2-N,2-N,7-N,7-N-tetraphenylphenanthrene-2,7-diamine | 1264757-03-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-N,2-N,7-N,7-N-tetraphenylphenanthrene-2,7-diamine
• CAS: 1264757-03-0
• 化学式: C₃₈H₂₈N₂
• 分子量: 512.654
• InChiKey: ADIXRURROKNHGE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  40
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-(二苯基氨基)苯硼酸频那醇酯 在 吡啶 、 4-二甲氨基吡啶 、 四(三苯基膦)钯 、 四丁基氟化铵 、 palladium diacetate 、 三溴化硼 、 sodium carbonate 、 R-(+)-1,1'-联萘-2,2'-双二苯膦 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 乙醇 、 二氯甲烷 、 水 、 1,2-二氯乙烷 、 甲苯 为溶剂， 反应 72.0h， 生成 2-N,2-N,7-N,7-N-tetraphenylphenanthrene-2,7-diamine
  参考文献：
  名称：

  Ph₂N-Susbtituted Ethylene-Bridged p-Phenylene Oligomers: Synthesis and Photophysical and Redox Properties

  摘要：

  For a series of p-phenylene-based oligomers terminated with two triphenylamines, their absorption, photoluminescence, and band gaps show a pattern of extensive pi-conjugation with increasing array size. Oligomers with large central arrays have greater quantum yields than their small analogues. Cyclic voltammetric (CV) measurements indicated two-step oxidations of the two diphenylamino groups for compounds 1-5 and one-step oxidations for the two amines of large oligomers 6 and 7.

  DOI：

  10.1021/jo1020163

文献信息

• ORGANIC LIGHT-EMITTING DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：EP3051604A1

  公开（公告）日：2016-08-03

  An organic light-emitting device includes: a first electrode; a second electrode opposite the first electrode; an emission layer between the first electrode and the second electrode; a hole transport region between the first electrode and the emission layer; and an electron transport region between the emission layer and the second electrode, the electron transport region including an electron control layer, wherein the hole transport region includes at least one compound selected from a first compound represented by Formula 1 and a second compound represented by Formula 2, and the electron control layer includes a third compound represented by Formula 3:

  一种有机发光器件包括：第一电极；与第一电极相对的第二电极；位于第一电极和第二电极之间的发射层；位于第一电极和发射层之间的空穴传输区域；以及位于发射层和第二电极之间的电子传输区域，电子传输区域包括电子控制层，其中空穴传输区域包括至少一种选自式 1 所代表的第一化合物和式 2 所代表的第二化合物的化合物，电子控制层包括式 3 所代表的第三化合物：
• Polymeric compound and polymeric electroluminescence element using the same
  申请人：Fukushima Daisuke

  公开号：US20100176377A1

  公开（公告）日：2010-07-15

  A polymer compound comprising at least one of repeating units of the following formula (1) and at least one of repeating units selected from the following formulae (2) and (3). (Ar 1 represents an aryl group or monovalent aromatic heterocyclic group, Ar 2 represents an arylene group or divalent aromatic heterocyclic group, and Z represents a divalent aromatic group having a condensed ring structure.) (a ring A and a ring B represent an aromatic hydrocarbon ring, at least one of the ring A and the ring B is an aromatic hydrocarbon ring having two or more benzene rings condensed, and Rw and Rx represent each independently a hydrogen atom, alkyl group or the like.) (a ring C and a ring D represent an aromatic ring, Y represents an oxygen atom, sulfur atom or —O—C(R K ) 2 —, and R K represents a hydrogen atom, alkyl group or the like.).
• Ph₂N-Susbtituted Ethylene-Bridged <i>p</i>-Phenylene Oligomers: Synthesis and Photophysical and Redox Properties
  作者：Balagopal Shainamma Shaibu、Sheng-Hsun Lin、Chi-Yen Lin、Ken-Tsung Wong、Rai-Shung Liu

  DOI：10.1021/jo1020163

  日期：2011.2.18

  For a series of p-phenylene-based oligomers terminated with two triphenylamines, their absorption, photoluminescence, and band gaps show a pattern of extensive pi-conjugation with increasing array size. Oligomers with large central arrays have greater quantum yields than their small analogues. Cyclic voltammetric (CV) measurements indicated two-step oxidations of the two diphenylamino groups for compounds 1-5 and one-step oxidations for the two amines of large oligomers 6 and 7.