2-(6-methacryloyloxy-1,4-dioxahexyl)-1,3-bis(4-pyridylethynyl)benzene | 934550-09-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-(6-methacryloyloxy-1,4-dioxahexyl)-1,3-bis(4-pyridylethynyl)benzene
• 英文别名: 2-[2-[2,6-Bis(2-pyridin-4-ylethynyl)phenoxy]ethoxy]ethyl 2-methylprop-2-enoate
• CAS: 934550-09-1
• 化学式: C₂₈H₂₄N₂O₄
• 分子量: 452.51
• InChiKey: UZNRFWZYFKYXIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  34
• 可旋转键数：
  13
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  70.5
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-(6-methacryloyloxy-1,4-dioxahexyl)-1,3-bis(4-pyridylethynyl)benzene 、 palladium (II) nitrate 以 氘代二甲亚砜 为溶剂， 生成
  参考文献：
  名称：

  纳米级的壳分子，限制了内膜聚合单元。

  摘要：

  DOI：

  10.1002/anie.200603561
• 作为产物：
  描述：

  1,3-dibromo-2-(6-methacryloyloxy-1,4-dioxahexyl)benzene 、 4-ethynylpyridine hydrochloride 在 copper(l) iodide 、 二(氰基苯)二氯化钯 三叔丁基膦 、 4-甲氧基苯酚 、 二异丙胺 作用下， 以 1,4-二氧六环 、 正己烷 为溶剂， 反应 22.0h， 以87%的产率得到2-(6-methacryloyloxy-1,4-dioxahexyl)-1,3-bis(4-pyridylethynyl)benzene
  参考文献：
  名称：

  纳米级的壳分子，限制了内膜聚合单元。

  摘要：

  DOI：

  10.1002/anie.200603561

文献信息

• Polymerizable Spherical Transition Metal Complex, Spherical Transition Metal Complex, and Production Method Thereof
  申请人：Fujita Makoto

  公开号：US20090318663A1

  公开（公告）日：2009-12-24

  A polymerizable spherical transition metal complex is provided which has a hollow shell which is formed from transition metal atoms and bidentate organic ligands, the bidentate organic ligands having a substituent having a polymerizable group moiety at an end thereof, and the substituents being oriented towards the interior of the hollow shell. A spherical transition metal complex in which, in the hollow shell of the polymerizable spherical transition metal complex, the polymerizable groups are polymerized, and a production method thereof are also provided. The polymerizable spherical transition metal complex which is a spherical transition metal complex having a hollow shell, is characterized in that the hollow shell is formed from a transition metal atoms (wherein a represents an integer of 6 to 60), and 2a bidentate organic ligands, the bidentate organic ligands have a substituent having at least one or more polymerizable group moieties at an end thereof, and the substituents are oriented towards an interior of the hollow shell. The spherical transition metal complex is characterized in that the polymerizable groups are polymerized in the hollow shell of the polymerizable spherical transition metal complex. The production method thereof is also provided.