RUTHENIUM-BASED CATALYTIC COMPLEXES AND THE USE OF SUCH COMPLEXES FOR OLEFIN METATHESIS
申请人:Mauduit Marc
公开号:US20100087644A1
公开(公告)日:2010-04-08
The invention relates to all compounds of the formula (I) or (II) in which: L is a neutral ligand; X, X′ are anionic ligands; R
1
and R
2
are, separately, a hydrogen, a C
1
-C
6
alkyl, a C
1
-C
6
perhalogenoalkyl, a aldehyde, a ketone, an ester, a nitrile, an aryl, a pyridinium alkyl, an optionally substituted C
5
or C
6
pyridinium alkyl, perhalogenoalkyl or cyclohexyl, a C
n
h2
N
Y radical 10 with n between 1 and 6 and y an i8onic marker, or a radical having the formula: wherein R
1
can be a radical of formula (Ibis) when the compound has formula (I) or of formula (IIbis) when the compound has formula (II), R
3
is a C
1
-C
6
alkyl, or a C
5
or C
6
cycloalkyl or a C
5
or C
6
aryl; R
0
, R
4
, R
5
, R
6
, R
7
, R
8
, R
9
, R
10
, R
11
, are, separately, a hydrogen, C
1
-C
6
alkyl, a C
1
-C
6
perhalogenoalkyl, or a C
5
or C
6
aryl; wherein R
9
, R
10
, R
11
can be a heterocycle; X
1
is anion. R
1
and R
2
can form, with the N and the C to which they are attached, a heterocycle.
本发明涉及公式(I)或(II)中的所有化合物,其中:L为中性配体;X,X'为阴离子配体;R1和R2分别为氢,C1-C6烷基,C1-C6全氟烷基,醛,酮,酯,腈,芳基,吡啶基烷基,可选取代的C5或C6吡啶基烷基,全氟烷基或环己基,Cnh2NY基团10,其中n在1至6之间,y为离子标记,或具有以下公式的基团:其中当化合物具有公式(I)时,R1可以是公式(Ibis)的基团,当化合物具有公式(II)时,R1可以是公式(IIbis)的基团,R3为C1-C6烷基,或C5或C6环烷基或C5或C6芳基;R0,R4,R5,R6,R7,R8,R9,R10,R11分别为氢,C1-C6烷基,C1-C6全氟烷基或C5或C6芳基;其中R9,R10,R11可以是杂环;X1为阴离子。R1和R2可以与它们连接的N和C形成杂环。