3,3'-((1,4-phenylenebis(methylene))bis(oxy))bis(N1,N2-dimesitylpropane-1,2-diamine) | 951787-52-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3'-((1,4-phenylenebis(methylene))bis(oxy))bis(N1,N2-dimesitylpropane-1,2-diamine)
• CAS: 951787-52-3
• 化学式: C₅₀H₆₆N₄O₂
• 分子量: 755.1
• InChiKey: XQJSDYHKTZJAMT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.61
• 重原子数：
  56.0
• 可旋转键数：
  18.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  66.58
• 氢给体数：
  4.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  3,3'-((1,4-phenylenebis(methylene))bis(oxy))bis(N1,N2-dimesitylpropane-1,2-diamine) 、 原甲酸三乙酯 在 氟硼酸铵 作用下， 以 甲苯 为溶剂， 反应 6.0h， 以57%的产率得到
  参考文献：
  名称：

  Self-Supported Oligomeric Grubbs/Hoveyda-Type Ru−Carbene Complexes for Ring-Closing Metathesis

  摘要：

  On the basis of the release-return metathesis mechanism, self-supported oligomeric Grubbs/Hoveyda-type Ru-carbene complexes have been designed and synthesized as a new type of recoverable catalyst for ring-closing metathesis. The catalytic activities of the self-supported oligomeric Ru-carbene complex in ring-closing metathesis are comparable to those of their homogeneous counterpart as they work homogeneously and are recovered heterogeneously.

  DOI：

  10.1021/ol7016774
• 作为产物：
  描述：

  2,4,6-三甲基苯胺 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 38.0h， 生成 3,3'-((1,4-phenylenebis(methylene))bis(oxy))bis(N1,N2-dimesitylpropane-1,2-diamine)
  参考文献：
  名称：

  Self-Supported Oligomeric Grubbs/Hoveyda-Type Ru−Carbene Complexes for Ring-Closing Metathesis

  摘要：

  On the basis of the release-return metathesis mechanism, self-supported oligomeric Grubbs/Hoveyda-type Ru-carbene complexes have been designed and synthesized as a new type of recoverable catalyst for ring-closing metathesis. The catalytic activities of the self-supported oligomeric Ru-carbene complex in ring-closing metathesis are comparable to those of their homogeneous counterpart as they work homogeneously and are recovered heterogeneously.

  DOI：

  10.1021/ol7016774