| 1416051-29-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• CAS: 1416051-29-0
• 化学式: C₁₁H₁₈O
• 分子量: 166.263
• InChiKey: LQXXOLMINOMDNF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  在 iron p-toluenesulfonate 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 10.0h， 以89%的产率得到2-(cyclopent-1-en-1-ylmethyl)tetrahydro-2H-pyran
  参考文献：
  名称：

  Chemoselective Activities of Fe(III) Catalysts in the Hydrofunctionalization of Allenes

  摘要：

  A range of tetrahydropyrans and piperidines were produced by Fe(III)-catalyzed intramolecular hydroalkoxylation and hydroamination reactions of allenes. Various Fe catalysts with different counterions were tested. Their activities toward allene and alkene activation depended sensitively on their counterion and reaction conditions. Mechanistic study of the reaction intermediates found a new reaction pattern involving the Fe catalysts and diene substrates.

  DOI：

  10.1021/ol303021d

文献信息

• Chemoselective Activities of Fe(III) Catalysts in the Hydrofunctionalization of Allenes
  作者：Min Seok Jung、Won Sun Kim、Ye Ho Shin、Ha Jeong Jin、Young Sam Kim、Eun Joo Kang

  DOI：10.1021/ol303021d

  日期：2012.12.21

  A range of tetrahydropyrans and piperidines were produced by Fe(III)-catalyzed intramolecular hydroalkoxylation and hydroamination reactions of allenes. Various Fe catalysts with different counterions were tested. Their activities toward allene and alkene activation depended sensitively on their counterion and reaction conditions. Mechanistic study of the reaction intermediates found a new reaction pattern involving the Fe catalysts and diene substrates.