

  The present invention relates to a new compound derived from ruthenium, of formula (I), known as pentaamin ruthenium [3-(2-phenanthren-9-yl-vinyl)pyridine] complex, as well as the use thereof as an electrochemical indicator of hybridization in a method for the detection of hybridization between nucleic acid sequences, for the quantification of said sequences, as well as the detection of the presence of a mismatched base and the position thereof within a nucleic acid sequence.

  本发明涉及一种从钌（式 (I)）衍生的新化合物，称为五胺钌[3-(2-菲-9-基-乙烯基)吡啶]络合物，以及将其用作核酸序列间杂交检测方法中的杂交电化学指示剂，用于对所述序列进行定量，以及检测核酸序列中是否存在错配碱基及其位置。
• METHOD FOR ELECTROCHEMICAL DETECTION OF NUCLEIC ACID SEQUENCES
  申请人：Lorenzo Abad Encarnacion

  公开号：US20100236942A1

  公开（公告）日：2010-09-23

  The present invention relates to a new compound derived from ruthenium, of formula (I), known as pentaamin ruthenium [3-(2-phenanthren-9-yl-vinyl)pyridine] complex, as well as the use thereof as an electrochemical indicator of hybridization in a method for the detection of hybridization between nucleic acid sequences, for the quantification of said sequences, as well as the detection of the presence of a mismatched base and the position thereof within a nucleic acid sequence.