4,4'-(1,1-环己烷二基)二[N-(4-甲基苯基)苯胺] | 64819-53-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4,4'-(1,1-环己烷二基)二[N-(4-甲基苯基)苯胺]
• 英文名称: 1,1-bis[(di-4-tolylamino)phenyl]cyclohexane
• 英文别名: 1,1-Bis[4-(4-methylphenylamino)phenyl]cyclohexane；4-methyl-N-[4-[1-[4-(4-methylanilino)phenyl]cyclohexyl]phenyl]aniline
• CAS: 64819-53-0
• 化学式: C₃₂H₃₄N₂
• 分子量: 446.635
• InChiKey: NSAIEWNSTRFQGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.9
• 重原子数：
  34
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921590090

反应信息

• 作为反应物：
  描述：

  3-（（（6-（4-溴苯基）己氧基）甲基）-3-乙基氧杂环丁烷 、 4,4'-(1,1-环己烷二基)二[N-(4-甲基苯基)苯胺] 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 生成 N-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]phenyl]-N-[4-[1-[4-(N-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]phenyl]-4-methylanilino)phenyl]cyclohexyl]phenyl]-4-methylaniline
  参考文献：
  名称：

  Crosslinkable TAPC-Based Hole-Transport Materials for Solution-Processed Organic Light-Emitting Diodes with Reduced Efficiency Roll-Off

  摘要：

  Abstract1‐Bis[4‐[N,N‐di(4‐tolyl)amino]phenyl]‐cyclohexane (TAPC) has been widely used in xerography and organic light‐emitting diodes (OLEDs), but derivatives are little known. Here, a new series of solution‐processable, crosslinkable hole conductors based on TAPC with varying highest occupied molecular orbital (HOMO) energies from −5.23 eV to −5.69 eV is implemented in blue phosphorescent OLEDs. Their superior perfomance compared with the well‐known N4,N4,N4′,N4′‐tetraphenylbiphenyl‐4,4′‐diamine (TPDs) analogues regarding hole‐injection and mobility, electron and exciton blocking capabilities, efficiency, and efficiency roll‐off is demonstrated. Overall, the TAPC‐based devices feature higher luminous and power efficiency over a broader range of brightness levels and reduced efficiency roll off. A systematic broadening of the emission zone is observed as the hole‐injection barrier between the anode and the hole‐transporting layer increased.

  DOI：

  10.1002/adfm.201201197
• 作为产物：
  描述：

  对溴甲苯 、 1,1-双(4-氨基苯基)环己烷 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 生成 4,4'-(1,1-环己烷二基)二[N-(4-甲基苯基)苯胺]
  参考文献：
  名称：

  Crosslinkable TAPC-Based Hole-Transport Materials for Solution-Processed Organic Light-Emitting Diodes with Reduced Efficiency Roll-Off

  摘要：

  Abstract1‐Bis[4‐[N,N‐di(4‐tolyl)amino]phenyl]‐cyclohexane (TAPC) has been widely used in xerography and organic light‐emitting diodes (OLEDs), but derivatives are little known. Here, a new series of solution‐processable, crosslinkable hole conductors based on TAPC with varying highest occupied molecular orbital (HOMO) energies from −5.23 eV to −5.69 eV is implemented in blue phosphorescent OLEDs. Their superior perfomance compared with the well‐known N4,N4,N4′,N4′‐tetraphenylbiphenyl‐4,4′‐diamine (TPDs) analogues regarding hole‐injection and mobility, electron and exciton blocking capabilities, efficiency, and efficiency roll‐off is demonstrated. Overall, the TAPC‐based devices feature higher luminous and power efficiency over a broader range of brightness levels and reduced efficiency roll off. A systematic broadening of the emission zone is observed as the hole‐injection barrier between the anode and the hole‐transporting layer increased.

  DOI：

  10.1002/adfm.201201197

文献信息

• [EN] COMPOSITION OF MATTER FOR USE IN ORGANIC LIGHT-EMITTING DIODES<br/>[FR] COMPOSITION DE MATIÈRE DESTINÉE À ÊTRE UTILISÉE DANS DES DIODES ÉLECTROLUMINESCENTES ORGANIQUES
  申请人：KYULUX INC

  公开号：WO2019195104A1

  公开（公告）日：2019-10-10

  The present disclosure relates to compounds of Formula (I) or (II), as compounds capable of emitting delayed fluorescence, and uses of the compounds in organic light-emitting diodes.

  本公开涉及到Formula (I)或(II)的化合物，作为能够发出延迟荧光的化合物，并且这些化合物在有机发光二极管中的应用。
• Organic electroluminescent (EL) devices
  申请人：Xerox Corporation

  公开号：US20030170490A1

  公开（公告）日：2003-09-11

  A new class of conjugated organic polymers or copolymers comprising a triazine group. This class of polymers or copolymers may be used in organic electroluminescent (EL) devices.

  一种新型的共轭有机聚合物或共聚物，包括三嗪基团。这类聚合物或共聚物可用于有机电致发光（EL）器件。
• ORGANIC COMPOSITION AND ELECTRONIC DEVICE COMPRISING ORGANIC LAYER COMPRISING SAID COMPOSITION
  申请人：Rohm and Haas Electronic Materials Korea Ltd.

  公开号：US20180151807A1

  公开（公告）日：2018-05-31

  A composition suitable for organic layers of electronic devices that shows improved luminescent properties, and electronic devices comprising organic layers comprising such composition.

  一种适用于电子器件的有机层的组合物，显示出改善的发光性能，以及包括含有该组合物的有机层的电子器件。
• [EN] COMPOSITION OF MATTER FOR USE IN ORGANIC LIGHT-EMITTING DIODES<br/>[FR] COMPOSITION DE SUBSTANCE DESTINÉE À ÊTRE UTILISÉE DANS DES DIODES ÉLECTROLUMINESCENTES ORGANIQUES
  申请人：KYULUX INC

  公开号：WO2018237393A1

  公开（公告）日：2018-12-27

  The present disclosure relates to compounds capable of emitting delayed fluorescence, and uses of these compounds in organic light-emitting diodes.

  本公开涉及能够发射延迟荧光的化合物，以及这些化合物在有机发光二极管中的用途。
• Composition of matter for use in organic light-emitting diodes
  申请人：Kyulux North America, Inc.

  公开号：US10892425B1

  公开（公告）日：2021-01-12

  The present disclosure relates to compounds of formula (I) or formula (II) as compounds capable of emitting delayed fluorescence and uses of these compounds in organic light-emitting diodes.

  本公开涉及公式(I)或公式(II)的化合物，这些化合物能够发出延迟荧光，并且在有机发光二极管中使用这些化合物。