The first diphosphastibolyl complexes: synthesis and characterisation of [Ru(η<sup>5</sup>-C<sub>5</sub>R<sub>5</sub>)(η<sup>5</sup>-C<sub>2</sub>Bu<sup>t</sup><sub>2</sub>P<sub>2</sub>Sb)]; R = H or Me
作者:Matthew D. Francis、David E. Hibbs、Michael B. Hursthouse、Cameron Jones、K. M. Abdul Malik
DOI:10.1039/cc9960001591
日期:——
Treatment of the novel ring anion [C(2)Bu(2)(t)P(2)Sb](-) 4 with [Ru(eta(5)-C(5)R(5))(MeCN)(3)]PF6, (R = H, Me), affords the compounds [Ru(eta(5)-C(5)R(5))(eta(5)-(C2BU2P2Sb)-P-t)] (R = H 6, Me 7), which represent the first examples of complexes derived from a diphosphastibolyl ring; the X-ray crystal structure of 7 is described.