2-allylphenyl chloromethyl ether | 121824-51-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-allylphenyl chloromethyl ether
• 英文别名: 1-(Chloromethoxy)-2-prop-2-enylbenzene
• CAS: 121824-51-9
• 化学式: C₁₀H₁₁ClO
• 分子量: 182.65
• InChiKey: LTANFQGXUUCHBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-allyl-2-[(methylsulfanyl)methoxy]benzene 在 乙酰氯 、 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 2.67h， 生成 2-allylphenyl chloromethyl ether
  参考文献：
  名称：

  Antonsen, Oeyvind; Benneche, Tore; Undheim, Kjell, Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1988, vol. 42, # 8, p. 515 - 523

  摘要：

  DOI：

文献信息

• CYCLOHEXANE POLYCARBOXYLIC ACID DERIVATIVES AS PLASTICIZERS FOR ADHESIVES AND SEALANTS
  申请人：Mack Helmut

  公开号：US20110232825A1

  公开（公告）日：2011-09-29

  The invention provides an adhesive or sealant comprising at least (A) one compound selected from the group consisting of silylated polyurethanes, silylated polyureas, silylated polyethers, silylated polysulfides and silyl-terminated acrylates, and at least (B) one cyclohexane polycarboxylic acid derivative. The composition has enhanced extensibility with good adhesion properties and high tensile strength. A process is disclosed for preparing the adhesive or sealant, and also disclosed is the use thereof for producing material bonds between parts to be joined.

  本发明提供了一种粘合剂或密封剂，包括至少（A）从包括硅化聚氨酯、硅化聚氨基甲酸酯、硅化聚醚、硅化聚硫化物和硅基终止丙烯酸酯的群组中选择的一种化合物，以及至少（B）一种环己烷聚羧酸衍生物。该组合物具有良好的粘附性和高拉伸强度的增强延展性。还公开了制备粘合剂或密封剂的过程，并公开了将其用于在要连接的零件之间产生材料粘结的用途。
• Sealant for double-layered glass
  申请人：KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0312967A1

  公开（公告）日：1989-04-26

  A sealant for double-layerd glass contains a saturated hydrocarbon based polymer having at least one silicon-containing group that has a hydroxyl group or a hydrolyzable group bonded to a silicon atom and which is capable of crosslinking by forming siloxane bond.

  一种用于双层玻璃的密封胶含有一种饱和烃基聚合物，该聚合物至少含有一个含硅基团，该基团具有与硅原子结合的羟基或可水解基团，并能通过形成硅氧烷键而交联。
• Process for producing unsaturated group-terminated high-molecular weight polyalkylene oxide
  申请人：KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0415404A2

  公开（公告）日：1991-03-06

  A process for producing an unsaturated group-­terminated high-molecular weight polyalkylene oxide by adding an alkali metal and/or an alkali metal compound capable of producing an alkali metal hydroxide on reaction with water to a hydroxyl-terminated polyalkylene oxide having a repeating unit represented by formula -R¹-O- (wherein R¹ represents a divalent alkylene group having from 2 to 8 carbon atoms) to substitute the hydrogen atom of the hydroxyl end group with an alkali metal (alkoxidation) the resulting polyalkylene oxide is reacted with a polyhalogen compound to increase the molecular weight of the polyalkylene oxide and then additional alkali metal and/or alkali metal compound is added before reacting the resulting high-molecular weight polyalkylene oxide with an unsaturated halogen compound to introduce an unsaturated group to the molecular chain terminals. The first addition of alkali metal and/or alkali metal compound capable of producing an alkali metal hydroxide on reacting with water is added in an amount equivalent to or less than the hydroxyl end groups of said polyalkylene oxide and second addition of alkali metal and/or alkali metal compound is added in an amount equivalent to or greater than the remaining hydroxyl end groups.

  一种生产不饱和基团封端的高分子量聚环氧烷的工艺，其方法是在具有式 -R¹-O- 代表的重复单元的羟基封端的聚环氧烷中加入碱金属和/或与水反应后能生成碱金属氢氧化物的碱金属化合物，以碱金属取代羟基末端基团的氢原子（烷氧基化）。(其中 R¹ 代表具有 2 至 8 个碳原子的二价烷基)，用碱金属取代羟基末端基团的氢原子 (烷氧基化)，所得的聚环氧烷与多卤素化合物反应，以增加聚环氧烷的分子量，然后在所得的高分子量聚环氧烷与不饱和卤素化合物反应之前，再加入碱金属和/或碱金属化合物，以在分子链末端引入不饱和基团。第一次加入的碱金属和/或碱金属化合物在与水反应时能生成碱金属氢氧化物，加入量等于或小于所述聚环氧烷的羟基端基，第二次加入的碱金属和/或碱金属化合物的量等于或大于剩余的羟基端基。
• CURING AGENT, METHOD OF PREPARATION THEREOF, AND CURABLE COMPOSITION PREPARED THEREFROM
  申请人：Kanegafuchi Chemical Industry Co., Ltd.

  公开号：EP0431173A1

  公开（公告）日：1991-06-12

  A curable composition comprising: (1) a non-polymeric organic curing agent having at least two hydrosilyl groups in its molecule, (2) an organic polymer having at least one alkenyl group in its molecule, and (3) a hydrosilylation catalyst. It can rapidly be cured to the depths to give a product having good mechanical properties.

  一种可固化组合物，包括：(1) 分子中含有至少两个氢硅烷基的非聚合有机固化剂，(2) 分子中含有至少一个烯基的有机聚合物，以及 (3) 氢硅烷化催化剂。它可以快速固化到一定深度，使产品具有良好的机械性能。
• Curable composition for injection molding
  申请人：KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0709403A1

  公开（公告）日：1996-05-01

  A curable compoisiton for injection molding which comprises, as essential ingredients, (A) a saturated hydrocarbon polymer containing at least one alkenyl group capable of undergoing a hydrosilylation reaction per molecule, (B) a hardener having a molecular weight of 30,000 or lower and containing at least two hydrosilyl groups per molecule, and (C) a hydrosilylation catalyst.

  一种用于注塑成型的可固化组合物，其基本成分包括：(A) 饱和碳氢化合物聚合物，每分子至少含有一个能发生氢化硅反应的烯基；(B) 硬化剂，分子量为 30,000 或更低，每分子至少含有两个氢化硅基；(C) 氢化硅催化剂。