cobalt(II) 5-(4-carboxyphenyl)-10,15,20-triphenyl porphyrin | 454187-33-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cobalt(II) 5-(4-carboxyphenyl)-10,15,20-triphenyl porphyrin
• CAS: 454187-33-8
• 化学式: C₄₅H₂₈CoN₄O₂
• 分子量: 715.736
• InChiKey: PBNZLHTYMHANBE-DAJBKUBHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cobalt(II) 5-(4-carboxyphenyl)-10,15,20-triphenyl porphyrin 在 氯化亚砜 作用下， 以 氯仿 为溶剂， 反应 3.0h， 生成
  参考文献：
  名称：

  不同饱和磁化强度的二氧化硅包覆Fe3O4纳米颗粒键合金属卟啉的合成及催化性能

  摘要：

  本文采用改良的硅烷化方法合成了一系列具有不同饱和磁化强度的纳米颗粒结合金属卟啉。在地磁场(5 × 10−5 T)下，随着饱和磁化强度的增加，这些纳米颗粒结合的金属卟啉催化环己烷氧化碘代苯中环己醇的产率增长速度为铁卟啉>锰卟啉>钴卟啉。摘要 采用改进的硅烷化方法合成了一系列不同饱和磁化强度的纳米颗粒结合金属卟啉。在地磁场（5 × 10−5 T）下，随着饱和磁化强度的增加，

  DOI：

  10.1007/s10562-010-0379-z
• 作为产物：
  描述：

  苯甲醛 在 丙酸 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.0h， 生成 cobalt(II) 5-(4-carboxyphenyl)-10,15,20-triphenyl porphyrin
  参考文献：
  名称：

  Immobilization of metalloporphyrin on a silica shell with bimetallic oxide core for ethylbenzene oxidation

  摘要：

  在这项研究中，金属卟啉被固定在核壳结构的SiO₂@CeO₂上，掺杂有过渡金属如铁、铜、钴和锰。

  DOI：

  10.1039/c5ra02020d

文献信息

• Preparation of Co–N–C supported on silica spheres with high catalytic performance for ethylbenzene oxidation
  作者：Zhigang Liu、Lintao Ji、Xulong Dong、Zhen Li、Lingling Fu、Qiuan Wang

  DOI：10.1039/c4ra09269d

  日期：——

  In this study, Co–N–C supported on silica spheres is prepared through heat-treatment of supported metalloporphyrin in an N₂ atmosphere.

  在这项研究中，通过在N₂气氛中热处理支撑的金属卟啉制备了载有二氧化硅球的Co-N-C。
• Preparation and Self-assembly of Chiral Porphyrin Diads on the Gold Electrodes of Quartz Crystal Microbalances: A Novel Potential Approach to the Development of Enantioselective Chemical Sensors
  作者：Roberto Paolesse、Donato Monti、Laura La Monica、Mariano Venanzi、Antonella Froiio、Sara Nardis、Corrado Di Natale、Eugenio Martinelli、Arnaldo D'Amico

  DOI：10.1002/1521-3765(20020603)8:11<2476::aid-chem2476>3.0.co;2-e

  日期：2002.6.3

  Porphyrin diad 1 was synthesized by reaction of the acyl chloride of porphyrin 2 and trans-1,2-dithiane-4,5-diol. The Co complex of this diad was studied as a potential enantioselective receptor for chiral recognition in solution and in the solid state. In solution both enantiomers of limonene induce significant changes in the visible and circular dichroism (CD) spectra of [Co2(1)], while a different

  卟啉二元化合物1是通过卟啉2的酰氯与反式1,2-二噻吩-4,5-二醇反应而合成的。研究了该二元共聚物的Co络合物作为潜在的对映选择性受体，用于溶液和固态中的手性识别。在溶液中，柠檬烯的两种对映异构体均会引起[Co2（1）]的可见光和圆二色性（CD）光谱发生显着变化，而反式1,2-二氨基环己烷的对映体对则观察到不同的行为。这些化合物获得了不同的[Co2（1）]手性识别效率，在柠檬烯的情况下观察到了显着的对映异构。[Co2（1）]的自组装单分子层沉积到石英晶体微天平的金电极上，用作在气相中运行的纳米重力传感器的传感材料。已经研究了这些传感器对手性分析物的对映体对的对映歧化性质。对于载有供体配体原子的分析物，我们没有观察到明显的对映选择性，而在柠檬烯的情况下，则观察到了很大程度的手性鉴别。该结果对于用于阵列配置的对映选择性化学传感器的潜在开发特别令人鼓舞。对于载有供体配体原子的分析物，我们没有观
• Aqueous Reductive Dechlorination of Chlorinated Ethylenes with Tetrakis(4-carboxyphenyl)porphyrin Cobalt
  作者：Joseph M. Fritsch、Kristopher McNeill

  DOI：10.1021/ic0504339

  日期：2005.6.1

  ethylenes by 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin cobalt ((TCPP)Co), a cobalt complex structurally similar to vitamin B12, was studied. It was found to have superior aqueous-phase dechlorination activity on chlorinated ethylenes (CEs) relative to vitamin B12. Bimolecular rate constants for the degradation of CEs by (TCPP)Co of 250, 24, 0.24, and 1.5 M(-1) s(-1) were found for perchloroethylene

  研究了5,10,15,20-四（4-羧基苯基）卟啉钴（（TCPP）Co）（一种结构类似于维生素B12的钴配合物）对氯化乙烯的催化脱氯。已发现相对于维生素B12，其对氯化乙烯（CEs）具有优异的水相脱氯活性。对于全氯乙烯（PCE），三氯乙烯（TCE），顺式二氯乙烯（cDCE），发现（TCPP）Co通过250、24、0.24和1.5 M（-1）s（-1）降解CE的双分子速率常数）和反式二氯乙烯（tDCE）。通过动力学分析，确定了PCE和TCE的速率规律在底物和催化剂中是一阶的，并且PCE的降解显示出对柠檬酸钛本体还原剂的浓度和pH值敏感。用紫外可见吸收光谱，各种还原剂和循环伏安法研究了Co（I）氧化态对脱卤的重要性。通过制备（TPP）Co（反式-C2H2Cl）以及通过质谱观察（TPP）Co（C2HCl2）和（TCPP）Co（ ），获得了氯乙烯络合物作为潜在的催化循环中间体的证据。报告
• Influence of heat treatment on catalytic performance of Co–N–C/SiO2 for selective oxidation of ethylbenzene
  作者：Zhi-Gang Liu、Lin-Tao Ji、Jia Liu、Ling-Ling Fu、Su-Fang Zhao

  DOI：10.1016/j.molcata.2014.07.032

  日期：2014.12

  The effect of heat treatment on the Co-N-C/SiO2 catalysts prepared through supported metalloporphyrin has been investigated for selective oxidation of ethylbenzene. And techniques such as BET, XRD, FT-IR, UV-vis, TEM, TG-DTA and XPS are used to explore the relationship between heat temperature and the catalytic performance of the catalysts. The results show that Co-N-C/SiO2 catalyst heated at 500 degrees C exhibits much higher activity for ethylbenzene oxidation compared with its counterparts such as Co-N-C/SiO2 catalysts heated at 300 degrees C, 400 degrees C, 600 degrees C and 700 degrees C, respectively. This may be attributed to the formation of much more Co-N-4-C active sites on the surface of Co-N-C/SiO2 catalyst heated at 500 degrees C. (C) 2014 Elsevier B.V. All rights reserved.
• Immobilization of cobalt porphyrin on CeO2@SiO2 core–shell nanoparticles as a novel catalyst for selective oxidation of diphenylmethane
  作者：Xiang Guo、Yuan-Yuan Li、Dan-Hua Shen、Yuan-Yuan Song、Xiao Wang、Zhi-Gang Liu

  DOI：10.1016/j.molcata.2012.11.005

  日期：2013.2

  In this study, CeO2@SiO2 core-shell nanoparticles have been synthesized and used as supports to graft cobalt porphyrin via an amide bond. The catalyst was characterized using techniques such as FT-IR, UV-vis, SEM, TEM and BET. The results show that the catalyst was composed of regular nanoparticles (around 50 nm) with a core-shell structure. In addition, the catalyst exhibits an excellent activity, selectivity and stability for solvent-free selective oxidation of diphenylmethane with atmospheric pressure of oxygen. The conversion of diphenylmethane was as high as 41.6% with selectivity to diphenyl ketone of 96.3%. Even after reused up to 6 times, the catalyst maintained stable working ability. (C) 2012 Elsevier B.V. All rights reserved.