9-(6-(4-(9H-carbazol-9-yl)phenyl)pyridin-3-yl)-9H-carbazole | 1384055-91-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(6-(4-(9H-carbazol-9-yl)phenyl)pyridin-3-yl)-9H-carbazole
• 英文别名: cppy；4,5'-bis(N-carbazolyl)-2'-phenylpyridine；9-[6-(4-Carbazol-9-ylphenyl)pyridin-3-yl]carbazole
• CAS: 1384055-91-7
• 化学式: C₃₅H₂₃N₃
• 分子量: 485.588
• InChiKey: CTOBILDJOZYBGJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  38
• 可旋转键数：
  3
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  22.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  iridium(III) chloride trihydrate 、 9-(6-(4-(9H-carbazol-9-yl)phenyl)pyridin-3-yl)-9H-carbazole 以 乙二醇乙醚 、 水 为溶剂， 反应 24.0h， 以96%的产率得到Ir(cppy)₂Cl₂Ir(cppy)₂
  参考文献：
  名称：

  Carbazole-Substituted Iridium Complex as a Solid State Emitter for Two-Photon Intravital Imaging

  摘要：

  A tris-cyclometalated iridium complex that beats two ligands functionalized by peripheral carbazole groups combines an intense solid state emission and a significant two photon absorption cross section in the near-infrared. After incorporation into a physiological micellar suspension, it can be used for the intravital two-photon fluorescence microscopy of cerebral vasculature.

  DOI：

  10.1021/acs.inorgchem.6b01253
• 作为产物：
  描述：

  5-溴-2-(4-溴苯基)吡啶 、 咔唑 在 18-冠醚-6 、 铜 、 potassium carbonate 作用下， 以 邻二氯苯 为溶剂， 反应 168.0h， 以89%的产率得到9-(6-(4-(9H-carbazol-9-yl)phenyl)pyridin-3-yl)-9H-carbazole
  参考文献：
  名称：

  用于高效单层磷光OLED的基于N杂环咔唑的主体

  摘要：

  使用新型的基于N-杂环咔唑的主体材料展示了高效的单层有机发光二极管（OLED）。制备了具有ITO / MoO 3 /主体/主体：掺杂剂/主体/ Cs 2 CO 3 / Al结构的磷光OLED，其中新材料同时充当电子传输，空穴传输和主体层。实现了最大电流和外部量子效率分别为92.2 cd A -1和26.8％的器件，这是迄今为止单层OLED所报道的最高值。

  DOI：

  10.1002/adma.201200927

文献信息

• ORGANIC COMPOUND, CHARGE TRANSPORT MATERIAL AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Pioneer Corporation

  公开号：EP1858094A1

  公开（公告）日：2007-11-21

  An organic compound is represented by following Formula (I) : wherein Cz1 and Cz2 may be the same as or different from each other and each represent a carbazolyl group; Q1 and Q2 may be the same as or different from each other and each represent a direct bond or an arbitrary linkage group; and Cz1, Cz2, Q1, Q2, Ring B1 and Ring B2 may each be substituted. The organic compound and charge transporting material show both excellent hole transporting ability and excellent electron transporting ability and have satisfactory durability against electric oxidation/reduction and a high triplet excitation level. An organic electroluminescent device using the organic compound emits light with a high efficiency and is highly stably driven.

  有机化合物由下式（I）表示： 其中 Cz1 和 Cz2 可以相同或不同，各自代表一个咔唑基团；Q1 和 Q2 可以相同或不同，各自代表一个直接键或任意连接基团；Cz1、Cz2、Q1、Q2、环 B1 和环 B2 可以各自被取代。该有机化合物和电荷传输材料同时显示出优异的空穴传输能力和优异的电子传输能力，并具有令人满意的抗电氧化/还原耐久性和高三重激发水平。使用该有机化合物的有机电致发光器件发光效率高，驱动高度稳定。
• AROMATIC AMINE DERIVATIVE, ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP2816025A1

  公开（公告）日：2014-12-24

  An organic EL device that has a high efficiency and a long service life, an electronic apparatus containing the organic EL device, and a compound capable of providing the organic EL device. The compound is specifically represented by the following general formula (1): wherein in the general formula (1), Ar1 represents an organic group A represented by the following general formula (A-1); Ar2 represents the organic group A or an organic group B represented by the following general formula (B-1); and Ar3 represents the organic group B or an organic group C represented by the following general formula (C-1), provided that in the case where both Ar1 and Ar2 are the organic groups A, the organic groups A may be the same as or different from each other, in the general formula (A-1), R1 and R2 each represent a hydrogen atom, an alkyl group or an aryl group, and R1 and R2 may be bonded to each other to form a hydrocarbon ring; R3 to R6 each represent an alkyl group, a cycloalkyl group or an aryl group; and a, b, c and d each independently represent an integer of from 0 to 2, provided that R3 and R4 may be bonded to each other to form a hydrocarbon ring; and in the case where a or b is 2, adjacent groups of R3 or adjacent groups of R4 may be bonded to each other to form a hydrocarbon ring, in the general formula (B-1), Ar4 and Ar5 each represent an arylene group; Ar6 represents an aryl group; R7 to R9 each represent an alkyl group, a cycloalkyl group or an aryl group; e, f and g each represent an integer of from 0 to 2; and h and i each represent 0 or 1, provided that R7 to R9 may be bonded to each other to form a hydrocarbon ring; and in the case where e, f or g is 2, adjacent groups of R7, adjacent groups of R8 or adjacent groups of R9 may be bonded to each other to form a hydrocarbon ring, in the general formula (C-1), Ar7 represents an aryl group; R10 represents an alkyl group, a cycloalkyl group or an aryl group; and j represents an integer of from 0 to 2, provided that in the case where j is 2, adjacent groups of R10 may be bonded to each other to form a hydrocarbon ring.

  一种具有高效率和长使用寿命的有机电致发光器件，一种包含该有机电致发光器件的电子设备，以及一种能够提供该有机电致发光器件的化合物。该化合物具体由以下通式（1）表示： 其中，在通式（1）中，Ar1 代表由以下通式（A-1）表示的有机基团 A；Ar2 代表有机基团 A 或由以下通式（B-1）表示的有机基团 B；以及 Ar3 代表有机基团 B 或由以下通式（C-1）表示的有机基团 C，条件是在 Ar1 和 Ar2 都是有机基团 A 的情况下，有机基团 A 可以彼此相同或彼此不同、 在通式（A-1）中，R1 和 R2 分别代表氢原子、烷基或芳基，R1 和 R2 可相互键合形成烃环；R3 至 R6 分别代表烷基、环烷基或芳基；a、b、c 和 d 各自独立地代表 0 至 2 的整数，条件是 R3 和 R4 可以相互键合以形成一个烃环；在 a 或 b 为 2 的情况下，R3 的相邻基团或 R4 的相邻基团可以相互键合以形成一个烃环、 在通式（B-1）中，Ar4 和 Ar5 分别代表芳烯基；Ar6 代表芳基；R7 至 R9 分别代表烷基、环烷基或芳基；e、f 和 g 分别代表 0 至 2 的整数；以及 h 和 i 各自代表 0 或 1，条件是 R7 至 R9 可相互键合形成一个烃环；在 e、f 或 g 为 2 的情况下，R7 的相邻基团、R8 的相邻基团或 R9 的相邻基团可相互键合形成一个烃环、 在通式（C-1）中，Ar7 代表芳基；R10 代表烷基、环烷基或芳基；j 代表 0 至 2 的整数，但在 j 为 2 的情况下，R10 的相邻基团可相互键合形成烃环。
• AROMATIC AMINE COMPOUND, ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP3018119A1

  公开（公告）日：2016-05-11

  An aromatic amine derivative having a specific structure, an organic electroluminescence device, and an electronic equipment are provided. The organic electroluminescence device includes organic thin film layers which include a light emitting layer and are disposed between a cathode and an anode. At least one layer of the organic thin film layers includes the aromatic amine derivative. The organic electroluminescence device can be operated at low driving voltage and has high efficiency. The compound achieves the above organic electroluminescence device.

  本文提供了一种具有特定结构的芳香胺衍生物、一种有机电致发光器件和一种电子设备。有机电致发光器件包括有机薄膜层，其中包括发光层，并置于阴极和阳极之间。有机薄膜层中至少有一层包括芳香胺衍生物。该有机电致发光器件可在低驱动电压下运行，并具有高效率。该化合物实现了上述有机电致发光器件。
• Organic EL multi-color light-emitting device
  申请人：Matsumoto Toshiki

  公开号：US10276637B2

  公开（公告）日：2019-04-30

  An organic EL multi-color emitting device including a substrate, and a first light-emitting element and a second light-emitting element arranged on the surface of the substrate; the first light-emitting element including, between an anode and a cathode, a first organic layer, a second organic layer and a third organic layer in this sequence in a direction perpendicular to the surface of the substrate; the second light-emitting element including, between an anode and a cathode, a second organic layer and a third organic layer in this sequence in a direction perpendicular to the surface of the substrate; the first organic layer including a first light-emitting dopant; the third organic layer including a second light-emitting dopant; the second organic layer including any of (A) a compound including an arylamine site, and a furan site or a thiophene site, (B) a compound including an arylamine site and a site comprising a nitrogen-containing six-membered ring structure, (C) a compound including a carbazole site, and a furan site or a thiophene site, and (D) a compound including a carbazole site and a site including a nitrogen-containing six-membered ring structure.

  一种有机EL多色发光器件，包括基板，以及排列在基板表面上的第一发光元件和第二发光元件；第一发光元件在阳极和阴极之间包括沿垂直于基板表面的方向依次排列的第一有机层、第二有机层和第三有机层；第二发光元件在阳极和阴极之间包括沿垂直于基板表面的方向依次排列的第二有机层和第三有机层；第一有机层包括第一发光掺杂剂； 第三有机层包括第二发光掺杂剂；(A) 包括芳胺位点和呋喃位点或噻吩位点的化合物；(B) 包括芳胺位点和包含含氮六元环结构的位点的化合物；(C) 包括咔唑位点和呋喃位点或噻吩位点的化合物；(D) 包括咔唑位点和包含含氮六元环结构的位点的化合物。
• Aromatic amine compound, organic electroluminescent element and electronic device
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10411192B2

  公开（公告）日：2019-09-10

  An aromatic amine derivative having a specific structure, an organic electroluminescence device, and an electronic equipment are provided. The organic electroluminescence device includes organic thin film layers which include a light emitting layer and are disposed between a cathode and an anode. At least one layer of the organic thin film layers includes the aromatic amine derivative. The organic electroluminescence device can be operated at low driving voltage and has high efficiency. The compound achieves the above organic electroluminescence device.

  本文提供了一种具有特定结构的芳香胺衍生物、一种有机电致发光器件和一种电子设备。有机电致发光器件包括有机薄膜层，其中包括发光层，并置于阴极和阳极之间。有机薄膜层中至少有一层包括芳香胺衍生物。该有机电致发光器件可在低驱动电压下运行，并具有高效率。该化合物实现了上述有机电致发光器件。