(E)-5-tetradecenal | 174155-52-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (E)-5-tetradecenal
• 英文别名: 5-Tetradecenal；(E)-tetradec-5-enal
• CAS: 174155-52-3
• 化学式: C₁₄H₂₆O
• 分子量: 210.36
• InChiKey: HJCIVWWOKIXNOJ-MDZDMXLPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (E)-5-tetradecenal 在 重铬酸吡啶 、 lithium aluminium deuteride 作用下， 生成 (Z)-5-[1-2H1]tetradecenal
  参考文献：
  名称：

  Cycloalkene Budding:  A Unique Rearrangement Observed in the Mass Spectra of N,N-Dimethylhydrazones of Unsaturated Aldehydes

  摘要：

  DOI：

  10.1021/jo971960f
• 作为产物：
  描述：

  (E)-5-tetradecenol 在 重铬酸吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 (E)-5-tetradecenal
  参考文献：
  名称：

  摘要：

  The Iepidopteran genus Saturnia has three representatives in North America, S. walterorum, S.mendocino, and S. albofasciata. (E4,Z9)-Tetradecadienal (E4,Z9-14 : Ald) was identified as a sex pheromone component for all three species by combinations of coupled gas chromatography-electroantennogram detection (GC-EAD), GC-mass spectrometry (MS), and field trials. In field trials, all three species were strongly attracted to (E4,Z9-14 : Ald) as a single component. Small amounts of (Z)-9-tetradecenal (Z9-14: Ald) also were found in extracts of all three species, but blends of this compound with E4,Z9-14 : Aid were no more attractive to male moths than E4,Z9-14 : Aid alone. Extracts of pheromone glands of female S. walterorum occasionally contained a third, trace compound eliciting responses from male antennae in GC-EAD experiments, but this compound was not identified. It is suggested that the three species can use the same, single component as a sex attractant because the flight period of S. albofasciata (Fall) is different than that of the other two species (spring), whereas the geographic distributions of S. mendocino and S. walterorum overlap over only small portions of their ranges. Furthermore, the latter two species readily hybridize, so there may be minimal fitness cost to cross-attraction.

  DOI：

  10.1023/a:1010310204552

文献信息

• Renewably derived aldehydes and methods of making and using the same
  申请人：Elevance Renewable Sciences, Inc.

  公开号：US10472588B2

  公开（公告）日：2019-11-12

  Methods for making specialty chemical products and chemical intermediates using hydroformylation are generally disclosed. Further, compositions and compounds formed using such methods are also disclosed. In some embodiments, methods are disclosed for refining a renewably sourced material, such as a natural oil, to form compositions, which can be further reacted employing the methods disclosed herein to form certain specialty chemical products or chemical intermediates.

  利用加氢甲酰化制造特种化学产品和化学中间体的方法已普遍公开。此外，还公开了使用此类方法形成的组合物和化合物。在某些实施例中，公开了提炼可再生材料（如天然油）以形成组合物的方法，这些组合物可通过本文公开的方法进一步反应以形成某些特种化学产品或化学中间体。
• Disproportionation of functional olefins
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0099572B1

  公开（公告）日：1989-09-06
• PHEROMONE DISPENSER
  申请人：Harmsen Sven

  公开号：US20110266361A1

  公开（公告）日：2011-11-03

  The present invention relates to a pheromone dispenser, filled with pheromone or a pheromone-comprising liquid and comprising (a) a deep-drawn plastic film made of a thermoplastic film material and featuring at least one dish-shaped zone for receiving a pheromone, and a planar plastic film made of a thermoplastic film material and which is connected with the deep-drawn plastic film, the planar plastic film together with the at least one dish-shaped zone of the deep-drawn plastic film forming a durably sealed chamber which comprises the pheromone or the pheromone-comprising liquid, and (c) a recess in the zone of the interconnected plastic films, the planar plastic film being permeable to the pheromone. The invention also relates to a process for producing such a pheromone dispenser.
• Renewably Derived Aldehydes and Methods of Making and Using the Same
  申请人：Elevance Renewable Sciences, Inc.

  公开号：US20150252290A1

  公开（公告）日：2015-09-10

  Methods for making specialty chemical products and chemical intermediates using hydroformylation are generally disclosed. Further, compositions and compounds formed using such methods are also disclosed. In some embodiments, methods are disclosed for refining a renewably sourced material, such as a natural oil, to form compositions, which can be further reacted employing the methods disclosed herein to form certain specialty chemical products or chemical intermediates.
• AIR FRESHENING PRODUCT
  申请人：The Procter & Gamble Company

  公开号：US20210106710A1

  公开（公告）日：2021-04-15

  An antibacterial air freshening product for an interior environment. The product includes a container containing 1 ml to 50 ml of a freshening composition in fluid communication with a membrane. The composition is substantially free of a surfactant and has from 0.5% to 20% of a volatile aldehyde mixture, by weight of the composition. The volatile aldehyde mixture includes a C5 to C8 unbranched unsubstituted linear alkenal and a C9 to C14 unbranched unsubstituted linear alkenal. A weight ratio of the C5 to C8 unbranched unsubstituted linear alkenal to the C9 to C14 unbranched unsubstituted linear alkenal is from 3:1 to 1:3.