beryllium oxalate * 3H2O

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: beryllium oxalate * 3H2O
• 英文别名: beryllium oxalate trihydrate；oxalic acid ; beryllium oxalate；Oxalsaeure; Berylliumoxalat；Beryllium oxalate monohydrate；beryllium;oxalate;hydrate
• 化学式: Be*C₂O₄*3H₂O
• 分子量: 151.078
• InChiKey: RSNRQACYQZKPDF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -4.72
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  81.3
• 氢给体数：
  1
• 氢受体数：
  5

ADMET

毒理性

• 副作用

纤维原性 - 引发组织损伤和纤维化（疤痕形成）。

Fibrogenic - Inducing tissue injury and fibrosis (scarring).

来源:Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

反应信息

• 作为反应物：
  描述：

  beryllium oxalate * 3H2O 以100%的产率得到beryllium oxide
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Be: MVol., 3.2.1.1, page 82 - 83

  摘要：

  DOI：
• 作为产物：
  描述：

  beryllium hydroxide 、 草酸 以 水 为溶剂， 生成 beryllium oxalate * 3H2O
  参考文献：
  名称：

  Rosenheim, A.; Woge, P., Zeitschrift fur anorganische Chemie, 1897, vol. 15, p. 294

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Be: MVol., 3.10, page 146 - 161
  作者：

  DOI：——

  日期：——
• EQUILIBRIUM IN THE SYSTEM BERYLLIUM OXIDE, OXALIC ANHYDRIDE AND WATER.
  作者：Charles L. Parsons、Wm. O. Robinson

  DOI：10.1021/ja01971a001

  日期：1906.5
• Parsons, Ch. L.; Robinson, W. O., Zeitschrift fur anorganische Chemie, 1906, vol. 49, p. 180
  作者：Parsons, Ch. L.、Robinson, W. O.

  DOI：——

  日期：——
• Parsons, Ch. L.; Robinson, W. O., Journal of the American Chemical Society, 1906, vol. 28, p. 559
  作者：Parsons, Ch. L.、Robinson, W. O.

  DOI：——

  日期：——
• The thermal decomposition of beryllium oxalate and related materials
  作者：David Dollimore、Julie L. Konieczay

  DOI：10.1016/s0040-6031(98)00340-2

  日期：1998.9

  The compound beryllium oxalate trihydrate decomposes on heat treatment to beryllium oxide. Preparation of samples of beryllium oxalate under varying conditions revealed that the oxalate is hygroscopic and can exist as a trihydrate, a monohydrate or a combination of both depending on the partial pressure of water Vapor above the sample. The dehydration of these samples was shown by the thermogravimetric data to be followed by a subsequent one-step decomposition to BeO. There was some indication of intermediate compounds existing in the decomposition to the BeO. The kinetic behavior of this latter stage was studied in a series of isothermal experiments and was best described by a D2 diffusion mechanism with an activation energy of 88.9 kJ mol(-1). This is lower than that commonly reported for other Group II oxalates which suggests a less stable oxalate. By decomposing the beryllium oxalates at various temperatures, the surface area of the solid residue increases with a loss of crystal morphology but the oxide product resists sintering. (C) 1998 Elsevier Science B.V.