vanadium oxalate | 14974-48-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: vanadium oxalate
• 英文别名: vanadium (II) oxalate；Oxalic acid, vanadium salt；oxalate;vanadium(2+)
• CAS: 14974-48-2
• 化学式: C₂O₄*V
• 分子量: 138.961
• InChiKey: KTWTWVHLJFWEBP-UHFFFAOYSA-L

物化性质

• 物理描述：
  Liquid; WetSolid

计算性质

• 辛醇/水分配系数(LogP)：
  -3.52
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  vanadia 、 草酸 以 水 为溶剂， 生成 vanadium oxalate
  参考文献：
  名称：

  METHOD FOR PRODUCING XYLYLENEDIAMINE

  摘要：

  A method for producing xylylenediamine, including performing a first hydrogenation including hydrogenating a mixed solution including dicyanobenzene and a solvent including liquid ammonia in a fixed-bed reactor such that a reaction product (A) is produced, performing ammonia separation including separating and removing liquid ammonia included in the reaction product (A) or a reaction product (D) such that a reaction product (B) or (E) is produced, performing solid-liquid separation including subjecting the reaction product (B) or (A) to solid-liquid separation and removing a solid component such that a reaction product (C) or the reaction product (D) is produced, and performing a second hydrogenation including hydrogenating the reaction product (C) or (E) in a fixed-bed reactor. After the first hydrogenation is performed, the ammonia separation and the solid-liquid separation are performed in this order or reverse order, followed by the second hydrogenation.

  公开号：

  US20220153682A1

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: V: MVol.B1, 134, page 348 - 350
  作者：

  DOI：——

  日期：——
• Meyer, J.; Aulich, M., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Meyer, J.、Aulich, M.

  DOI：——

  日期：——
• METHOD FOR PRODUCING XYLYLENEDIAMINE
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20220153682A1

  公开（公告）日：2022-05-19

  A method for producing xylylenediamine, including performing a first hydrogenation including hydrogenating a mixed solution including dicyanobenzene and a solvent including liquid ammonia in a fixed-bed reactor such that a reaction product (A) is produced, performing ammonia separation including separating and removing liquid ammonia included in the reaction product (A) or a reaction product (D) such that a reaction product (B) or (E) is produced, performing solid-liquid separation including subjecting the reaction product (B) or (A) to solid-liquid separation and removing a solid component such that a reaction product (C) or the reaction product (D) is produced, and performing a second hydrogenation including hydrogenating the reaction product (C) or (E) in a fixed-bed reactor. After the first hydrogenation is performed, the ammonia separation and the solid-liquid separation are performed in this order or reverse order, followed by the second hydrogenation.