1--2-(diphenylphosphino)ethan | 152066-54-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1--2-(diphenylphosphino)ethan
• 英文别名: 1-{di(4-methoxyphenyl)phosphino}-2-(diphenylphosphino)ethane；2-Bis(4-methoxyphenyl)phosphanylethyl-diphenylphosphane；2-bis(4-methoxyphenyl)phosphanylethyl-diphenylphosphane
• CAS: 152066-54-1
• 化学式: C₂₈H₂₈O₂P₂
• 分子量: 458.477
• InChiKey: ZFJKSUHJIKLDSC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  32
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  六羰基铬 、 1--2-(diphenylphosphino)ethan 、 乙腈 以 乙腈 为溶剂， 以80%的产率得到fac-acetonitrile(tricarbonyl)(1-{di(4-methoxyphenyl)phosphino}-2-(diphenylphosphino)ethane)chromium
  参考文献：
  名称：

  Optisch aktive Übergangsmetall-Komplexe CV. Faciale und meridionale Chromcarbonylphosphin-Komplexe

  摘要：

  The optically active, facial complex Cr(CO)3(PP'P'') (1) with the tridentade ligand PP'P'' = (R)-(+)-1,2,4-tris(diphenyl-phosphino)butane has been synthesized and characterized. The complex Cr(CO)3(PP')P'' (PP' = (R)-(+)-prophos, P'' = PMe2Ph) forms two pairs of diastereomers, facial (3, 4) and meridional (5, 6), respectively, that can be separated by preparative column chromatography. Surprisingly, the CD spectra of Cr(CO)3(PP'P'') (1) and the facial diastereomer of Cr(CO)3(PP')P'' (3), which have the same configuration at the Cr atom, are dissimilar. The meridional configuration of the two isomers 5 and 6 of Cr(CO)3(PP')PMe2Ph is supported by the P-31 and H-1 NMR spectra of the optically inactive complex Cr(CO)3(PP')P'' (PP' = 1-[di(4-methoxyphenyl)phosphino]-2-(diphenylphosphino)ethane P'' = PMePh2), which forms the meridional isomers 9 and 10.

  DOI：

  10.1016/0022-328x(93)86065-p
• 作为产物：
  描述：

  双(4-甲氧基苯基)膦 、 乙烯基二苯基膦 在 potassium n-butoxide 作用下， 生成 1--2-(diphenylphosphino)ethan
  参考文献：
  名称：

  Optisch aktive Übergangsmetall-Komplexe CV. Faciale und meridionale Chromcarbonylphosphin-Komplexe

  摘要：

  The optically active, facial complex Cr(CO)3(PP'P'') (1) with the tridentade ligand PP'P'' = (R)-(+)-1,2,4-tris(diphenyl-phosphino)butane has been synthesized and characterized. The complex Cr(CO)3(PP')P'' (PP' = (R)-(+)-prophos, P'' = PMe2Ph) forms two pairs of diastereomers, facial (3, 4) and meridional (5, 6), respectively, that can be separated by preparative column chromatography. Surprisingly, the CD spectra of Cr(CO)3(PP'P'') (1) and the facial diastereomer of Cr(CO)3(PP')P'' (3), which have the same configuration at the Cr atom, are dissimilar. The meridional configuration of the two isomers 5 and 6 of Cr(CO)3(PP')PMe2Ph is supported by the P-31 and H-1 NMR spectra of the optically inactive complex Cr(CO)3(PP')P'' (PP' = 1-[di(4-methoxyphenyl)phosphino]-2-(diphenylphosphino)ethane P'' = PMePh2), which forms the meridional isomers 9 and 10.

  DOI：

  10.1016/0022-328x(93)86065-p

文献信息

• Optisch aktive Übergangsmetall-Komplexe CV. Faciale und meridionale Chromcarbonylphosphin-Komplexe
  作者：Henri Brunner、Andreas Stumpf

  DOI：10.1016/0022-328x(93)86065-p

  日期：1993.10

  The optically active, facial complex Cr(CO)3(PP'P'') (1) with the tridentade ligand PP'P'' = (R)-(+)-1,2,4-tris(diphenyl-phosphino)butane has been synthesized and characterized. The complex Cr(CO)3(PP')P'' (PP' = (R)-(+)-prophos, P'' = PMe2Ph) forms two pairs of diastereomers, facial (3, 4) and meridional (5, 6), respectively, that can be separated by preparative column chromatography. Surprisingly, the CD spectra of Cr(CO)3(PP'P'') (1) and the facial diastereomer of Cr(CO)3(PP')P'' (3), which have the same configuration at the Cr atom, are dissimilar. The meridional configuration of the two isomers 5 and 6 of Cr(CO)3(PP')PMe2Ph is supported by the P-31 and H-1 NMR spectra of the optically inactive complex Cr(CO)3(PP')P'' (PP' = 1-[di(4-methoxyphenyl)phosphino]-2-(diphenylphosphino)ethane P'' = PMePh2), which forms the meridional isomers 9 and 10.