3,6-bis(benzoylbiphenyl)ethynylcarbazole-9-carboxylic acid 1,1-dimethyltridecyl ester | 935682-41-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,6-bis(benzoylbiphenyl)ethynylcarbazole-9-carboxylic acid 1,1-dimethyltridecyl ester
• CAS: 935682-41-0
• 化学式: C₇₀H₆₃NO₄
• 分子量: 982.275
• InChiKey: ZWCLTGKNDGLZOY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.46
• 重原子数：
  75.0
• 可旋转键数：
  18.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  65.37
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  3,6-bis(benzoylbiphenyl)ethynylcarbazole-9-carboxylic acid 1,1-dimethyltridecyl ester 在 molybdenum triamide 对硝基苯酚 作用下， 以 various solvent(s) 为溶剂， 反应 22.0h， 以81%的产率得到ACTC
  参考文献：
  名称：

  Detection of Explosives with a Fluorescent Nanofibril Film

  摘要：

  A new type of fluorescence sensory material has been developed from an alkoxycarbonyl-substituted carbazole-cornered tetracycle. Films fabricated from such materials are shown to be efficient in detecting explosive vapor, probably owing to the extended 1D molecular stacking between the component molecules and intrinsic nanoporous morphology thus formed within the film. The former facilitates long-range exciton migration, while the latter favors adsorption and diffusion of gaseous adsorbates within the film. A combination of these two characteristics enables efficient fluorescence quenching of the film by gaseous quenchers.

  DOI：

  10.1021/ja070747q
• 作为产物：
  描述：

  3,6-二溴咔唑 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 tris(dibenzylideneacetone)dipalladium (0) 哌啶 、 4-二甲氨基吡啶 、 sodium hydroxide 、 三乙胺 、 三苯基膦 作用下， 以 四氢呋喃 、 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 4.75h， 生成 3,6-bis(benzoylbiphenyl)ethynylcarbazole-9-carboxylic acid 1,1-dimethyltridecyl ester
  参考文献：
  名称：

  Detection of Explosives with a Fluorescent Nanofibril Film

  摘要：

  A new type of fluorescence sensory material has been developed from an alkoxycarbonyl-substituted carbazole-cornered tetracycle. Films fabricated from such materials are shown to be efficient in detecting explosive vapor, probably owing to the extended 1D molecular stacking between the component molecules and intrinsic nanoporous morphology thus formed within the film. The former facilitates long-range exciton migration, while the latter favors adsorption and diffusion of gaseous adsorbates within the film. A combination of these two characteristics enables efficient fluorescence quenching of the film by gaseous quenchers.

  DOI：

  10.1021/ja070747q

文献信息

• PREPARATION OF A CARBAZOLE-BASED MACROCYCLE VIA PRECIPITATION-DRIVEN ALKYNE METATHESIS
  作者：Zhang, Wei、Cho, Hyeon Mo、Moore, Jeffrey S.、Denmark, Scott E.、Butler, Christopher R.

  DOI：10.15227/orgsyn.084.0177

  日期：——