(1S,2S)-cyclohexane-1,2-dithiol | 677723-15-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醇
• 英文名称: (1S,2S)-cyclohexane-1,2-dithiol
• 英文别名: trans-Cyclohexandithiol-(1,2)
• CAS: 677723-15-8
• 化学式: C₆H₁₂S₂
• 分子量: 148.293
• InChiKey: YKRCKUBKOIVILO-WDSKDSINSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (1S,2S)-cyclohexane-1,2-dithiol 、 2-(iodo methyl)-4-tert-butyl-6-(di-tert-butyl-carbazole)phenol 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 16.0h， 以95%的产率得到4-tert-butyl-2-[[(1S,2S)-2-[[5-tert-butyl-3-(3,6-ditert-butylcarbazol-9-yl)-2-hydroxyphenyl]methylsulfanyl]cyclohexyl]sulfanylmethyl]-6-(3,6-ditert-butylcarbazol-9-yl)phenol
  参考文献：
  名称：

  Production of Olefin Dimers

  摘要：

  生产α-烯烃二聚体的方法包括在80°C或更高的温度下，将至少含有一种C8+（直链）α-烯烃的原料与由活化剂和一个或多个催化剂化合物组成的催化剂体系接触，该化合物由以下公式表示： 其中M是第4族金属；n为1、2或3；RA是氢或C1至C10烷基；R1、R2、R3、R4、R5、R6、R7和R8中的每一个独立地选择自氢和C1至C10烷基；每个X独立地选择自具有1至20个碳原子的烃基基团、氢化物、酰胺、烷氧基、硫化物、磷化物、卤化物及其组合物（两个X可能形成融合环或环系统的一部分），接触在有效条件下进行，以将至少C8+α-烯烃的部分寡聚化为至少含有30重量%α-烯烃二聚体和至少80摩尔%乙烯二烯不饱和度的寡聚化产品，其中α-烯烃的转化率至少为10重量%，基于进入反应器的α-烯烃单体的重量和生成的二聚体的重量。

  公开号：

  US20190002366A1

文献信息

• CATALYST FOR STEREOSELECTIVE OLEFIN POLYMERIZATION AND METHOD FOR MANUFACTURING STEREOSELECTIVE POLYOLEFIN
  申请人：Ishii Akihiko

  公开号：US20130059991A1

  公开（公告）日：2013-03-07

  A stereoselective olefin polymerization catalyst contains a complex represented by Formula (1): wherein n is 2 or 3; R 1 and R 2 are independently an optionally substituted alkyl group or a halogen atom; L is a ligand represented by CH 2 R 3 , a halogen atom, OR 4 , or NR 5 R 6 ; R 3 is a hydrogen atom, an aromatic group, or a trialkylsilyl group; R 4 is a lower alkyl group having 1 to 6 carbon atoms; and R 5 and R 6 are independently a hydrogen atom or a lower alkyl group having 1 to 6 carbon atoms. A method for manufacturing stereoselective polyolefin, includes polymerizing an olefin in the presence of the catalyst. The present invention provides a catalyst which enables highly isoselective polymerization generating a polymer having significantly high molecular weight and also can prepare stereoselective polyolefin with a narrow dispersity (Mw/Mn) or with a sharp molecular weight distribution, and provides a method for manufacturing stereoselective polyolefin with the catalyst.

  一种立体选择性烯烃聚合催化剂包含由式（1）表示的复合物： 其中n为2或3；R1和R2分别为可选择取代的烷基或卤素原子；L为CH2R3表示的配体、卤素原子、OR4或NR5R6；R3为氢原子、芳香族基团或三烷基硅基团；R4为具有1至6个碳原子的低烷基基团；R5和R6分别为氢原子或具有1至6个碳原子的低烷基基团。一种制备立体选择性聚烯烃的方法包括在催化剂存在下聚合烯烃。本发明提供了一种催化剂，可以实现高度立体选择性的聚合，生成具有显著高分子量的聚合物，并且可以制备具有窄分子量分布（Mw/Mn）或尖锐分子量分布的立体选择性聚烯烃，并提供了一种使用该催化剂制备立体选择性聚烯烃的方法。
• Production of olefin dimers
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US10358397B2

  公开（公告）日：2019-07-23

  A process for producing alpha-olefin dimers comprises contacting, at a temperature of 80° C. or more, a feedstock comprising at least one C8+ (linear) alpha-olefin with a catalyst system comprising activator and one or more catalyst compounds represented by the formula: where M is a Group 4 metal; n is 1, 2, or 3; RA is hydrogen or a C1 to C10 alkyl; each of R1, R2, R3, R4, R5, R6, R7, and R8 is independently selected from hydrogen and C1 to C10 alkyl; each X is independently selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halides, and a combination thereof, (two X's may form a part of a fused ring or a ring system), the contacting being conducted under conditions effective to oligomerize at least part of C8+ alpha-olefin to produce an oligomerized product containing at least 30 wt % of the alpha-olefin dimer and at least 80 mol % of vinylidene unsaturation, where the conversion of the alpha olefin is at least 10 wt %, based upon the weight of the alpha olefin monomer entering the reactor and the weight of dimer produced.

  一种生产α-烯烃二聚体的工艺，包括在 80° C 或更高温度下，将包含至少一种 C8+（线性）α-烯烃的原料与催化剂体系接触，该催化剂体系包含活化剂和一种或多种由式表示的催化剂化合物： 其中 M 为第 4 族金属；n 为 1、2 或 3；RA 为氢或 C1 至 C10 烷基；R1、R2、R3、R4、R5、R6、R7 和 R8 中的每一个独立地选自氢和 C1 至 C10 烷基；每个 X 独立地选自由 1 至 20 个碳原子的烃基、氢化物、酰胺、烷氧基化物、硫化物、磷化 物、卤化物及其组合组成的组、在使至少部分 C8+ α-烯烃低聚的有效条件下进行接触，以产生含有至少 30 重量％的 α-烯烃二聚体和至少 80 摩尔％的亚乙烯基不饱和的低聚产物，其中根据进入反应器的 α-烯烃单体重量和产生的二聚体重量计算，α-烯烃的转化率至少为 10 重量％。
• ETHYLENIC POLYMERIZATION CATALYST AND METHOD FOR MANUFACTURING ETHYLENIC POLYMER
  申请人：Ishi Akihiko

  公开号：US20130035462A1

  公开（公告）日：2013-02-07

  A catalyst for homopolymerization of ethylene or copolymerization of ethylene and an α-olefin comprises a complex represented by Formula (1): wherein n is 2 or 3; R 1 and R 2 are independently an optionally substituted alkyl group or a halogen atom; L is a ligand represented by CH 2 R 3 , a halogen atom, OR 4 , or NR 5 R 6 ; R 3 is a hydrogen atom, an aromatic group, or a trialkylsilyl group; R 4 is a lower alkyl group having 1 to 6 carbon atoms; and R 5 and R 6 are independently a hydrogen atom or a lower alkyl group having 1 to 6 carbon atoms. A method for manufacturing an ethylenic polymer involves homopolymerization of ethylene or copolymerization of ethylene and an α-olefin in the presence of the catalyst. The present invention provides a highly active tetradentate post-metallocene complex for ethylenic polymerization and a method for manufacturing the ethylenic polymer using the catalyst containing the complex.
• OLEFIN POLYMER PRODUCING METHOD, ETHYLENE POLYMER, AND MOLD PRODUCT
  申请人：OCHI Naoko

  公开号：US20130041119A1

  公开（公告）日：2013-02-14

  A method for producing an olefin polymer, including: polymerizing olefin monomers using the following substance (A1), the following substance (A2), and an activating agent (B): the substance (A1): a complex represented by the following general formula (1-1) or (1-2) the substance (A2): a transition metal compound represented by the following general formula (8) or a μ-oxo-type dimer of a transition metal compound represented by the general formula (8)
• US4004018A
  申请人：——

  公开号：US4004018A

  公开（公告）日：1977-01-18