di-n-propyl 1,4-cyclohexanedicarboxylate | 92371-47-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: di-n-propyl 1,4-cyclohexanedicarboxylate
• 英文别名: Hexahydroterephthalsaeure-dipropylester；Dipropyl cyclohexane-1,4-dicarboxylate
• CAS: 92371-47-6
• 化学式: C₁₄H₂₄O₄
• 分子量: 256.342
• InChiKey: YTZVKGLPOSQCML-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  丁二酸二异丙酯 在 5%-palladium/activated carbon 、 氢气 作用下， 以 异丙醇 为溶剂， 180.0 ℃ 、3.0 MPa 条件下， 生成 di-n-propyl 1,4-cyclohexanedicarboxylate
  参考文献：
  名称：

  一种制备1,4-环己烷二甲酸二酯的方法

  摘要：

  一种制备1,4-环己烷二甲酸二酯的新方法，该方法以丁二酸二酯为原料，经酯缩合得到丁二酰丁二酸二酯，然后丁二酰丁二酸二酯加氢脱水得到1,4-环己烷二甲酸二酯。本发明提供了一条制备1,4-环己烷二甲酸二酯的新路线，具有非常重要的发展潜力和广阔应用前景。

  公开号：

  CN104276953B

文献信息

• PROCESS FOR PRODUCING EXPANDABLE STYRENE POLYMER COMPOSITIONS
  申请人：Husemann Wolfram

  公开号：US20110291040A1

  公开（公告）日：2011-12-01

  A composition comprising at least one expandable styrene polymer component and at least one cyclohexanecarboxylic ester and also optionally further components can be processed to mechanically robust foam materials.

  本发明涉及一种组合物，包括至少一种可膨胀苯乙烯聚合物组分和至少一种环己烷羧酸酯，还可以选择性地加入其他组分，可加工成具有机械强度的泡沫材料。
• CYCLOHEXANE POLYCARBOXYLIC ACID DERIVATIVES AS PLASTICIZERS FOR ADHESIVES AND SEALANTS
  申请人：Mack Helmut

  公开号：US20110232825A1

  公开（公告）日：2011-09-29

  The invention provides an adhesive or sealant comprising at least (A) one compound selected from the group consisting of silylated polyurethanes, silylated polyureas, silylated polyethers, silylated polysulfides and silyl-terminated acrylates, and at least (B) one cyclohexane polycarboxylic acid derivative. The composition has enhanced extensibility with good adhesion properties and high tensile strength. A process is disclosed for preparing the adhesive or sealant, and also disclosed is the use thereof for producing material bonds between parts to be joined.

  本发明提供了一种粘合剂或密封剂，包括至少（A）从包括硅化聚氨酯、硅化聚氨基甲酸酯、硅化聚醚、硅化聚硫化物和硅基终止丙烯酸酯的群组中选择的一种化合物，以及至少（B）一种环己烷聚羧酸衍生物。该组合物具有良好的粘附性和高拉伸强度的增强延展性。还公开了制备粘合剂或密封剂的过程，并公开了将其用于在要连接的零件之间产生材料粘结的用途。
• Transesterification catalysts and thermoset coatings
  申请人：THE GLIDDEN COMPANY

  公开号：EP0252289A2

  公开（公告）日：1988-01-13

  A new transesterification catalyst comprises an epoxide and a non-acidic nucleophilic onium salt. Coating compositions having hydroxyl functional resin components and carboxylic ester components adapted for curing by transesterification following application to a substrate are formulated with in-situ formed cure catalyst comprising a non-acidic nucleophile and an epoxide-to-product coatings that readily cure by transesterification. Such coatings include polyesters, polyepoxides, and polyacrylates are useful in formulating high solids coating and powder coatings having exceptional physical properties. Extremely low-temperature cure coatings were obtained by transesterifying mixtures of polyols and polymeric esters having multiple activated ester linkages having the structure wherein Rʹ is lower alkyl and Y is -OH and O-alkyl radicals. These coatings provide low-temperature cure coatings for paper, plastic, and wood in addition to metal substrates. Such catalysts can be used in powder coatings compositions which comprise a hydroxyl functional binder having carboxylic ester functionality. Such resins include hydroxyl functional acrylic, hydroxyl functional polyester, ester functional polyesters and methyl succinate esters of bis phenol epoxides.

  一种新型酯交换催化剂由环氧化物和一种非酸性亲核鎓盐组成。 具有羟基官能树脂成分和羧酸酯成分的涂料组合物在涂抹到基材上后可通过酯交换反应固化，这种涂料组合物是用原位固化催化剂配制而成的，该催化剂由非酸性亲核物和环氧化物组成，可生成易于通过酯交换反应固化的涂料。此类涂料包括聚酯、聚环氧化物和聚丙烯酸酯，可用于配制具有优异物理性能的高固体份涂料和粉末涂料。 通过酯交换多元醇和聚合酯混合物获得极低温固化涂料，这些混合物具有多个活化酯连接，其结构如下 其中 Rʹ 为低级烷基，Y 为-OH 和 O-烷基。除金属基材外，这些涂料还可为纸张、塑料和木材提供低温固化涂料。 此类催化剂可用于粉末涂料组合物中，其中包括具有羧酸酯官能团的羟基官能团粘合剂。此类树脂包括羟基官能丙烯酸树脂、羟基官能聚酯、酯官能聚酯和双酚环氧化物甲基琥珀酸酯。
• Coating composition
  申请人：THE GLIDDEN COMPANY

  公开号：EP0328950A1

  公开（公告）日：1989-08-23

  A protective surface coating composition containing a catalytic amount of a transesterification catalyst, where the coating composition contains a polymeric binder adapted to crosslink by transesterification upon heat curing, the coating composition comprising: a polymeric binder containing hydroxyl functional groups and lower alkyl ester carboxylic ester functional groups adapted to transesterify and crosslink in the presence of a transesterification catalyst; said transesterification catalyst comprising on the basis of 100 weight parts of said polymeric binder betwen 1 and 20 weight parts of catalytic epoxy compound containing oxirane functionality in combination with 0.1 to 10 weight parts of (a) a conjugate base of a weak acid comprising an inorganic cation salt, where the conjugate base of a weak acid has a pka between 2.5 and 14; or (b) an inorganic salt having an inorganic cation selected from sodium, potassium, lithium, calcium, and iron and an inorganic anion selected from a halogen, azide, cyanide or hydroxide; where said polymeric binder is substantially free of carboxyl groups and is adapted to cure by transesterification.

  一种含有催化量的酯交换催化剂的保护性表面涂层组合物，其中涂层组合物含有一种聚合物粘合剂，该聚合物粘合剂在加热固化时可通过酯交换反应发生交联，该涂层组合物包括： 聚合物粘合剂，含有羟基官能团和低级烷基酯羧酸酯官能团，在酯交换催化剂作用下可发生酯交换和交联； 所述酯交换催化剂以 100 重量份所述聚合物粘合剂为基准，包括 1 至 20 重量份含有环氧乙烷官能团的催化环氧化合物与 0.1 至 10 重量份的 (a) 弱酸共轭碱，包括无机阳离子盐，其中弱酸共轭碱的 pka 值在 2.5 至 14 之间；或 (b) 无机盐，其无机阳离子选自钠、钾、锂、钙和铁，无机阴离子选自卤素、叠氮化物、氰化物或氢氧化物； 其中所述聚合物粘合剂基本上不含羧基，可通过酯交换反应固化。
• PROCESS FOR THE PREPARATION OF CYCLOHEXANEDIMETHANOL
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0922690A1

  公开（公告）日：1999-06-16

  This invention provides a process for preparing cyclohexanedimethanol comprising hydrogenating a cyclohexanedicarboxylic acid dialkyl ester by a fixed-bed continuous reaction in the presence of a preformed copper-containing catalyst under the conditions of reaction temperature of 200 to 280°C, hydrogen pressure of 185 to 300 kgf/cm2 and hydrogen gas feed rate of 1 to 40 cm/s in terms of superficial linear velocity, the cyclohexanedicarboxylic acid dialkyl ester being prepared, typically, by ring hydrogenating of an aromatic dicarboxylic acid dialkyl ester in the presence of a preformed supported ruthenium catalyst by a fixed-bed continuous reaction.

  本发明提供了一种制备环己烷二甲醇的工艺，该工艺包括在预制含铜催化剂存在下，通过固定床连续反应对环己烷二羧酸二烷基酯进行氢化，反应温度为200至280℃，氢气压力为185至300千克/平方厘米，氢气进料速度为1至40厘米/秒、氢气压力为 185 至 300 kgf/cm2，氢气进料速度（以表面线速度计）为 1 至 40 cm/s，环己烷二羧酸二烷基酯的制备通常是通过芳香族二羧酸二烷基酯在预制的支撑钌催化剂存在下通过固定床连续反应进行环氢化。