(γ-pyridylmethyl)diphenylphosphine oxide N-oxide | 134576-23-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (γ-pyridylmethyl)diphenylphosphine oxide N-oxide
• 英文别名: 4-[(Diphenylphosphoryl)methyl]-1-pyridiniumolate；4-(diphenylphosphorylmethyl)-1-oxidopyridin-1-ium
• CAS: 134576-23-1
• 化学式: C₁₈H₁₆NO₂P
• mdl: MFCD01303912
• 分子量: 309.304
• InChiKey: BZDWFAMYTCYOIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (4-吡啶甲基)锂 在 双氧水 作用下， 以 四氢呋喃 、 溶剂黄146 为溶剂， 反应 25.67h， 生成 (γ-pyridylmethyl)diphenylphosphine oxide N-oxide
  参考文献：
  名称：

  Phosphorylmethylpyridines and their N-oxides: Synthesis and equilibrium CH-acidity

  摘要：

  Certain phosphorylmethylpyridines and their N-oxides were synthesized, which are of interest as extractants and complex-forming agents. Their equilibrium CH-acidity with reference to 9-phenylfluorene (K+ counterion) was studied by the indicator method in dimethyl sulfoxide. The acidifying action of a series of pyridine groupings was characterized by means of sigma-C- values.

  DOI：

  10.1007/bf00958579

文献信息

• BODRIN, G. V.;MATVEEVA, A. G.;TEREXOVA, M. N.;MATROSOV, E. N.;PETROV, EH.+, IZV. AN CCCP. CEP. XIM.,(1991) N, S. 912-921
  作者：BODRIN, G. V.、MATVEEVA, A. G.、TEREXOVA, M. N.、MATROSOV, E. N.、PETROV, EH.+

  DOI：——

  日期：——
• Phosphorylmethylpyridines and their N-oxides: Synthesis and equilibrium CH-acidity
  作者：G. V. Bodrin、A. G. Matveeva、M. I. Terekhova、E. I. Matrosov、�. S. Petrov、Yu. M. Polikarpov、M. I. Kabachnik

  DOI：10.1007/bf00958579

  日期：1991.4

  Certain phosphorylmethylpyridines and their N-oxides were synthesized, which are of interest as extractants and complex-forming agents. Their equilibrium CH-acidity with reference to 9-phenylfluorene (K+ counterion) was studied by the indicator method in dimethyl sulfoxide. The acidifying action of a series of pyridine groupings was characterized by means of sigma-C- values.