3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,18-Tritriacontafluorooctadecyl methacrylate | 59778-97-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,18-Tritriacontafluorooctadecyl methacrylate
• 英文别名: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,18-tritriacontafluorooctadecyl 2-methylprop-2-enoate
• CAS: 59778-97-1
• 化学式: C₁₆F₃₃CH₂CH₂OC(O)C(CH₃)=CH₂
• 分子量: 932.3
• InChiKey: XLGBPNZHUPJRPB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.6
• 重原子数：
  57
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  35

反应信息

• 作为产物：
  描述：

  三十三氟-1-十八烷醇 、 甲基丙烯酸 生成 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,18-Tritriacontafluorooctadecyl methacrylate
  参考文献：
  名称：

  MARUYAMA, TOSIKI;JOKOO, XIDEHDZIRO

  摘要：

  DOI：

文献信息

• Transition metal compound, polymerization-initiator system comprising the same, and process for producing polymer
  申请人：Uemura Makoto

  公开号：US20070270521A1

  公开（公告）日：2007-11-22

  A transition metal compound represented by the formula, [(CpR 1 m )(CO) 2 M 1 ][M 2 (CO) 2 (CpR 2 n )], wherein Cp is a cyclopentadienyl ring, R 1 and R 2 are independently of each other a hydrocarbyl group having 1 to 20 carbon atoms, and each of at least one R 1 and at least one R 2 is a hydrocarbyl group having 5 to 20 carbon atoms, m and n are independently of each other an integer of 1 to 5, and M 1 and M 2 are independently of each other a transition metal atom of the group 8 in the periodic table of elements; a polymerization-initiator system comprising said transition metal compound; and a process for producing a polymer in the presence of the polymerization-initiator system.

  一个由该公式表示的过渡金属化合物，[(CpR1m)(CO)2M1][M2(CO)2(CpR2n)]，其中Cp是一个环戊二烯环，R1和R2是独立的烃基团，含有1至20个碳原子，至少一个R1和至少一个R2是含有5至20个碳原子的烃基团，m和n是独立的1至5的整数，M1和M2是元素周期表中8族的过渡金属原子；包括所述过渡金属化合物的聚合物化引发剂系统；以及在聚合物化引发剂系统存在的情况下生产聚合物的过程。
• PHOTOSENSITIVE RESIN COMPOSITION AND FLEXOGRAPHIC RESIN PLATE
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP0950923A1

  公开（公告）日：1999-10-20

  The present invention provides a photosensitive resin composition which comprises an urethane resin obtained by reacting (A) a carboxyl group-containing polymer having an acid value of 30 mg KOH/g or more and a glass transition temperature of 30°C or more, (B) a compound having two isocyanate groups in one molecule, (C) a compound having two hydroxyl groups in one molecule and (D) a photopolymerizable unsaturated monomer having one hydroxyl group in one molecule, and a photopolymerization initiator, and a resin plate for flexography using the photosensitive resin composition, whereby the photosensitive resin composition having water developing properties, high in sensitivity and impact resilience, and excellent in water resistance, ink resistance and press life of a hardened portion forming a line pattern area of a printing plate material and the resin plate for flexography prepared by the use of the photosensitive resin composition can be provided.

  本发明提供了一种感光树脂组合物，它包括由以下物质反应得到的聚氨酯树脂：(A)酸值大于等于30毫克KOH/克且玻璃化温度大于等于30℃的含羧基聚合物；(B)一个分子中含有两个异氰酸酯基团的化合物；(C)一个分子中含有两个羟基的化合物；(D)一个分子中含有一个羟基的可光聚合不饱和单体、和一种光聚合引发剂，以及一种使用该感光树脂组合物的柔性版印刷用树脂版，从而可以提供具有水显影特性、高灵敏度和高冲击回弹性，以及在形成印刷版材料的线条图案区域的硬化部分和使用该感光树脂组合物制备的柔性版印刷用树脂版中具有优异的耐水性、耐油墨性和印刷寿命的感光树脂组合物。
• ELASTOMER COMPOSITION AND THERMOPLASTIC RESIN COMPOSITION CONTAINING THE SAME
  申请人：KANEKA CORPORATION

  公开号：EP1179566A1

  公开（公告）日：2002-02-13

  There is provided an elastomer composition for an impact modifier and a thermoplastic resin composition having improved impact resistance using the same. An elastomer composition comprises a block copolymer (a) containing a methacrylate polymer and a siloxane polymer, and a graft copolymer (b) containing a polymer component having a glass transition temperature of lower than 25°C. And the composition is mixed with a thermoplastic resin (c).

  本发明提供了一种用于抗冲改性剂的弹性体组合物，以及使用该组合物可提高抗冲击性的热塑性树脂组合物。弹性体组合物包括含有甲基丙烯酸酯聚合物和硅氧烷聚合物的嵌段共聚物（a），以及含有玻璃化转变温度低于 25°C 的聚合物成分的接枝共聚物（b）。该组合物与热塑性树脂 (c) 混合。
• THERMOPLASTIC RESIN COMPOSITION
  申请人：Kaneka Corporation

  公开号：EP1398353A1

  公开（公告）日：2004-03-17

  A thermoplastic resin composition comprising a thermoplastic resin (a) and a block copolymer (b) containing a methacrylic polymer block (A) and an acrylic polymer block (B).

  一种热塑性树脂组合物，由热塑性树脂（a）和嵌段共聚物（b）组成，嵌段共聚物含有甲基丙烯酸聚合物嵌段（A）和丙烯酸聚合物嵌段（B）。
• BLOCK COPOLYMER
  申请人：KANEKA CORPORATION

  公开号：EP1475397A1

  公开（公告）日：2004-11-10

  The present invention relates to a block copolymer (A) including a (meth)acrylic polymer block (a) and an acrylic polymer block (b). The (meth)acrylic polymer block (a) is preferably copolymerized with a monomer having a functional group having high cohesive force, such as a carboxyl group, so that the 5%-weight-loss temperature is 300°C or more or the tensile strength is 3 MPa or more, and the hardness measured by a type A durometer according to JIS K6253 is 50 or less, and a compression set measured after 22 hours at 70°C is 45% or less. The block copolymer (A) exhibits excellent thermal decomposition resistance and low compression set at high temperatures. The block copolymer (A) can be used as a soft material for automobile, and has low hardness, high adhesion, high oil resistance, high weather resistance, high heat resistance, high recycling property, high tensile properties; and high wax remover resistance.

  本发明涉及一种嵌段共聚物（A），包括（甲基）丙烯酸聚合物嵌段（a）和丙烯酸聚合物嵌段（b）。(甲基)丙烯酸聚合物嵌段(a)最好与具有高内聚力官能团（如羧基）的单体共聚，从而使 5%失重温度为 300°C 或以上，或拉伸强度为 3 MPa 或以上，且根据 JIS K6253 用 A 型硬度计测量的硬度为 50 或以下，在 70°C 下 22 小时后测量的压缩永久变形为 45% 或以下。嵌段共聚物（A）具有优异的抗热分解性能，高温下的压缩永久变形小。嵌段共聚物（A）可用作汽车软质材料，具有低硬度、高附着力、高耐油性、高耐候性、高耐热性、高回收性、高拉伸性和高抗脱蜡性。