Acetic acid 4-((3E,5E,7E)-10-acetoxy-deca-3,5,7-trienyl)-2-hydroxy-phenyl ester | 206666-58-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Acetic acid 4-((3E,5E,7E)-10-acetoxy-deca-3,5,7-trienyl)-2-hydroxy-phenyl ester
• 英文别名: [(3E,5E,7E)-10-(4-acetyloxy-3-hydroxyphenyl)deca-3,5,7-trienyl] acetate
• CAS: 206666-58-2
• 化学式: C₂₀H₂₄O₅
• 分子量: 344.408
• InChiKey: LWFIOBDHPWBWRA-OKWWDJPNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  25
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  72.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 Acetic acid 4-((3E,5E,7E)-10-acetoxy-deca-3,5,7-trienyl)-2-hydroxy-phenyl ester 生成 Acetic acid 4-((3E,5E,7E)-10-acetoxy-deca-3,5,7-trienyl)-2-methoxy-phenyl ester
  参考文献：
  名称：

  Alkylphenols from the cephalaspidean mollusc Haminoea callidegenita

  摘要：

  Alkylphenols 6-10 are the main metabolites isolated from the parapodia extract of the marine mollusc Haminoea callidegenita. The structure and the anatomical location of these compounds strongly support their potential defensive role as alarm pheromones. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)00117-8
• 作为产物：
  描述：

  2,2-dimethyl-5-[(3E,5E,7E)-10-(oxan-2-yloxy)deca-3,5,7-trienyl]-1,3-benzodioxole 在 吡啶 、 水 作用下， 以 二氯甲烷 为溶剂， 反应 18.0h， 生成 Acetic acid 4-((3E,5E,7E)-10-acetoxy-deca-3,5,7-trienyl)-2-hydroxy-phenyl ester
  参考文献：
  名称：

  Synthesis of alkylphenols and alkylcatechols from the marine mollusc Haminoea callidegenita

  摘要：

  Alkylphenols 1-5, potential alarm pheromones of the marine mollusc Haminoea callidegenita, have been synthesized using a convergent approach centred on a Stifle coupling reaction. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)00532-3

文献信息

• Synthesis of alkylphenols and alkylcatechols from the marine mollusc Haminoea callidegenita
  作者：Irene Izzo、Salvatore De Caro、Francesco De Riccardis、Aldo Spinella

  DOI：10.1016/s0040-4039(00)00532-3

  日期：2000.5

  Alkylphenols 1-5, potential alarm pheromones of the marine mollusc Haminoea callidegenita, have been synthesized using a convergent approach centred on a Stifle coupling reaction. (C) 2000 Elsevier Science Ltd. All rights reserved.
• Alkylphenols from the cephalaspidean mollusc Haminoea callidegenita
  作者：Aldo Spinella、Luis A. Alvarez、Guido Cimino

  DOI：10.1016/s0040-4039(98)00117-8

  日期：1998.4

  Alkylphenols 6-10 are the main metabolites isolated from the parapodia extract of the marine mollusc Haminoea callidegenita. The structure and the anatomical location of these compounds strongly support their potential defensive role as alarm pheromones. (C) 1998 Elsevier Science Ltd. All rights reserved.