Al(III) triflate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: Al(III) triflate
• 英文别名: bis(trifluoromethylsulfonyloxy)alumanyl trifluoromethanesulfonate
• 化学式: C₃AlF₉O₉S₃
• 分子量: 474.2
• InChiKey: FKOASGGZYSYPBI-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -0.23
• 重原子数：
  25
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  197
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  苯 、 乙烯 、 Al(III) triflate 生成 乙基苯
  参考文献：
  名称：

  OLAH, GEORGE A.

  摘要：

  DOI：
• 作为产物：
  描述：

  三氟甲磺酸 、 三溴化铝 生成 Al(III) triflate
  参考文献：
  名称：

  OLAH, GEORGE A.

  摘要：

  DOI：

文献信息

• Boron, aluminum and gallium perfluoro alkanesulfonate and resinsulfonate
  申请人：——

  公开号：US04721559A1

  公开（公告）日：1988-01-26

  Boron, aluminum and gallium C.sub.1 -C.sub.18 perfluoroalkanesulfonates (CF.sub.3 (CF.sub.2).sub.n SO.sub.3).sub.3 M (M=B, A1, Ga; n=0-17) as well as perfluororesin sulfonates such as Nafionates are new, highly effective Friedel-Crafts catalysts. In contrast to volatile aluminum and boron trihalides, the Group III-B perfluoroalkanesulfonates are generally of low or no volatility and, except for boron triflate and some of its homologs, only sparingly soluble incommon organic solvents. This allows their use as solid or supported Friedel-Crafts catalysts of wide utility and scope in continuous heterogenous catalytic processes. At the same time, boron triflate and related lower perfluoroalkanesulfonates are particularly efficient soluble catalysts in solution reactions.

  硼、铝和镓的C.sub.1-C.sub.18全氟烷基磺酸盐（CF.sub.3（CF.sub.2）.sub.nSO.sub.3）.sub.3M（M=B，A1，Ga；n=0-17），以及全氟树脂磺酸盐如Nafionates是新的、高效的费托合成催化剂。与挥发性的铝和硼三卤化物不同，III-B族全氟烷基磺酸盐通常具有低或无挥发性，并且除了硼三氟酸盐及其一些同系物外，只在常见有机溶剂中微溶。这使它们能够作为广泛应用于连续杂质催化过程中的固体或支撑费托合成催化剂。同时，硼三氟酸盐和相关的较低全氟烷基磺酸盐在溶液反应中特别有效。
• Method for inhibiting perspiration
  申请人：——

  公开号：US04219540A1

  公开（公告）日：1980-08-26

  Method of inhibiting perspiration with antiperspirant compositions containing trivalent metal salts of trifluoromethanesulfonic acid of the formula: Me (CF.sub.3 SO.sub.3).sub.3 wherein Me is aluminum, lanthanum, cerium or didymium obtained by reacting trifluoromethanesulfonic acid with the appropriate metal carbonate or sulfide or by the exchange reaction of the appropriate metal sulfate with barium trifluoromethanesulfonate.

  使用含有三氟甲磺酸三价金属盐的抗汗剂组合物来抑制汗液的方法，其中该三价金属盐的化学式为：Me（CF3SO3）3，其中Me为铝、镧、铈或镝，该组合物可通过将三氟甲磺酸与适当的金属碳酸盐或硫化物反应或通过适当的金属硫酸盐与三氟甲磺酸钡进行交换反应来获得。
• Process for the preparation of addition products of epoxides and
  申请人：BP Chimie Societe Anonyme

  公开号：US04543430A1

  公开（公告）日：1985-09-24

  Process for the preparation of addition products of epoxides and hydroxylated compounds, characterized by the fact that it comprises the reaction of an epoxide and a hydroxylated compound in the homogeneous liquid phase, in the presence, as catalyst, of a salt of trifluoromethanesulphonic acid.

  制备环氧化物和羟基化合物加成产物的过程，其特点在于它包括在均相液相中反应环氧化物和羟基化合物，催化剂为三氟甲磺酸盐。
• Boron aluminum and gallium perfluoro alkanesulfonate and resinsulfonate
  申请人：——

  公开号：US05110778A1

  公开（公告）日：1992-05-05

  Boron, aluminum and gallium C.sub.1 -C.sub.18 perfluoroalkane-sulfonates (CF.sub.3 (CF.sub.2).sub.n SO.sub.3).sub.3 M (M=B, A1, Ga; n=0-17) as well as perfluororesin sulfonates such as Nafionates are new, highly effective Friedel-Crafts catalysts. In contrast to volatile aluminum and boron trihalides, the Group III-B perfluoroalkanesulfonates are generally of low or no volatility and, except for boron triflate and some of its homologs, only sparingly soluble incommon organic solvents. This allows their use as solid or supported Friedel-Crafts catalysts of wide utility and scope in continuous heterogenous catalytic processes. At the same time, boron triflate and related lower perfluoroalkanesulfonates are particularly efficient soluble catalysts in solution reactions.

  硼，铝和镓C.sub.1-C.sub.18全氟烷基磺酸盐（CF.sub.3（CF.sub.2）.sub.n SO.sub.3）.sub.3 M（M = B，A1，Ga; n = 0-17），以及类似Nafionates的全氟树脂磺酸盐是新的，高效的Friedel-Crafts催化剂。与挥发性的铝和硼卤化物不同，III-B族的全氟烷基磺酸盐通常具有低或无挥发性，并且除了硼三氟酸盐和其一些同系物外，仅在常见有机溶剂中略溶。这使它们可以作为广泛实用的固体或支撑型Friedel-Crafts催化剂在连续的异相催化过程中使用。与此同时，硼三氟酸盐和相关的低全氟烷基磺酸盐在溶液反应中特别高效。
• (3-hydroxy-4-amino-butan-2-yl) -3- (2-thiazol-2-yl-pyrrolidine-1-carbonyl) benzamide derivatives and related compounds as beta-secretase inhibitors for treating
  申请人：CoMentis, Inc.

  公开号：US08299267B2

  公开（公告）日：2012-10-30

  The present invention provides novel beta-secretase inhibitors and methods for their use, including methods of treating of Alzheimer's disease.

  本发明提供了新颖的β-分泌酶抑制剂及其使用方法，包括治疗阿尔茨海默病的方法。