1,1-Bis(diphenylphosphanylmethyl)-2,2-dimethylhydrazine | 305830-90-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1-Bis(diphenylphosphanylmethyl)-2,2-dimethylhydrazine
• CAS: 305830-90-4
• 化学式: C₂₈H₃₀N₂P₂
• 分子量: 456.507
• InChiKey: LUNOLIDDXWYMAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  32
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [RuH2(PPh3)4] 、 1,1-Bis(diphenylphosphanylmethyl)-2,2-dimethylhydrazine 以 四氢呋喃 为溶剂， 以97%的产率得到
  参考文献：
  名称：

  Phosphorus-Containing Dendrimers and Their Transition Metal Complexes as Efficient Recoverable Multicenter Homogeneous Catalysts in Organic Synthesis

  摘要：

  Metalladendrimers of generation 3 with either 24 terminal palladium or ruthenium diphosphine complexes or one ruthenium diphosphine complex located at the core have been found to be efficient, recoverable catalysts in three general organic reactions: Stille couplings, Knoevenagel condensations, and Michael additions.

  DOI：

  10.1021/om0005607
• 作为产物：
  描述：

  偏二甲肼 、 (二苯基膦基)甲醇 以 四氢呋喃 为溶剂， 反应 15.0h， 生成 1,1-Bis(diphenylphosphanylmethyl)-2,2-dimethylhydrazine
  参考文献：
  名称：

  Synthesis and Characterization of Controlled Dendritic Architectures by Association of Two Phosphorus Dendrons Through a Metallic Center

  摘要：

  The reactions of RuCl2(PPh3)(3) with either a small amino diphosphine or a first-generation phosphorus-containing dendron possessing an aminodiphosphine as the core induce the formation of complexes in which two amino diphosphines are associated through the metallic center. Determination of the structure of the smallest complex by X-ray diffraction shows that the metal is surrounded by a square-based bi-pyramid defined by the four phosphorus atoms of both diphosphines in a single plane, with the chlorine atoms at both summits. The first generation dendrons behave in the same way as the small compound, and allow us to isolate an original bis dendron, associated through the ruthenium atom.

  DOI：

  10.1080/10426500902947971

文献信息

• KATALYSATORSYSTEME FÜR DIE HERSTELLUNG VON COPOLYMERISATEN AUS KOHLENMONOXID UND OLEFINISCH UNGESÄTTIGTEN VERBINDUNGEN
  申请人：BASF AKTIENGESELLSCHAFT

  公开号：EP0944666B1

  公开（公告）日：2003-03-05
• US6103867A
  申请人：——

  公开号：US6103867A

  公开（公告）日：2000-08-15