N,N-bis-{4-[2-(4-dibutylaminophenyl)vinyl]phenyl}benzamide | 862420-03-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-bis-{4-[2-(4-dibutylaminophenyl)vinyl]phenyl}benzamide
• 英文别名: N,N-bis[4-[(E)-2-[4-(dibutylamino)phenyl]ethenyl]phenyl]benzamide
• CAS: 862420-03-9
• 化学式: C₅₁H₆₁N₃O
• 分子量: 732.065
• InChiKey: RFQSKFVVBIIVKR-FRCMOREXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.3
• 重原子数：
  55
• 可旋转键数：
  21
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  26.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N,N-bis-{4-[2-(4-dibutylaminophenyl)vinyl]phenyl}benzamide 在 氢氧化钾 作用下， 以 四氢呋喃 、 甲醇 、 水 为溶剂， 反应 12.0h， 生成 (E,E)-bis(4-(2-(4-N,N-dibutylaminophenyl)ethenyl)phenyl)amine
  参考文献：
  名称：

  Synthesis of Triphenylamine-Cored Dendritic Two-Photon Absorbing Chromophores

  摘要：

  A new series of dendritic two-photon absorbing chromophores containing triphenylamine moiety as a core or branching points have been synthesized through a convergent synthetic strategy. One-photon and two-photon optical properties of these molecules were characterized. In the nanosecond time domain, these molecules exhibited large two-photon absorption (TPA) cross sections up to 7.56-12.2 X 10(-44) S cm(4) at 800 nm, indicating that these molecular structures were viable candidates for various two-photon related applications.

  DOI：

  10.1021/ol050905n
• 作为产物：
  描述：

  N,N-diphenylbenzamide 在 palladium diacetate 溴 、 三乙胺 、 三(邻甲基苯基)磷 作用下， 以 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 反应 80.0h， 生成 N,N-bis-{4-[2-(4-dibutylaminophenyl)vinyl]phenyl}benzamide
  参考文献：
  名称：

  Synthesis of Triphenylamine-Cored Dendritic Two-Photon Absorbing Chromophores

  摘要：

  A new series of dendritic two-photon absorbing chromophores containing triphenylamine moiety as a core or branching points have been synthesized through a convergent synthetic strategy. One-photon and two-photon optical properties of these molecules were characterized. In the nanosecond time domain, these molecules exhibited large two-photon absorption (TPA) cross sections up to 7.56-12.2 X 10(-44) S cm(4) at 800 nm, indicating that these molecular structures were viable candidates for various two-photon related applications.

  DOI：

  10.1021/ol050905n

文献信息

• Synthesis of Triphenylamine-Cored Dendritic Two-Photon Absorbing Chromophores
  作者：Peng Wei、Xiangdong Bi、Zhe Wu、Zhi Xu

  DOI：10.1021/ol050905n

  日期：2005.7.1

  A new series of dendritic two-photon absorbing chromophores containing triphenylamine moiety as a core or branching points have been synthesized through a convergent synthetic strategy. One-photon and two-photon optical properties of these molecules were characterized. In the nanosecond time domain, these molecules exhibited large two-photon absorption (TPA) cross sections up to 7.56-12.2 X 10(-44) S cm(4) at 800 nm, indicating that these molecular structures were viable candidates for various two-photon related applications.