2-Methoxycyclohexyl acetate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-Methoxycyclohexyl acetate
• 英文别名: (2-methoxycyclohexyl) acetate
• 化学式: C₉H₁₆O₃
• mdl: MFCD00027366
• 分子量: 172.22
• InChiKey: LSOLQEYCFGSFGP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.888
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-Methoxycyclohexyl acetate 以45%的产率得到
  参考文献：
  名称：

  LAUMEN, KURT;BREITGOFF, DETLEF;SEEMAYER, ROBERT;SCHNEIDER, MANFRED P., J. CHEM. SOC. CHEM. COMMUN.,(1989) N, C. 148-150

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING LINEAR AND/OR CYCLIC CARBONATE ESTERS
  申请人：Bayer MaterialScience AG

  公开号：US20150203467A1

  公开（公告）日：2015-07-23

  The present invention relates to a method for producing linear and/or cyclic carbonate esters, involving the step of reacting an epoxide with carbon dioxide in the presence of a catalyser. The invention further relates to the use of special catalysers for reacting epoxides with carbon dioxide, special catalysers and special reaction products. The catalyser comprises a complex of a metal M or M-A with a ligand L, the metal M being present in an oxidation state of >=0, A standing for halide, carboxylate, phenolate, sulfonate, phosphonate, alkyl, alkoxy or amido, and the ligand L having the subsequent structure (Ia) or (Ib), wherein one or both of the OH groups shown in (Ia) and/or (Ib) can also be deprotonated.

  本发明涉及一种生产线性和/或环状碳酸酯的方法，包括在催化剂存在下将环氧化物与二氧化碳反应的步骤。该发明还涉及使用特殊催化剂来使环氧化物与二氧化碳反应，特殊催化剂和特殊反应产物。该催化剂包括金属M或M-A与配体L的复合物，金属M以>=0的氧化态存在，A代表卤素、羧酸盐、酚酚盐、磺酸盐、膦酸盐、烷基、烷氧基或氨基，配体L具有下述结构(Ia)或(Ib)，其中(Ia)和/或(Ib)中显示的一个或两个OH基团也可以被去质子化。
• METAL CATALYSTS FOR SELECTIVE FORMATION OF CYCLIC CARBONATES, PROCESS FOR PREPARING CYCLIC CARBONATE USING THE SAME AND USE OF CYCLIC CARBONATE
  申请人：KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

  公开号：US20170081302A1

  公开（公告）日：2017-03-23

  Provided are a novel metal catalyst for preparing cyclic carbonate, and a method for preparing cyclic carbonate using the same, and more particularly, a method for selectively preparing cyclic carbonate in a high yield and at a higher conversion rate as compared to the existing catalysts, using the metal complex including a ligand represented by Chemical Formula 1 below and a trivalent metal in Group 8 or Group 13 as a catalyst and using various structures of epoxide compounds and carbon dioxide as raw materials. In addition, provided are the prepared cyclic carbonate, and an electrolyte including the same: in Chemical Formula 1, R 1 is hydrogen, (C1-C20)alkyl or halogen; R 2 is hydrogen, (C1-C20)alkyl, (C1-C20)alkoxy, halogen or nitro.

  提供了一种用于制备环状碳酸酯的新型金属催化剂，以及使用该催化剂制备环状碳酸酯的方法，更具体地说，使用包括化学式1所示的配体和第8族或第13族的三价金属作为催化剂，并利用环氧化合物和二氧化碳等原料，以高产率和更高转化率选择性制备环状碳酸酯的方法，相较于现有催化剂。此外，提供了制备的环状碳酸酯，以及包括该碳酸酯的电解质：在化学式1中，R1为氢、(C1-C20)烷基或卤素；R2为氢、(C1-C20)烷基、(C1-C20)烷氧基、卤素或硝基。
• Basavaiah Deevi, Krishna Peddinti Rama, Tetrahedron, 50 (1994) N 35, S 10521-10530
  作者：Basavaiah Deevi, Krishna Peddinti Rama

  DOI：——

  日期：——
• PROCESS FOR PREPARING POLYCARBONATES BY POLYMERIZATION OF FIVE-MEMBERED-RING CYCLIC CARBONATES
  申请人：Total Research & Technology Feluy

  公开号：EP2992032B1

  公开（公告）日：2017-12-06
• Process for Preparing Polycarbonates by Polymerization of Five-Membered-Ring Cyclic Carbonates
  申请人：TOTAL RESEARCH & TECHNOLOGY FELUY

  公开号：US20160068630A1

  公开（公告）日：2016-03-10

  A process for the preparation of polycarbonates may include ring-opening polymerization of five-membered cyclic carbonates in the presence of a catalyst; a compound of formula (I), stereoisomers, racemics, or mixtures thereof; and optionally cyclic esters, stereoisomers, racemics, or mixtures thereof. Formula (I) is: Each dotted bond “a” and “b” is a solid bond, a wedged bond, or a hashed wedged bond. R 21 and R 22 , taken together with the carbon atoms 4 and 5 of the cyclic carbonate, may form a ring. The ring may be a C 5-9 cycloalkylene, C 5-9 cycloalkenylene, or C 6-12 arylene. The ring may optionally be substituted with substituents including halo, hydroxyl, C 1-6 alkyl, haloC 1-6 alkyl, C 1-6 alkoxy, haloC 1-6 alkoxy, C 6-12 aryl, C 1-6 alkylthio, carboxyl, C 1-6 alkoxycarbonyl, C 1-6 alkylcarbonyloxy, amino; or mono- or di-C 1-6 alkylamino.