1-(1-methyl-1-tert-butylperoxyethyl)-3-isopropenylbenzene | 96319-55-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(1-methyl-1-tert-butylperoxyethyl)-3-isopropenylbenzene
• 英文别名: 1-(2-Tert-butylperoxypropan-2-yl)-3-prop-1-en-2-ylbenzene
• CAS: 96319-55-0
• 化学式: C₁₆H₂₄O₂
• 分子量: 248.365
• InChiKey: UPJJAYDKTWNELO-UHFFFAOYSA-N

物化性质

• 沸点：
  307.3±21.0 °C(Predicted)
• 密度：
  0.9442 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,3-二异丙基苯 在 sodium hydroxide 、 高氯酸 、 碘 、 氧气 作用下， 以 溶剂黄146 为溶剂， 反应 8.0h， 生成 1-(1-methyl-1-tert-butylperoxyethyl)-3-isopropenylbenzene
  参考文献：
  名称：

  Dikii, M. A.; Gevus', O. I.; Puchin, V. A., Journal of Organic Chemistry USSR (English Translation), 1986, p. 336 - 338

  摘要：

  DOI：

文献信息

• COMPOSITIONS, SYNTHESIS, AND USES OF HYDROLYZABLE SILANE MODIFIED CASHEW NUT SHELL LIQUID DERIVATIVES
  申请人：Cardolite Corporation

  公开号：US20190077815A1

  公开（公告）日：2019-03-14

  The present disclosure provides cashew nut shell liquid derivatives based organosilicon products and methods and uses of preparing the same.

  本公开提供以腰果壳液衍生物为基础的有机硅产物、其制备方法和用途。
• Composition suitable for use in polymer cross-linking processes
  申请人：AKZO N.V.

  公开号：EP0238104A1

  公开（公告）日：1987-09-23

  A composition is disclosed which is especially suitable for use in the pretreatment of polymers that have to be cross-linked with a radical forming cross-linking agent. The resulting shaped, cross-linked products display excellent surface properties. The composition contains a finely divided, film forming polymer, e.g. polyethylene, a finely divided rubber filler, e.g. silanized clay, and an organic peroxide, e.g. dicumyl peroxide.

  本发明公开了一种组合物，它特别适用于需要用自由基交联剂进行交联的聚合物的预处理。交联后的成型产品具有极佳的表面特性。该组合物含有一种细小的成膜聚合物（如聚乙烯）、一种细小的橡胶填料（如硅烷化粘土）和一种有机过氧化物（如过氧化二辛酯）。
• Peroxide vulcanized rubber composition
  申请人：Akzo Nobel N.V.

  公开号：EP0540103A1

  公开（公告）日：1993-05-05

  A peroxide-vulcanized rubber composition which comprises the vulcanization reaction product of a rubber, an organic peroxide, a biscitraconimido compound and a radical scavenger, is disclosed. The peroxide-vulcanized rubber compositions of the disclosure have significantly improved physical properties. Also disclosed are a peroxide-vulcanization process carried out in the presence of a biscitraconimido compound and a radical scavenger to control the scorch time and the use of a biscitraconimido compound and a radical scavenger to control scorch time in the peroxide-vulcanization of rubber.

  本发明公开了一种过氧化物-硫化橡胶组合物，该组合物由橡胶的硫化反应产物、一种有机过氧化物、一种双琥珀酰亚胺化合物和一种自由基清除剂组成。本公开的过氧化物硫化橡胶组合物具有显著改善的物理性能。
• Peroxide cured fluorocarbon elastomer compositions
  申请人：Carl Freudenberg

  公开号：EP1574543A1

  公开（公告）日：2005-09-14

  A process involves adding a peroxide masterbatch to a molten blend of a fluorocarbon elastomer and a thermoplastic material. The peroxide masterbatch contains greater than or equal to 5% weight percent organic peroxide, further contains a fluorocarbon elastomer, and typically also contains a crosslinker containing at least two sites of olefinic unsaturation. The fluorocarbon elastomer in the molten blend and in the peroxide masterbatch may be the same or different. After the peroxide masterbatch is added to the molten blend, the combination is mixed at a temperature and for a time sufficient to effect cure of the fluorocarbon elastomers. By using a masterbatch, a faster and more uniform dispersion of peroxide curative is possible due to pre-dispersion of peroxide in the elastomer phase, which leads to shaped articles having improved mechanical properties.

  一种工艺是将过氧化物母料添加到氟碳弹性体和热塑性材料的熔融混合物中。过氧化物母料含有大于或等于 5% 重量百分比的有机过氧化物，还含有碳氟化合物弹性体，通常还含有至少两个烯烃不饱和位点的交联剂。熔融混合物和过氧化物母料中的碳氟化合物弹性体可以相同，也可以不同。过氧化物母料加入熔融混合物后，在足以使碳氟化合物弹性体固化的温度和时间下混合。通过使用母料，可使过氧化物固化剂更快、更均匀地分散在弹性体相中，从而使成型产品具有更好的机械性能。
• Elastomeric compositions containing fluoropolymer blends
  申请人：Carl Freudenberg KG

  公开号：EP1591469A1

  公开（公告）日：2005-11-02

  Processable rubber compositions contain a vulcanized fluorocarbon elastomer dispersed in a thermoplastic matrix comprising a fully fluorinated polymer and a partially fluorinated polymer. The processing temperature is below the melting point of the fully fluorinated polymer. The compositions are made by combining a curative, uncured fluorocarbon elastomer, a fully fluorinated thermoplastic, and a partially fluorinated thermoplastic material, and heating the mixture at a temperature and for a time sufficient to effect vulcanization of the elastomeric material, while mechanical energy is applied to mix the mixture during the heating step. Shaped articles such as seals, gaskets, O-rings, and hoses may be readily formed from the rubber compositions according to conventional thermoplastic processes such as blow molding, injection molding, and extrusion.

  可加工橡胶组合物包含一种硫化氟碳弹性体，分散在由全氟化聚合物和部分氟化聚合物组成的热塑性基体中。加工温度低于全氟化聚合物的熔点。将固化的、未固化的碳氟化合物弹性体、全氟化热塑性塑料和部分氟化热塑性塑料材料混合，并在足以使弹性体材料硫化的温度和时间下加热混合物，同时在加热步骤中施加机械能以混合混合物，即可制成这种组合物。根据吹塑、注塑和挤压等传统热塑性工艺，密封件、垫圈、O 形环和软管等异型制品很容易从橡胶组合物中成型。